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Investigation of electrokinetics at flowing water on doped graphene

Research Project

Project/Area Number 18K04880
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 28030:Nanomaterials-related
Research InstitutionTohoku University

Principal Investigator

OKADA Takeru  東北大学, 工学研究科, 准教授 (90616385)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2020: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2019: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2018: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywordsグラフェン / 固液界面 / 発電 / 動電 / 界面動電 / 流体 / 摩擦帯電 / 液滴流動 / エネルギーハーベスティング
Outline of Final Research Achievements

Liquid-flow-induced electricity generation from graphene-water interface has received attention for novel energy harvesting. In this research, we have obtained electricity generation from a single water droplet motion on graphene, and investigated the effect of the graphene surface condition on the electricity generation, which is controlled by heteroatom doping. As a result, nitrogen-doped graphene shows 3 times higher voltage generation compared to pristine graphene due to the doping-induced surface charging.The surface potential tuning is shown to play an important role. Furthermore, to investigate the mechanism and quantification of power density, we have fabricated micro-flow-chip which induces controlled-flow. The output performance per unit contact area between water and graphene is found to be proportional to the flow speed, with an electromotive force density of 0.0025 microvolt. The ability to quantify output density will help to construct guidelines for future applications.

Academic Significance and Societal Importance of the Research Achievements

本研究では新たなエネルギー創成デバイスとして水の流動と2次元材料であるグラフェン界面における発電について研究を行った。本研究によって発電量を増大させるためにはグラフェンへの窒素ドーピングが有効であることがわかった。また、制御された流れをつくることができるマイクロ流路を用いることでグラフェン-水界面の発電システムとして等価回路を規定し、起電力は流速と界面接触面積に依存することを明らかした。本研究の成果は、力学的変換を伴わない新たなエネルギー創成を提案するものであり、将来構想の一つであるトリリオンセンサーユニバースにおいて重要な知見をもたらすものである。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (19 results)

All 2020 2019 2018 Other

All Int'l Joint Research (5 results) Journal Article (6 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 6 results,  Open Access: 1 results) Presentation (8 results) (of which Int'l Joint Research: 7 results,  Invited: 2 results)

  • [Int'l Joint Research] University of Washington/NASA Ames Research Center(米国)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] Kyung Hee University(韓国)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] NASA/University of Washington(米国)

    • Related Report
      2019 Research-status Report
  • [Int'l Joint Research] Kyung Hee University(韓国)

    • Related Report
      2019 Research-status Report
  • [Int'l Joint Research] NASA, Ames Research Center/University of Washington(米国)

    • Related Report
      2018 Research-status Report
  • [Journal Article] Output density quantification of electricity generation by flowing deionized water on graphene2020

    • Author(s)
      Kuriya Kei、Ochiai Kotaro、Kalita Golap、Tanemura Masaki、Komiya Atsuki、Kikugawa Gota、Ohara Taku、Yamashita Ichiro、Ohuchi Fumio S.、Meyyappan M.、Samukawa Seiji、Washio Katsuyoshi、Okada Takeru
    • Journal Title

      Applied Physics Letters

      Volume: 117 Issue: 12 Pages: 123905-123905

    • DOI

      10.1063/5.0018862

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Neutral Beam Aided Surface Modification for Controlling Triboelectric Behavior2020

    • Author(s)
      Kim Wook、Okada Takeru、Samukawa Seiji、Choi Dukhyun
    • Journal Title

      Proceedings of the Seventh Asia International Symposium on Mechatronics

      Volume: 722 Pages: 346-350

    • DOI

      10.1007/978-981-32-9437-0_38

    • ISBN
      9789813294363, 9789813294370
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Surface modification of triboelectric materials by neutral beams2019

    • Author(s)
      Kim Wook、Okada Takeru、Park Hyun-Woo、Kim Jihye、Kim Sungsoo、Kim Sang-Woo、Samukawa Seiji、Choi Dukhyun
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 7 Issue: 43 Pages: 25066-25077

    • DOI

      10.1039/c9ta09990e

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effects of nitrogen-dopant bonding states on liquid-flow-induced electricity generation of graphene: A comparative study2019

