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Clarification of the mechanism for the shape elongation of embedded nanoparticles

Research Project

Project/Area Number 18K04898
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 28030:Nanomaterials-related
Research InstitutionNational Institute for Materials Science

Principal Investigator

AMEKURA Hiroshi  国立研究開発法人物質・材料研究機構, エネルギー・環境材料研究拠点, 主席研究員 (00354358)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2020: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2019: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2018: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords高速重イオン / ナノ粒子 / 照射誘起楕円変形 / イオンビーム / イオンシェーピング / C60 / クラスターイオン / C60クラスターイオン / 照射誘起楕円化 / C60イオン / 照射誘起変形現象
Outline of Final Research Achievements

This study aimed for the clarification of the mechanism of the shape elongation of embedded nanoparticles induced under swift heavy ion irradiation, and of the fundamental interactions between swift heavy ions and materials. The main results are: (i) we have carried out international collaborations with Australian team on the precise experiments of the small angle X-ray scattering and with Fin team on state-of-the-art numerical calculations. Then we have criticized models proposed for this phenomenon before and have reached the best one ever. (ii) We have demonstrated that this phenomenon, which normally requires ions of several tens MeV or more, is induced under a-few/several MeV C60 ion irradiation. This observation has an impact not only on saving energy, but on the industrialization of the phenomenon. While accelerators generating a hundred MeV ions or more are limited in two or three facilities in Japan, the accelerators generating a few MeV ions are quite many in Japan.

Academic Significance and Societal Importance of the Research Achievements

固体中に分散させた金属ナノ粒子に対してエネルギー数百MeVの高速重イオンビームを当てると全てのナノ粒子が同一方向に伸び、配向度の高い非等方的なナノ光学材料等の製造を実現する有力な手法として注目されている。本研究では同様の現象が数MeVのC60イオン照射でも起こることを明らかにした。これは単なる省エネルギー化技術ということだけではない。百MeV級の高速重イオンを発生できる施設は国内で2,3ヶ所しかないが、数MeVならば国内の多数の一般的加速器で可能である。本現象の産業化へひとつ近づいた。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (51 results)

All 2021 2020 2019 2018 Other

All Int'l Joint Research (13 results) Journal Article (12 results) (of which Int'l Joint Research: 11 results,  Peer Reviewed: 12 results,  Open Access: 4 results) Presentation (23 results) (of which Int'l Joint Research: 12 results,  Invited: 4 results) Book (1 results) Remarks (2 results)

  • [Int'l Joint Research] 山東大学/武漢大学(中国)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] Universite 20 Aout(アルジェリア)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] University of Helsinki(フィンランド)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] CIMAP(フランス)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] Australian National University(オーストラリア)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] Australian National University(オーストラリア)

    • Related Report
      2019 Research-status Report
  • [Int'l Joint Research] University of Helsinki(フィンランド)

    • Related Report
      2019 Research-status Report
  • [Int'l Joint Research] 山東大学/武漢大学(中国)

    • Related Report
      2019 Research-status Report
  • [Int'l Joint Research] Universite 20 Aout 1955(アルジェリア)

    • Related Report
      2019 Research-status Report
  • [Int'l Joint Research] Australian National University(オーストラリア)

    • Related Report
      2018 Research-status Report
  • [Int'l Joint Research] Helsinki University(フィンランド)

    • Related Report
      2018 Research-status Report
  • [Int'l Joint Research] 山東大学/武漢大学(中国)

    • Related Report
      2018 Research-status Report
  • [Int'l Joint Research] Universite 20 Aout(アルジェリア)

    • Related Report
      2018 Research-status Report
  • [Journal Article] Ion tracks in silicon formed by much lower energy deposition than the track formation threshold2021

    • Author(s)
      Amekura H.、Toulemonde M.、Narumi K.、Li R.、Chiba A.、Hirano Y.、Yamada K.、Yamamoto S.、Ishikawa N.、Okubo N.、Saitoh Y.
    • Journal Title

      Scientific Reports

      Volume: 11 Issue: 1

    • DOI

      10.1038/s41598-020-80360-8

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Irradiation Effects of Swift Heavy Ions Detected by Refractive Index Depth Profiling2020

    • Author(s)
      Amekura Hiroshi、Li Rang、Okubo Nariaki、Ishikawa Norito、Chen Feng
    • Journal Title

      Quantum Beam Science

      Volume: 4 Issue: 4 Pages: 39-39

    • DOI

      10.3390/qubs4040039

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] On the mechanism of the shape elongation of embedded nanoparticles2020

