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Development of three-dimensional intermolecular interaction and its application to organic molecular conductors and organic electronic materials

Research Project

Project/Area Number 18K05065
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 32020:Functional solid state chemistry-related
Research InstitutionUniversity of Hyogo

Principal Investigator

Yamada Jun-ichi  兵庫県立大学, 物質理学研究科, 教授 (90191311)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2020: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2019: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2018: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords有機分子性導体 / p型半導体 / ドナー分子 / 三次元的相互作用 / カルコゲン原子 / 重なり積分 / 有機電界効果トランジスタ / 有機π電子ドナー / 分子性導体 / 新しい物性
Outline of Final Research Achievements

The realization of three-dimensional (3D) interaction in organic molecular conductors and p-type semiconductors has not yet been much researched. In this study, we investigated the design and synthesis of new donor molecules with 3D interaction capable of being expected by developing end-to-end interaction induced by chalcogen atoms that are introduced into the terminals of molecule along the molecular long axis, in addition to two-dimensional side-by-side interaction caused by sulfur atoms that are introduced into both sides of the molecule. Our further search was made for conductivity and mobility based on the three-dimensionality.

Academic Significance and Societal Importance of the Research Achievements

有機超伝導体を始めとした分子性導体のドナー成分および有機電界効果トランジスタ(OFET)に用いられているp型半導体の開発研究では,これまで二次元的相互作用の発現が主流であった。本研究では,三次元的相互作用を発現する新しいドナー分子を構築するための合成戦略を打ち出し,弱いながらも三次元的相互作用が示唆されるドナー分子の構築に成功した。この合成戦略に従ってドナー分子の設計・合成をさらに行えば,三次元性に基づく高温有機超伝導体や高性能OFETの開発に繋がることが期待される。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (48 results)

All 2021 2020 2019 2018 Other

All Int'l Joint Research (2 results) Journal Article (14 results) (of which Int'l Joint Research: 8 results,  Peer Reviewed: 14 results,  Open Access: 2 results) Presentation (29 results) (of which Int'l Joint Research: 14 results) Remarks (3 results)

  • [Int'l Joint Research] ロシア科学アカデミー・化学物理問題研究所/ロシア科学アカデミー・固体物理学研究所/モスクワ物理技術研究所(ロシア連邦)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] ノッティンガム・トレント大学(英国)

    • Related Report
      2020 Annual Research Report
  • [Journal Article] Chiral metal down to 4.2 K - a BDH-TTP radical-cation salt with spiroboronate anion B(2-chloromandelate)2-2021

    • Author(s)
      Blundell Toby J.、Brannan Michael、Nishimoto Hiroshi、Kadoya Tomofumi、Yamada Jun-ichi、Akutsu Hiroki、Nakazawa Yasuhiro、Martin Lee
    • Journal Title

      Chemical Communications

      Volume: in press Issue: 44 Pages: 5406-5409

    • DOI

      10.1039/d1cc01441b

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] New Radical Cation Salts Based on BDH-TTP Donor: Two Stable Molecular Metals with a Magnetic [ReF6]2- Anion and a Semiconductor with a [ReO4]- Anion2021

    • Author(s)
      Kushch Nataliya D.、Shilov Gennady V.、Buravov Lev I.、Yagubskii Eduard B.、Zverev Vladimir N.、Canadell Enric、Yamada Jun-ichi
    • Journal Title

      Magnetochemistry

      Volume: 7 Issue: 4 Pages: 54-54

    • DOI

      10.3390/magnetochemistry7040054

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Structures and Conducting Properties of Molecular Conductors Based on Dimethyl-Substituted DTDA-TTP and DTDH-TTP2021

    • Author(s)
      Kinoshita Naoya、Suzuki Kento、bin Alias Mohamad Safuwan、Shirahata Takashi、Misaki Yohji、Yamada Jun-ichi
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 94 Issue: 4 Pages: 1273-1284

    • DOI

      10.1246/bcsj.20200399

    • NAID

      130008037361

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Structures and Physical Properties of Charge-Ordered Organic Conductor β-(MTDT-TTP)2BF42021

    • Author(s)
      Wada Tomoya、Nikaido Shun、Yoshino Harukazu、Yamada Jun-ichi、Kodama Takeshi、Kikuchi Koichi
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 94 Issue: 1 Pages: 164-169