    • Author(s)
      Okada Takeru、Kalita Golap、Tanemura Masaki、Yamashita Ichiro、Ouchi Fumio S.、Meyyappan M.、Samukawa Seiji
    • Journal Title

      Results in Physics

      Volume: 12 Pages: 1291-1293

    • DOI

      10.1016/j.rinp.2019.01.023

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Nitrogen doping effect on flow-induced voltage generation from graphene-water interface2018

    • Author(s)
      Okada Takeru、Kalita Golap、Tanemura Masaki、Yamashita Ichiro、Meyyappan M.、Samukawa Seiji
    • Journal Title

      Applied Physics Letters

      Volume: 112 Issue: 2

    • DOI

      10.1063/1.5007273

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Role of Doped Nitrogen in Graphene for Flow-Induced Power Generation2018

    • Author(s)
      Okada Takeru、Kalita Golap、Tanemura Masaki、Yamashita Ichiro、Meyyappan M.、Samukawa Seiji
    • Journal Title

      Advanced Engineering Materials

      Volume: 20 Issue: 11

    • DOI

      10.1002/adem.201800387

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] グラフェン上における液体流動発電の出力密度定量2020

    • Author(s)
      栗谷 京生、落合 耕太朗、Golap Kalita、種村 眞幸、小宮 敦樹、菊川 豪太、小原 拓、山下 一郎、Fumio S. Ohuchi、M. Meyyappan、寒川 誠二、鷲尾 勝由、岡田 健
    • Organizer
      2020年応用物理学東北支部 第75回学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Multiphase Flow and Interfacial Transport Phenomena at Phase and Material Boundaries2019

    • Author(s)
      1.S. Obayashi, S. Samukawa, T. Takagi, H. Wada, T. Okada, Y. Watanabe, M. Hashimoto, T. Iijima, P. Guy, L. Udpa, Y. Hattori, H. Nagai, K. Shimoyama, M. Hirota, A. Yakeno, G. Kikugawa, A. Komiya, S. Takeda, J. Ishimoto, T. Uchimoto, H. Kosukegawa
    • Organizer
      Eighteenth International Symposium on Advanced Fluid Information
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Electrokinetics at the Interface between Graphene and Moving Water Droplet2019

    • Author(s)
      T. Okada, G. Kalita, M. Tanemura, I. Yamashita, F. S. Ohuchi, M. Meyyappan, and S. Samukawa
    • Organizer
      8th International Symposium on Control of Semiconductor Interfaces
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Power Generation from the Interface between Graphene and Flowing Liquid Water2019

    • Author(s)
      T. Okada, G. Kalita, M. Tanemura, I. Yamashita, F. S. Ohuchi, M. Meyyappan, and S. Samukawa
    • Organizer
      32nd International Microprocesses ad Nanotechnology Conference
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Investigation of Nitrogen Doping Effect on Electrokinetics at Graphene-Water Interface2019

    • Author(s)
      T. Okada, G. Kalita, M. Tanemura, I. Yamashita, F. S. Ohuchi, M. Meyyappan, and S. Samukawa
    • Organizer
      Materials Research Society 2019 Fall Meeting & Exhibit
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Electricity generation by water flow on nitrogen-doped graphene2018

    • Author(s)
      T. Okada, G. Kalita, M. Tanemura, I. Yamashita, M. Meyyappan, and S. Samukawa
    • Organizer
      Fifteenth International Conference of Flow Dynamics
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Energy harvesting application of nitrogen-doped graphene2018

    • Author(s)
      T. Okada, G. Kalita, M. Tanemura, I. Yamashita, F.S. Ohuchi, M. Meyyappan, and S. Samukawa
    • Organizer
      12th International WorkShop on New Group IV Semiconductor Nanoelectronics
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Electricity generation from interface between flowing water and graphene2018

    • Author(s)
      T. Okada, G. Kalita, M. Tanemura, I. Yamashita, M. Meyyappan, and S. Samukawa
    • Organizer
      Materials Research Society 2018 Fall Meeting & Exhibit
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research

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Published: 2018-04-23   Modified: 2022-01-27  

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