    • Author(s)
      Amekura H.、Kluth P.、Mota-Santiago P.、Sahlberg I.、Jantunen V.、Leino A.A.、Vazquez H.、Nordlund K.、Djurabekova F.
    • Journal Title

      Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms

      Volume: 475 Pages: 44-48

    • DOI

      10.1016/j.nimb.2020.04.038

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Swift heavy ion irradiation to non-amorphizable CaF2 and amorphizable Y3Al5O12 (YAG) crystals2020

    • Author(s)
      Amekura H.、Li R.、Okubo N.、Ishikawa N.、Chen F.
    • Journal Title

      Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms

      Volume: 474 Pages: 78-82

    • DOI

      10.1016/j.nimb.2020.04.023

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Control of optical absorption of silica glass by Ag ion implantation and subsequent heavy ion irradiation2020

    • Author(s)
      Yamada Tomoko、Fukuda Kengo、Semboshi Satoshi、Saitoh Yuichi、Amekura Hiroshi、Iwase Akihiro、Hori Fuminobu
    • Journal Title

      Nanotechnology

      Volume: 31 Issue: 45 Pages: 455706-455706

    • DOI

      10.1088/1361-6528/abaadf

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Fused Silica with Embedded 2D‐Like Ag Nanoparticle Monolayer: Tunable Saturable Absorbers by Interparticle Spacing Manipulation2020

    • Author(s)
      Li Rang、Pang Chi、Li Ziqi、Yang Ming、Amekura Hiroshi、Dong Ningning、Wang Jun、Ren Feng、Wu Qiang、Chen Feng
    • Journal Title

      Laser & Photonics Reviews

      Volume: 14 Issue: 2

    • DOI

      10.1002/lpor.201900302

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Matrix-material dependence on the elongation of embedded gold nanoparticles induced by 4 MeV C60 and 200 MeV Xe Ion irradiation2020

    • Author(s)
      Li Rang、Narumi Kazumasa、Chiba Atsuya、Hirano Yoshimi、Tsuya Daiju、Yamamoto Shunya、Saitoh Yuichi、Okubo Nariaki、Ishikawa Norito、Pang Chi、Chen Feng、Amekura Hiroshi
    • Journal Title

      Nanotechnology

      Volume: 31 Issue: 26 Pages: 265606-265606

    • DOI

      10.1088/1361-6528/ab7e70

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] C60 ions of 1 MeV are slow but elongate nanoparticles like swift heavy ions of hundreds MeV2019

    • Author(s)
      Amekura H.、Narumi K.、Chiba A.、Hirano Y.、Yamada K.、Tsuya D.、Yamamoto S.、Okubo N.、Ishikawa N.、Saitoh Y.
    • Journal Title

      Scientific Reports

      Volume: 9 Issue: 1

    • DOI

      10.1038/s41598-019-49645-5

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Copper Nanoparticles Embedded in Lithium Tantalate Crystals for Multi-GHz Lasers2019

    • Author(s)
      Pang Chi、Li Rang、Li Ziqi、Dong Ningning、Amekura Hiroshi、Wang Shixiang、Yu Haohai、Wang Jun、Ren Feng、Ishikawa Norito、Okubo Nariaki、Chen Feng
    • Journal Title

      ACS Applied Nano Materials

      Volume: 2 Issue: 9 Pages: 5871-5877

    • DOI

      10.1021/acsanm.9b01321

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Vaporlike phase of amorphous SiO2 is not a prerequisite for the core/shell ion tracks or ion shaping2018

    • Author(s)
      Amekura H.、Kluth P.、Mota-Santiago P.、Sahlberg I.、Jantunen V.、Leino A. A.、Vazquez H.、Nordlund K.、Djurabekova F.、Okubo N.、Ishikawa N.
    • Journal Title

      Physical Review Materials

      Volume: 2 Issue: 9

    • DOI

      10.1103/physrevmaterials.2.096001

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Swift heavy ion irradiation to ZnO nanoparticles: Steep degradation at low fluences and stable tolerance at high fluences2018

    • Author(s)
      Amekura H.、Okubo N.、Ren F.、Ishikawa N.
    • Journal Title

      Journal of Applied Physics

      Volume: 124 Issue: 14

    • DOI

      10.1063/1.5050080

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ag nanoparticles embedded in Nd:YAG crystals irradiated with tilted beam of 200 MeV Xe ions: optical dichroism correlated to particle reshaping2018

    • Author(s)
      Li Rang、Pang Chi、Amekura Hiro、Ren Feng、Hubner Rene、Zhou Shengqiang、Ishikawa Norito、Okubo Nariaki、Chen Feng
    • Journal Title

