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Imaging of surface plasmons with a microspot photoelectron microscopy

Research Project

Project/Area Number 18K04942
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 29020:Thin film/surface and interfacial physical properties-related
Research InstitutionOsaka City University (2019-2020)
Keio University (2018)

Principal Investigator

Shibuta Masahiro  大阪市立大学, 大学院工学研究科, 准教授 (70596684)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2020: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2019: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2018: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords表面プラズモンポラリトン / 光電子顕微鏡 / フェムト秒レーザー / プラズモニックデバイス / 半導体ナノ粒子 / 表面プラズモン / フェムト秒ダイナミクス
Outline of Final Research Achievements

Surface plasmon polaritons are non-radiative electromagnetic waves propagating at an interface between metal and dielectric media. To utilize the SPPs for photonics or electronics in the next generation, it is crucial to visualize SPPs with some microscopic method.
In this research, the propagating SPPs has been successfully imaged by combining an advanced pulsed laser source and a photoelectron emission microscopy. Furthermore, it has been demonstrated that the physical properties of SPPs, e.g. propagating SPP velocity, can be precisely characterized by analyzing the images taken with different laser conditions.

Academic Significance and Societal Importance of the Research Achievements

高速情報通信や高効率光電変換 (太陽電池)などの分野においては、SPPの効果を駆使したデバイス (プラズモニックデバイス) 等の設計が不可欠である。本研究で確立したSPPの可視化と精密物性評価の方法論は、より高度なプラズモニックデバイス等の設計指針を得る上で極めて重要な基盤技術であり、当該分野の発展を更に加速させるものである。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (50 results)

All 2021 2020 2019 2018 Other

All Int'l Joint Research (3 results) Journal Article (12 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 12 results,  Open Access: 5 results) Presentation (32 results) (of which Int'l Joint Research: 8 results,  Invited: 4 results) Remarks (3 results)

  • [Int'l Joint Research] Philipps-Universitaet(ドイツ)

    • Related Report
      2019 Research-status Report
  • [Int'l Joint Research] Univ. of Sci. and Technol. of China/Chinese Academy of Sciences(中国)

    • Related Report
      2019 Research-status Report
  • [Int'l Joint Research] カイザーズラウテルン大学(ドイツ)

    • Related Report
      2018 Research-status Report
  • [Journal Article] Confined Hot Electron Relaxation at the Molecular Heterointerface of the Size-Selected Plasmonic Noble Metal Nanocluster and Layered C602021

    • Author(s)
      Shibuta Masahiro、Yamamoto Kazuo、Ohta Tsutomu、Inoue Tomoya、Mizoguchi Kaito、Nakaya Masato、Eguchi Toyoaki、Nakajima Atsushi
    • Journal Title

      ACS Nano

      Volume: 15 Issue: 1 Pages: 1199-1209

    • DOI

      10.1021/acsnano.0c08248

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Interfacial Oxidation of Ta-Encapsulating Si16 Cage Superatoms (Ta@Si16) on Strontium Titanate Substrates2020

    • Author(s)
      Shibuta Masahiro、Takano Ryota、Nakajima Atsushi
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 124 Issue: 51 Pages: 28108-28115

    • DOI

      10.1021/acs.jpcc.0c08813

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Temperature effects on the formation and the relaxation dynamics of metal-organic interface states2020

    • Author(s)
      Stallberg Klaus、Shibuta Masahiro、Hoefer Ulrich
    • Journal Title

      Physical Review B

      Volume: 102 Issue: 12

    • DOI

      10.1103/physrevb.102.121401

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Occupied and Unoccupied Levels of Half-Fluorinated and Perfluorinated Rubrene Thin Films Probed by One- and Two-Photon Photoemission2020

    • Author(s)
      Inoue Tomoya、Shibuta Masahiro、Suzuki Toshiyasu、Nakajima Atsushi
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 124 Issue: 23 Pages: 12409-12416

    • DOI

      10.1021/acs.jpcc.0c01162

    • Related Report
      2020 Annual Research Report 2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Visualization of Surface Plasmons Propagating at the Buried Organic/Metal Interface with Silver Nanocluster Sensitizers2020

    • Author(s)
      Yamagiwa Kana、Shibuta Masahiro、Nakajima Atsushi
    • Journal Title

      ACS Nano

      Volume: 14 Issue: 2 Pages: 2044-2052

    • DOI

      10.1021/acsnano.9b08653

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Highly Dispersive Nearly Free Electron Bands at a 2D-Assembled C60 Monolayer2019

