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Highly efficient hydrogen production process from water using electric field assist and strain effect

Research Project

Project/Area Number 18K04839
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 27030:Catalyst and resource chemical process-related
Research InstitutionKochi University (2020)
Waseda University (2018-2019)

Principal Investigator

Ogo Shuhei  高知大学, 教育研究部総合科学系複合領域科学部門, 講師 (40707915)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2020: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2019: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2018: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords資源・エネルギー有効利用技術 / 水素製造 / 水分解 / 低温電場触媒反応 / ストレインエフェクト / 電場触媒反応 / 低温触媒反応 / 酸化還元
Outline of Final Research Achievements

Applying an electric field to solid metal oxide catalysts with lattice strain enabled to proceed both oxygen evolution reaction from surface lattice oxygen of the oxide catalysts and hydrogen evolution by the reaction between lattice oxygen defects and steam, even at 350 degree-C with high reaction rate. Introducing lattice strain (strain effect) and applying the electric field were also effective for lowering the reaction temperature of various hydrogen producing reactions, such as steam reforming of hydrocarbons or alcohols and dehydrogenation of hydrocarbon in the presence of steam. At which, redox reaction involving the surface lattice oxygen of the oxide catalysts were promoted by the strain effects and the electric field assist, and thereby the reactions proceeded with high activity even at low temperatures. These results demonstrated the effectiveness of this research concept that low-temperature catalytic reaction using the electric field assist and the strain effects.

Academic Significance and Societal Importance of the Research Achievements

固体酸化物触媒への構造歪みの導入(ストレインエフェクト)や,微弱な電場を印加することにより,従来高温を必要とした固体酸化物の格子酸素を介した酸化還元反応を,著しく低温化した環境下で進めうることを示した。本成果は,酸化還元型の機構で進行する様々な触媒反応の低温化に応用可能であり,高温を要する様々な化学反応の低温駆動が可能となる。大幅な低温化により,産業的にインパクトの大きい未利用低温排熱を活用した水素製造等の高効率エネルギー製造プロセスの実現が期待される。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (23 results)

All 2021 2020 2019 2018 Other

All Journal Article (11 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 10 results,  Open Access: 5 results) Presentation (9 results) (of which Int'l Joint Research: 2 results,  Invited: 6 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results) (of which Overseas: 1 results)

  • [Journal Article] Fast oxygen ion migration in Cu?In?oxide bulk and its utilization for effective CO2 conversion at lower temperature2021

    • Author(s)
      Makiura Jun-Ichiro、Higo Takuma、Kurosawa Yutaro、Murakami Kota、Ogo Shuhei、Tsuneki Hideaki、Hashimoto Yasushi、Sato Yasushi、Sekine Yasushi
    • Journal Title

      Chemical Science

      Volume: 12 Issue: 6 Pages: 2108-2113

    • DOI

      10.1039/d0sc05340f

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Support effects on catalysis of low temperature methane steam reforming2020

    • Author(s)
      Torimoto Maki、Ogo Shuhei、Hisai Yudai、Nakano Naoya、Takahashi Ayako、Ma Quanbao、Seo Jeong Gil、Tsuneki Hideaki、Norby Truls、Sekine Yasushi
    • Journal Title

      RSC Advances

      Volume: 10 Issue: 44 Pages: 26418-26424

    • DOI

      10.1039/d0ra04717a

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Catalytic Dehydrogenation of Ethane over Doped Perovskite via the Mars?van Krevelen Mechanism2020

    • Author(s)
      Toko Kenta、Ito Kazuharu、Saito Hikaru、Hosono Yukiko、Murakami Kota、Misaki Satoshi、Higo Takuma、Ogo Shuhei、Tsuneki Hideaki、Maeda Shun、Hashimoto Kunihide、Nakai Hiromi、Sekine Yasushi
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 124 Issue: 19 Pages: 10462-10469

    • DOI

      10.1021/acs.jpcc.0c00138

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of metal cation doping in CeO2 support on catalytic methane steam reforming at low temperature in an electric field2020

    • Author(s)
      Takahashi Ayako、Inagaki Reona、Torimoto Maki、Hisai Yudai、Matsuda Taku、Ma Quanbao、Seo Jeong Gil、Higo Takuma、Tsuneki Hideaki、Ogo Shuhei、Norby Truls、Sekine Yasushi
    • Journal Title

      RSC Advances

      Volume: 10 Issue: 25 Pages: 14487-14492

    • DOI

      10.1039/d0ra01721c

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Heteroatom doping effects on interaction of H2O and CeO2 (111) surfaces studied using density functional theory: Key roles of ionic radius and dispersion2020

    • Author(s)
      Murakami Kota、Ogo Shuhei、Ishikawa Atsushi、Takeno Yuna、Higo Takuma、Tsuneki Hideaki、Nakai Hiromi、Sekine Yasushi
    • Journal Title

      The Journal of Chemical Physics

      Volume: 152 Issue: 1 Pages: 014707-014707

    • DOI

      10.1063/1.5138670

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Low Temperature Hydrogen Production by Ethanol Steam Reforming over Supported Metal Catalysts in an Electric Field2019