    • DOI

      10.1246/bcsj.20200286

    • NAID

      130007968758

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Two-dimensional radical-cationic Mott insulator based on an electron donor containing neither a tetrathiafulvalene nor tetrathiapentalene skeleton2020

    • Author(s)
      Kadoya Tomofumi、Sugiura Shiori、Tahara Keishiro、Higashino Toshiki、Kubo Kazuya、Sasaki Takahiko、Takimiya Kazuo、Yamada Jun-ichi
    • Journal Title

      CrystEngComm

      Volume: 22 Issue: 36 Pages: 5949-5953

    • DOI

      10.1039/d0ce00878h

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ultrafast Carrier Dynamics in an Organic Superconductor k-(BEDT-TTF)2Cu[N(CN)2]Br by Spectrally Resolved Pump-Probe Spectroscopy2020

    • Author(s)
      S. Tsuchiya, T.Mertelj, D. Mihailovic, J. Yamada, and Y. Toda
    • Journal Title

      J. Supercond. Nov. Magn.

      Volume: ー Issue: 8 Pages: 2299-2303

    • DOI

      10.1007/s10948-019-05382-4

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Steric effect of halogen substitution in an unsymmetrical benzothienobenzothiophene organic semiconductor2020

    • Author(s)
      Kadoya Tomofumi、Mano Shotaro、Hori Aoi、Tahara Keishiro、Sugimoto Kunihisa、Kubo Kazuya、Abe Masaaki、Tajima Hiroyuki、Yamada Jun-ichi
    • Journal Title

      Organic Electronics

      Volume: 78 Pages: 105570-105570

    • DOI

      10.1016/j.orgel.2019.105570

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 分子自由度と結合したモット転移の観測(トピックス)2019

    • Author(s)
      竹原陵介,中田耕平,宮川和也,鹿野田一司,角屋智史,山田順一
    • Journal Title

      固体物理

      Volume: 54(7)

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Energy Conversion and Storage; Catalysis; Optical, Electronic, and Magnetic Properties and Processes; Interfaces; Nanomaterials and Hybrid Materials2019

    • Author(s)
      Kadoya, Tomofumi; Oki, Ryouji; Kiyota, Yasuhiro; Koyama, Yuta; Higashino, Toshiki; Kubo, Kazuya; Mori, Takehiko; Yamada, Jun-ichi
    • Journal Title

      The Journal of Physical Chemistry

      Volume: 123 Issue: 9 Pages: 5216-5221

    • DOI

      10.1021/acs.jpcc.8b10687

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Quantum vortex melting and phase diagram in the layered organic superconductor κ-(BEDT-TTF)2Cu(NCS)22018

    • Author(s)
      S. Uji, Y. Fujii, S. Sugiura, T. Terashima, T. Isono, J. Yamada
    • Journal Title

      Phys. Rev. B

      Volume: 97 Issue: 2

    • DOI

      10.1103/physrevb.97.024505

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structure and Properties of a BEDT-TTF-Based Organic Conductor with a Ferrocene-Based Magnetic Anion Octamethylferrocenedisulfonate2018

    • Author(s)
      Akutsu Hiroki、Hashimoto Ryuichiro、Yamada Jun-ichi、Nakatsuji Shin'ichi、Turner Scott S.、Nakazawa Yasuhiro
    • Journal Title

      European Journal of Inorganic Chemistry

      Volume: 2018 Issue: 27 Pages: 3249-3252

    • DOI

      10.1002/ejic.201800482

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] A new Ni(dmit)2-based organic magnetic charge-transfer salt, (m-PO-CONH-N-methylpyridinium)[Ni(dmit)2]・CH3CN2018

    • Author(s)
      Akutsu Hiroki、Ito Soichi、Kadoya Tomofumi、Yamada Jun-ichi、Nakatsuji Shin'ichi、Turner Scott S.、Nakazawa Yasuhiro
    • Journal Title

      Inorganica Chimica Acta

      Volume: 482 Pages: 654-658

    • DOI

      10.1016/j.ica.2018.07.003

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Fluctuating superconductivity in κ-type organic compounds probed by polarized time-resolved spectroscopy2018

    • Author(s)
      K. Nakagawa, S. Tsuchiya, J. Yamada, Y. Toda
    • Journal Title