    • Author(s)
      Shibuta Masahiro、Yamamoto Kazuo、Guo Hongli、Zhao Jin、Nakajima Atsushi
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 124 Issue: 1 Pages: 734-741

    • DOI

      10.1021/acs.jpcc.9b10006

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Study on Electron Dynamics at Nanoscale Functional Films2019

    • Author(s)
      Shibuta Masahiro
    • Journal Title

      Molecular Science

      Volume: 13 Issue: 1 Pages: A0105

    • DOI

      10.3175/molsci.13.A0105

    • NAID

      130007696977

    • ISSN
      1881-8404
    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Formation of Highly Ordered Semiconducting Anthracene Monolayer Rigidly Connected to Insulating Alkanethiolate Thin Film2018

    • Author(s)
      Eguchi Toyoaki、Hirata Naoyuki、Shibuta Masahiro、Tsunoyama Hironori、Nakajima Atsushi
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 122 Issue: 45 Pages: 26080-26087

    • DOI

      10.1021/acs.jpcc.8b08907

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Liquid-phase catalysis by single-size palladium nanoclusters supported on strontium titanate: size-specific catalysts for Suzuki?Miyaura coupling2018

    • Author(s)
      Tsunoyama Hironori、Ito Haruchika、Komori Masafumi、Kobayashi Ryota、Shibuta Masahiro、Eguchi Toyoaki、Nakajima Atsushi
    • Journal Title

      Catalysis Science & Technology

      Volume: 8 Issue: 22 Pages: 5827-5834

    • DOI

      10.1039/c8cy01645c

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Nitric oxide oxidation of a Ta encapsulating Si cage nanocluster superatom (Ta@Si16) deposited on an organic substrate; a Si cage collapse indicator2018

    • Author(s)
      Shibuta Masahiro、Niikura Toshiki、Kamoshida Toshiaki、Tsunoyama Hironori、Nakajima Atsushi
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 20 Issue: 41 Pages: 26273-26279

    • DOI

      10.1039/c8cp05580g

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Oxidative reactivity of alkali-like superatoms of group 5 metal-encapsulating Si16 cage nanoclusters2018

    • Author(s)
      Shibuta Masahiro、Kamoshida Toshiaki、Ohta Tsutomu、Tsunoyama Hironori、Nakajima Atsushi
    • Journal Title

      Communications Chemistry

      Volume: 1 Issue: 1 Pages: 50-50

    • DOI

      10.1038/s42004-018-0052-9

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis and Characterization of Metal-Encapsulating Si16 Cage Superatoms2018

    • Author(s)
      Tsunoyama Hironori、Shibuta Masahiro、Nakaya Masato、Eguchi Toyoaki、Nakajima Atsushi
    • Journal Title

      Accounts of Chemical Research

      Volume: 印刷中 Issue: 8 Pages: 1735-1745

    • DOI

      10.1021/acs.accounts.8b00085

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] 気相精密大量合成とソフトランディング法による超原子ナノクラスター集積膜の作製とその電気特性評価2021

    • Author(s)
      横山高穂, 千葉竜弥, 平田直之, 渋田昌弘, 中嶋敦
    • Organizer
      日本化学会第101回春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Occupied and Unoccupied Levels of Half- and Per- Fluorinated Rubrene Thin Films Probed by One- and Two- Photon Photoemission2020

    • Author(s)
      (2)T. Inoue, M. Shibuta, T. Suzuki, A. Nakajima
    • Organizer
      表面・界面スペクトロスコピー2020
    • Related Report
      2020 Annual Research Report
  • [Presentation] 前期5d遷移金属内包シリコンケージナノクラスターの有機表面上における化学的特性の比較2020

    • Author(s)
      (3)寺坂一也, 渋田昌弘, 中嶋敦
    • Organizer
      表面・界面スペクトロスコピー2020
    • Related Report
      2020 Annual Research Report
  • [Presentation] Localized surface plasmonic resonances of size-selected silver nanoclusters (Agn) soft-landed on an organic substrate2020

    • Author(s)
      (4)K. Mizoguchi, T. Inoue, M. Shibuta, A. Nakajima
    • Organizer
      表面・界面スペクトロスコピー2020
    • Related Report
      2020 Annual Research Report
  • [Presentation] 遷移金属内包シリコンケージナノクラスター薄膜の作製と電気伝導機構の解明2020