      Nanotechnology

      Volume: 29 Issue: 42 Pages: 424001-424001

    • DOI

      10.1088/1361-6528/aad75b

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] イオントラック形成閾値よりもだいぶ低いエネルギー付与でのトラック形成2021

    • Author(s)
      雨倉 宏、鳴海一雅、Rang Li、千葉敦也、平野貴美、山田圭介、山本春也、石川法人、大久保成彰、斎藤勇一
    • Organizer
      日本物理学会2021年年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] MeV C60イオンビーム照射によるナノ粒子の楕円変形2020

    • Author(s)
      雨倉 宏
    • Organizer
      第21回「イオンビームによる表面・界面の解析と改質」特別研究会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Swift heavy ion irradiation to non-amorphizable CaF2 and amorphizable YAG crystals2020

    • Author(s)
      H. Amekura, R. Li, N. Okubo, N. Ishikawa, F. Chen
    • Organizer
      30th Annual Meetings of MRS-Japan
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] YAG(Y3Al5O12)およびCaF2結晶の光透過特性への高速重イオン照射効果2020

    • Author(s)
      雨倉 宏、大久保成彰、石川法人、鳴海一雅、千葉敦也、平野貴美、山田圭介、山本春也、斎藤勇一
    • Organizer
      日本物理学会2020年秋季大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] MeV C60+クラスターイオン照射によるナノ粒子の楕円変形2020

    • Author(s)
      雨倉 宏、鳴海一雅、Rang Li、千葉敦也、平野貴美、山田圭介、山本春也、斎藤勇一
    • Organizer
      高崎サイエンスフェスタ2020
    • Related Report
      2020 Annual Research Report
  • [Presentation] Shape Elongation of Embedded Nanoparticles Induced by MeV C60 Ion Irradiation2020

    • Author(s)
      H. Amekura
    • Organizer
      International Workshop on Radiation Effects of Materials and Devices (REMD-2020)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] MeV C60クラスターイオン照射によるナノ粒子の楕円化II2020

    • Author(s)
      雨倉 宏、鳴海一雅、千葉敦也、平野貴美、山本春也、Rang Li、斎藤勇一
    • Organizer
      日本物理学会2020年年次大会
    • Related Report
      2019 Research-status Report
  • [Presentation] 高速重イオンの代替ビームとしてのMeV C60クラスターイオンビーム2019

    • Author(s)
      雨倉 宏
    • Organizer
      日本学術振興会荷電粒子ビームの工業への応用第132委員会
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] Ion Beam Materials Research in MRS-Japan for Recent Thirty Years2019

    • Author(s)
      H. Amekura, T. Aoki, K. Baba, F. Chen, P.K. Chu, W. Ensinger, D. Ila, H. Itoh, N. Kishimoto, T. Kobayashi, S. Nakao, H. Nishikawa, K. Yasuda
    • Organizer
      日本MRS創立30周年記念特別シンポジウム
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] Core/Shell Track Formation and Nanoparticle Elongation in SiO2 under Swift Heavy Ion Irradiation2019

    • Author(s)
      H. Amekura, P. Kluth, P. Mota, I. Sahlberg, V. Jantunen, A. A. Leino, H. Vazquez, K. Nordlund, F. Djurabekova, N. Okubo, N. Ishikawa
    • Organizer
      20th International Conference on Radiation Effects in Insulators (REI-2019)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Is a Non-Amorphizable Crystal Better for Optical Applications than an Amorphizable Crystal under Swift Heavy Ion Irradiation?2019

    • Author(s)
      H. Amekura, Rang Li, N. Okubo, N. Ishikawa, and Feng Chen
    • Organizer
      23rd International Workshop on Inelastic Ion-Surface Collisions (IISC-23)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Matrix-Material Dependence of the Elongation of Embedded Nanoparticles Induced by 4 MeV C60 Ion Irradiation2019

    • Author(s)
      Rang Li, H. Amekura, K. Narumi, A. Chiba, Y. Hirano, D. Tsuya, S. Yamamoto, Feng Chen, N. Okubo, N. Ishikawa, Y. Saitoh
    • Organizer
      23rd International Workshop on Inelastic Ion-Surface Collisions (IISC-23)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Elongation of Embedded Metal Nanoparticles by MeV C60 Ion Irradiation2019

    • Author(s)
      H. Amekura, K. Narumi, A. Chiba, Y. Hirano, K. Yamada, D. Tsuya, S. Yamamoto, Rang Li, N. Okubo, N. Ishikawa, Y. Saitoh
    • Organizer
      第29回 日本MRS年次大会(国際シンポジウム)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] MeV C60クラスターイオン照射によるナノ粒子の楕円化2019