    • Author(s)
      OGO Shuhei、SEKINE Yasushi
    • Journal Title

      Journal of the Japan Petroleum Institute

      Volume: 62 Issue: 6 Pages: 264-271

    • DOI

      10.1627/jpi.62.264

    • NAID

      130007740847

    • ISSN
      1346-8804, 1349-273X
    • Year and Date
      2019-11-01
    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Dehydrogenation of Ethane via the Mars?van Krevelen Mechanism over La0.8Ba0.2MnO3?δ Perovskites under Anaerobic Conditions2019

    • Author(s)
      Saito Hikaru、Seki Hirofumi、Hosono Yukiko、Higo Takuma、Seo Jeong Gil、Maeda Shun、Hashimoto Kunihide、Ogo Shuhei、Sekine Yasushi
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 123 Issue: 43 Pages: 26272-26281

    • DOI

      10.1021/acs.jpcc.9b06475

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Electric Field and Mobile Oxygen Promote Low-Temperature Oxidative Coupling of Methane over La1?xCaxAlO3?δ Perovskite Catalysts2019

    • Author(s)
      Sato Ayaka、Ogo Shuhei、Takeno Yuna、Takise Kent、Seo Jeong Gil、Sekine Yasushi
    • Journal Title

      ACS Omega

      Volume: 4 Issue: 6 Pages: 10438-10443

    • DOI

      10.1021/acsomega.9b00594

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] 天然ガス・バイオマスからの水素・低級オレフィン生成のための低温触媒反応場の研究2019

    • Author(s)
      小河 脩平
    • Journal Title

      ペトロテック

      Volume: 42 Pages: 651-655

    • NAID

      130007684316

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Steam reforming of aromatic hydrocarbon at low temperature in electric field2019

    • Author(s)
      Takise Kent、Sato Ayaka、Muraguchi Keisuke、Ogo Shuhei、Sekine Yasushi
    • Journal Title

      Applied Catalysis A: General

      Volume: 573 Pages: 56-63

    • DOI

      10.1016/j.apcata.2019.01.011

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] 電場触媒反応による低温での天然ガスからのエチレン合成とその場観察レーザーラマン分光による触媒構造歪み評価2019

    • Author(s)
      小河脩平,関根 泰
    • Journal Title

      Jasco Report

      Volume: 61 Pages: 20-23

    • NAID

      40021787410

    • Related Report
      2018 Research-status Report
  • [Presentation] 未利用資源有効利用のための低温触媒反応の研究2021

    • Author(s)
      小河脩平
    • Organizer
      アカデミアセミナー in 高知大学
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Catalytic methane conversions at low-temperature in electric field2021

    • Author(s)
      Shuhei Ogo
    • Organizer
      ICAT International Symposium on Electric Field Assisted Heterogeneous Catalysis and Alloy Catalysis
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 電場印加による電子・酸化物イオンの能動的制御と低温触媒反応2020

    • Author(s)
      小河脩平
    • Organizer
      2020日本化学会中国四国支部大会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] メタン直接転換のための低温触媒反応場2020

    • Author(s)
      小河脩平
    • Organizer
      高知化学シンポジウム2020
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] 天然ガス・バイオマスからの水素・低級オレフィン生成のための低温触媒反応場の研究2019

    • Author(s)
      ○小河脩平
    • Organizer
      石油学会第68回研究発表会
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] 電場印加触媒反応を用いた水からの水素生成2019

    • Author(s)
      ○牧浦淳一郎,黒澤佑太郎,荻野健太郎,比護拓馬,小河脩平,関根 泰
    • Organizer
      第49回石油・石油化学討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] 未利用資源有効利用のための高性能触媒の開発2018

    • Author(s)
      小河脩平
    • Organizer
      第6回元素戦略に基づいた触媒設計シンポジウム
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] 電場触媒反応を用いた酸化還元による水分解2018

    • Author(s)
      ○黒澤佑太郎,荻野健太郎,小河脩平,矢部智宏,近藤和吉,加納一彦,小島邦裕,関根 泰
    • Organizer
      第122回触媒討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] Low temperature hydrogen production by water splitting using redox reaction in electric field2018

    • Author(s)
      ○Yutaro Kurosawa, Kentaro Ogino, Shuhei Ogo, Tomohiro Yabe, Wakichi Kondo, Kazuhiko Kano, Kunihiro Kojima, Yasushi Sekine
    • Organizer
      TOCAT8
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Remarks] 個人研究成果発信用HP

    • URL

      http://www.cc.kochi-u.ac.jp/~ogo/

    • Related Report
      2020 Annual Research Report 2019 Research-status Report
  • [Remarks] 個人研究成果発信用HP

    • URL

      http://www.aoni.waseda.jp/ogo/

    • Related Report
      2018 Research-status Report
  • [Patent(Industrial Property Rights)] 触媒体および燃料改質装置2018

    • Inventor(s)
      小島邦裕, 近藤和吉, 加納一彦, 関根泰, 小河脩平,他3名
    • Industrial Property Rights Holder
      小島邦裕, 近藤和吉, 加納一彦, 関根泰, 小河脩平,他3名
    • Industrial Property Rights Type
      特許
    • Filing Date
      2018
    • Acquisition Date
      2019
    • Related Report
      2019 Research-status Report
    • Overseas

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Published: 2018-04-23   Modified: 2022-01-27  

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