    • Author(s)
      千葉竜弥, 横山高穂, 平田直之, 渋田昌弘, 角山寛規, 中嶋敦
    • Organizer
      日本化学会第100回春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] 6族金属内包シリコンケージ超原子の表面担持状態における化学特性評価2020

    • Author(s)
      寺坂一也, 鴨志田寿明, 新倉寿希, 渋田昌弘, 角山寛規, 中嶋敦
    • Organizer
      日本化学会第100回春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] 有機基板上にソフトランディングした単一サイズ銀ナノクラスター(Agn)の電子物性評価2020

    • Author(s)
      溝口凱斗, 井上朋也, 渋田昌弘, 中嶋敦
    • Organizer
      日本化学会第100回春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] 遷移金属内包シリコンケージクラスター薄膜の電気伝導特性2020

    • Author(s)
      横山高穂, 千葉竜弥, 平田直之, 角山寛規, 渋田昌弘, 中嶋敦
    • Organizer
      第67回応用物理学会春季学術講演会
    • Related Report
      2019 Research-status Report
  • [Presentation] Fabrication and Electrical Characterization of Metal-Encapsulating Si16 Cage Nanocluster Assembled Thin Films2020

    • Author(s)
      T. Yokoyama, T. Chiba, N. Hirata, H. Tsunoyama, M. Shibuta, A. Nakajima
    • Organizer
      Symposium on Size Selected Clusters
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Highly Dispersive Nearly Free Electron Bands at a 2D-assembled C60 Monolayer2019

    • Author(s)
      M. Shibuta, K. Yamamoto, H. Guo, J. Zhao, A. Nakajima
    • Organizer
      表面・界面スペクトロスコピー2019
    • Related Report
      2019 Research-status Report
  • [Presentation] Chemical Stabilization of Aluminum Superatoms on Controlled Organic Substrates2019

    • Author(s)
      T. Inoue, M. Shibuta, A. Nakajima
    • Organizer
      表面・界面スペクトロスコピー2019
    • Related Report
      2019 Research-status Report
  • [Presentation] 赤外反射吸収分光によるAu(111)表面に修飾した自己組織化単分子膜及び配位子保護金ナノクラスターの構造評価2019

    • Author(s)
      T. Yokoyama, N. Hirata, H. Tsunoyama, T. Eguchi, Y. Negishi, A. Nakajima
    • Organizer
      表面・界面スペクトロスコピー2019
    • Related Report
      2019 Research-status Report
  • [Presentation] 6族金属内包シリコンケージ超原子の表面担持状態における化学特性評価2019

    • Author(s)
      寺坂一也, 鴨志田寿明, 渋田昌弘, 角山寛規, 中嶋敦
    • Organizer
      表面・界面スペクトロスコピー2019
    • Related Report
      2019 Research-status Report
  • [Presentation] Fabrication and Characterization of Metal Encapsulating Si16 Cage Superatom (M@Si16) Heterolayer Film2019

    • Author(s)
      T. Niikura, T. Kamoshida, M. Shibuta, H. Tsunoyama, A. Nakajima
    • Organizer
      表面・界面スペクトロスコピー2019
    • Related Report
      2019 Research-status Report
  • [Presentation] Characterization and optimization of cluster-surface interaction: metal-encapsulating Si16 nanocluster superatoms on organic substrates2019

    • Author(s)
      M. Shibuta
    • Organizer
      The 76th Fujihara Seminar: International Workshop on Designer Nanocluster Materials
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Fabrication and Characterization of M@Si16 Hetero Layer Film2019

    • Author(s)
      T. Niikura, M. Shibuta, H. Tsunoyama, A. Nakajima
    • Organizer
      The 76th Fujihara Seminar: International Workshop on Designer Nanocluster Materials
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Visualization of surface plasmon polaritons propagating at dielectric/metal interfaces by 2P-PEEM2019

    • Author(s)
      M. Shibuta, K. Yamagiwa, A. Nakajima
    • Organizer
      11-th International Symposium on Ultrafast Surface Dynamics
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Charge State Dependence of Oxidative Reactivity for Aluminum Superatoms Deposited on Organic Substrate2019

    • Author(s)
      井上朋也, 渋田昌弘, 角山寛規, 中嶋敦
    • Organizer
      第35回化学反応討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] Visualization of surface plasmons propagating at the buried organic-metal interface2019

    • Author(s)
      M. Shibuta
    • Organizer
      SFB Organics Workshop
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] クラスター表面相互作用の有機分子制御による超原子の酸化反応性2019

