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Clarification of the growth mechanism of nanorods in a surfactant gel and the synthesis of silver nanorods

Research Project

Project/Area Number 18K04900
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 28030:Nanomaterials-related
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

Takenaka Yoshiko  国立研究開発法人産業技術総合研究所, 材料・化学領域, 主任研究員 (60467454)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2020: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords界面活性剤 / 金ナノロッド / 銀ナノロッド / ゲル / ミセル / ナノ粒子 / 常温プロセス / ナノロッド / 成長メカニズム / ゲル化
Outline of Final Research Achievements

We investigated the growth mechanism of gold nanorods grown in an aqueous surfactant solution. For the elongation of gold nanorods, it is important to sustain the metastable gel phase of surfactant for a long time and to coexist with micellar phase. Although high temperature and pressure were necessary for the growth of long silver nanorods in previous study, by applying the synthesis of gold nanorods to silver, we succeeded to make long silver nanorods with the length of over 1 micrometer under room temperature and pressure. Our silver nanorods also showed an antibacterial ability against E. Coli.

Academic Significance and Societal Importance of the Research Achievements

1マイクロメートルを超える長い金ナノロッドは、光学素子や細胞プローブへの応用が期待されるナノ材料である。申請者らはこれまでに、界面活性剤のゲル中で金ナノロッドが長く成長することを明らかにしていたが、その成長メカニズムは不明であった。今回、成長メカニズムを明らかにすることで、同様の成長法を銀に応用することができ、従来高温条件での合成が一般的だった銀ナノロッドを、常温常圧の条件で1マイクロメートル以上に成長させることが出来た。この結果は、1マイクロメートルを超える長い銀ナノロッド合成の省エネルギー化に、成功したと言えるものである。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (7 results)

All 2019 2018 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (3 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results) Remarks (3 results)

  • [Journal Article] Effect of the Crystallization Process of Surfactant Bilayer Lamellar Structures on the Elongation of High-Aspect-Ratio Gold Nanorods2019

    • Author(s)
      Takamichi Inaba, Yoshiko Takenaka, Youhei Kawabata, and Tadashi Kato
    • Journal Title

      Journal of Physical Chemistry B

      Volume: 123 Issue: 22 Pages: 4776-4783

    • DOI

      10.1021/acs.jpcb.8b10897

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Presentation] High-Aspect-Ratio Gold Nanorods Grow in the Transient Lamellar Structure of Surfactant2019

    • Author(s)
      Yoshiko Takenaka
    • Organizer
      Okinawa Colloids 2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] How does a High-Aspect-Ratio Gold Nanorod Elongate in Surfactant Bilayer Lamellar Structures?2019

    • Author(s)
      Takamichi Inaba, Yoshiko Takenaka, Youhei Kawabata and Tadashi Kato
    • Organizer
      ECIS 2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] 界面活性剤2重膜構造が高アスペクト比金ナノロッドの伸長に果たす役割2018

    • Author(s)
      稲葉尭通、武仲能子、川端庸平、加藤直
    • Organizer
      コロイドおよび界面化学討論会
    • Related Report
      2018 Research-status Report
  • [Remarks] 武仲能子プロフィール

    • URL

      https://sites.google.com/site/takenakayoshikoprofile/home/work

    • Related Report
      2019 Research-status Report
  • [Remarks] 産業技術総合研究所スマート材料グループHP

    • URL

      https://smgriscaist.blogspot.com/

    • Related Report
      2018 Research-status Report
  • [Remarks] 武仲能子HP業績(論文 等)

    • URL

      https://sites.google.com/site/takenakayoshikoprofile/home/work

    • Related Report
      2018 Research-status Report

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Published: 2018-04-23   Modified: 2023-12-25  

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