    • Author(s)
      雨倉 宏、Rang Li、鳴海一雅、千葉敦也、平野貴美、山本春也、斎藤勇一
    • Organizer
      日本物理学会2019年秋季大会
    • Related Report
      2019 Research-status Report
  • [Presentation] MeV C60+クラスターイオンビームによるナノ粒子の楕円変形2019

    • Author(s)
      雨倉 宏、 鳴海一雅 、 千葉敦也、 平野貴美、 Rang Li、山田圭介、山本春也、 斎藤勇一
    • Organizer
      高崎サイエンスフェスタ
    • Related Report
      2019 Research-status Report
  • [Presentation] 高速重イオン照射によるコア・シェル型イオントラックの形成と ナノ粒子の楕円化2019

    • Author(s)
      雨倉 宏, 石川法人, 大久保成彰, P. Kluth, F. Djurabekova, K. Nordlund
    • Organizer
      日本物理学会2019年年次大会
    • Related Report
      2018 Research-status Report
  • [Presentation] A new type of refractive index modification in YAG crystals induced by swift heavy ion irradiation2018

    • Author(s)
      H. Amekura, Rang Li, Feng Chen, N. Okubo, N. Ishikawa
    • Organizer
      10TH INTERNATIONAL SYMPOSIUM ON SWIFT HEAVY IONS IN MATTER & 28TH INTERNATIONAL CONFERENCE ON ATOMIC COLLISIONS IN SOLIDS
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Appearance of a new optical absorption peak around 600 nm in silica glass implanted with energetic Ag ions2018

    • Author(s)
      K. Fukuda, A. Iwase, F. Hori, Y. Saitoh, S. Semboshi, and H. Amekura
    • Organizer
      10TH INTERNATIONAL SYMPOSIUM ON SWIFT HEAVY IONS IN MATTER & 28TH INTERNATIONAL CONFERENCE ON ATOMIC COLLISIONS IN SOLIDS
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] SWIFT HEAVY IONS EFFECT ON THE OPTICAL, ELECTRICAL AND STRUCTURAL PROPERTIES OF CU2ZNSNS2 THIN FILMS2018

    • Author(s)
      M. Khoualed, F.Z. Boutebakh, S. Ghemid, H. Amekura, N. Ishikawa, M.S. Aida, N. Attaf, A. Chettah
    • Organizer
      10TH INTERNATIONAL SYMPOSIUM ON SWIFT HEAVY IONS IN MATTER & 28TH INTERNATIONAL CONFERENCE ON ATOMIC COLLISIONS IN SOLIDS
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 高速重イオン照射による非晶質SiO2への コア/シェル型イオントラックの形成機構2018

    • Author(s)
      雨倉 宏, 石川法人, 大久保成彰
    • Organizer
      日本物理学会2018年秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Formation of Core/Shell Ion Tracks in Amorphous SiO2 under Swift Heavy Ion Irradiation2018

    • Author(s)
      H. Amekura, P. Kluth, P. Mota-Santiago, I. Sahlberg, V. Jantunen, A. A. Leino, H. Vazquez, K. Nordlund, F. Djurabekova, N. Okubo, N. Ishikawa
    • Organizer
      第28回日本MRS年次大会(国際シンポジウム)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Reshaping of Embedded Ag Nanoparticles in Nd:YAG Crystal by Swift Heavy Ion Irradiation2018

    • Author(s)
      R. Li, H. Amekura, N. Ishikawa, F. Chen
    • Organizer
      第28回日本MRS年次大会(国際シンポジウム)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] X-ray diffraction and thermal spike model study of damage induced in Cu2ZnSnS2 thin films irradiated with swift heavy ions2018

    • Author(s)
      M. Khoualed, A. Chettah, S. Ghemid, F.Z. Boutebakh, H. Amekura, N. Ishikawa, M.S.Aida, N. Attaf
    • Organizer
      第28回日本MRS年次大会(国際シンポジウム)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Book] Ion Irradiation of Dielectrics for Photonic Applications2020

    • Author(s)
      F. Chen, H. Amekura, Y. Jia
    • Total Pages
      290
    • Publisher
      Springer
    • ISBN
      9789811546075
    • Related Report
      2020 Annual Research Report
  • [Remarks] SAMURAI (NIMS研究者総覧)

    • URL

      http://samurai.nims.go.jp/AMEKURA_Hiroshi-e.html

    • Related Report
      2020 Annual Research Report 2018 Research-status Report
  • [Remarks] NIMS研究者総覧

    • URL

      http://samurai.nims.go.jp/AMEKURA_Hiroshi-e.html

    • Related Report
      2019 Research-status Report

URL: 

Published: 2018-04-23   Modified: 2022-01-27  

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