    • Author(s)
      鴨志田 寿明, 渋田 昌弘, 太田 努, 角山 寛規, 中嶋 敦
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Research-status Report
  • [Presentation] 表面担持された典型元素ナノクラスター超原子の化学的安定性の評価2019

    • Author(s)
      井上 朋也, 渋田 昌弘, 角山 寛規, 中嶋 敦
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Research-status Report
  • [Presentation] Charge State Dependence of Oxidative Reactivity for Aluminum Superatoms Deposited on Organic Substrate2019

    • Author(s)
      Tomoya Inoue, Masahiro Shibuta, Hironori Tsunoyama, Atsushi Nakajima
    • Organizer
      第35回化学反応討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] Photoexcited electron dynamics at nanoscale functional films studied by 2PPE spectroscopy and microscopy2018

    • Author(s)
      Masahiro Shibuta
    • Organizer
      International Symposium on Spectroscopy and Dynamics at Surface and Interface
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Size evolution and electron dynamics in organic molecular assembly2018

    • Author(s)
      Atsushi Nakajima, Masahiro Shibuta, Toyoaki Eguchi, Hironori Tsunoyama, Naoyuki Hirata
    • Organizer
      第34回化学反応討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] Chemical reaction dynamics of metal-encapsulating silicon cage nanocluster (M@Si16) film2018

    • Author(s)
      Toshiki Niikura, Toshiaki Kamoshida, Masahiro Shibuta, Hironori Tsunoyama, Atsushi Nakajima
    • Organizer
      第34回化学反応討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] Chemical Characterization of Group 3-5 Metals Encapsulating Si16 Cage Nanoclusters on Organic Surfaces2018

    • Author(s)
      Toshiaki Kamoshida, Masahiro Shibuta, Tsutomu Ohta, Hironori Tsunoyama, Atsushi Nakajima
    • Organizer
      Cluster-Surface Interaction workshop 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 時間分解顕微光電子分光による有機ナノ薄膜表面・界面の電子ダイナミクス計測2018

    • Author(s)
      渋田 昌弘
    • Organizer
      第61回 極限コヒーレント光科学セミナー
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] フラーレン基板にソフトランディングした銀ナノクラスターによる2光子励起光電子のプラズモニック増強効果2018

    • Author(s)
      渋田 昌弘,山元 一生,太田 努, 中嶋 敦
    • Organizer
      第12回分子科学討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] Chemical Stability of 3-5 Group Transition Metal-Encapsulating Si16 Cage Nanocluster Superatoms on Organic Molecular Substrates2018

    • Author(s)
      鴨志田 寿明, 渋田昌弘, 太田 努, 角山 寛規, 中嶋 敦
    • Organizer
      第12回分子科学討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] Spectroscopy and Imaging of Photocarriers in Organic Functional Films Probed by Two-Photon Photoemission2018

    • Author(s)
      Masahiro Shibuta
    • Organizer
      9 th Workshop on Advanced Spectroscopy of Organic Materials for Electronic Applications
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Charge State Optimization of Group 3-5 Metals Encapsulating Si16 Cage Superatoms on Organic Surfaces2018

    • Author(s)
      鴨志田 寿明, 渋田昌弘, 太田 努, 角山 寛規, 中嶋 敦
    • Organizer
      表面・界面スペクトロスコピー2018
    • Related Report
      2018 Research-status Report
  • [Presentation] 金属内包シリコンケージナノクラスター(M@Si16)集積薄膜の作製と化学反応特性の解明2018

    • Author(s)
      新倉 寿希, 渋田昌弘, 鴨志田 寿明, 角山 寛規, 中嶋 敦,
    • Organizer
      表面・界面スペクトロスコピー2018
    • Related Report
      2018 Research-status Report
  • [Remarks] 大阪市立大学工学研究科ナノマテリアル工学研究室

    • URL

      http://ocunano.xsrv.jp/

    • Related Report
      2019 Research-status Report
  • [Remarks] 慶應義塾大学理工学部化学科中嶋研究室

    • URL

      http://www.chem.keio.ac.jp/~nakajima-lab/

    • Related Report
      2019 Research-status Report
  • [Remarks] 慶應義塾大学理工学部化学科ナノ物理化学研究室

    • URL

      http://sepia.chem.keio.ac.jp/Nakalab/

    • Related Report
      2018 Research-status Report

URL: 

Published: 2018-04-23   Modified: 2022-01-27  

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