      EPL (Europhysics Letters)

      Volume: 122 Issue: 6 Pages: 67003-67003

    • DOI

      10.1209/0295-5075/122/67003

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Mott Transition Coupled to Molecular Motion in a Quasi-Two-Dimensional Organic Material (Editors' Choice)2018

    • Author(s)
      R. Takehara, K. Nakada, K. Miyagawa, T. Kadoya, J. Yamada, K. Kanoda
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 87 Issue: 9 Pages: 094707-094707

    • DOI

      10.7566/jpsj.87.094707

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Presentation] BEDT-BDTに基づくラジカルカチオン塩の構造と物性2020

    • Author(s)
      角屋智史,杉浦栞理,田原圭志朗,東野寿樹,久保和也,佐々木孝彦,瀧宮和男,山田 順一
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] BEDT-BDTの新しいセレン類縁体の合成と有機伝導体への応用2020

    • Author(s)
      宍戸雅治,角屋智史,杉浦栞理,田原圭志朗,東野寿樹,久保和也,佐々木孝彦,瀧宮和男,山田 順一
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] エチル基が置換したπ縮小型 TTPドナーを用いた分子性導体の構造と物性2020

    • Author(s)
      鈴木拳土,木下直哉,白旗崇,山田順一,御崎洋二
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 脱プロトン化した2-フェニルピリジンとビス(アルキルチオ)-TTF-ジチオレン配位子をもつ非対称型金(Ⅲ)錯体の構造相転移2020

    • Author(s)
      荒田園巳,井上智仁,キムユナ,角屋智史,山田順一,久保和也
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 2,2’-ビピリジン誘導体とジチオレン配位子をもつ平面四配位型非対称白金錯体の電子状態と伝導材料への応用2020

    • Author(s)
      弓野瑞季,キムユナ,角屋智史,山田順一,久保和也
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] メチル基が置換したπ縮小型TTPドナーを用いた分子性導体の構造と物性2020

    • Author(s)
      鈴木拳土,木下直哉,白旗崇,山田順一,御崎洋二
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] 非TTF系ドナーを用いた二次元モット絶縁体θ-(BEDT-BDT)PF62020

    • Author(s)
      角屋智史,東野寿樹,杉浦栞理,久保和也,佐々木孝彦,瀧宮和男,山田順一
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] 電荷秩序絶縁体(MTDT-TTP)2Xの構造と物性2020

    • Author(s)
      和田智也,山田順一,兒玉健,菊地耕一
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] A multi pulse optical study on anomalous nonequilibrium polarization dynamics above Tc in organic superconductors2019

    • Author(s)
      S. Tsuchiya, T. Mertelj, D. Mihailovic, J. Yamada, H. Taniguchi, Y. Toda
    • Organizer
      International Conference of Superstripes 2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Electrochromic Properties of Thin Film Devices Based on Unsymmetrical Platinum(II) and Gold(III) Complexes Coordinated by Pyridine and Dithiolene Ligand Derivatives2019

    • Author(s)
      K. Kubo, Y. Kim, A. Hori, C. Tomota, A. Motita, T. Kadoya, S. Noro, N. Tamaoki, T. Nakamura, J. Yamada
    • Organizer
      The 18th International Symposium on Novel Aromatic Compounds (ISNA-18)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] The First BDH-TTP Salts with Magnetic Anion [ReCl4(C2O4)]2-2019

    • Author(s)
      A. V. Kazakova, L. I. Buravov, L. V. Zorina, S. V. Simonov, J. Yamada, E. B. Yagubskii
    • Organizer
      13th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM 2019)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Crystal Structures and Physical Properties of Unsymmetrical [(N-N)Pt(S-S)] Type Complexes with Long Alkyl Groups2019

    • Author(s)
      A. Hori, K. Kubo, T. Kadoya, J-i. Yamada
    • Organizer
      13th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM 2019)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Structural Features of Cation Radical Salts Constructed by Donor-Type Nickel Dithiolene Complexes with Fused Cycloalkane Rings and Their Physical Properties2019

    • Author(s)
      M. Sadahiro, K. Kubo, T. Kadoya, R. Kato, J. Yamada
    • Organizer
      7th Asian Conference on Coordination Chemistry (ACCC7 2019)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Unsymmetrical Platinum Dithiolene Complexes Coordinated by 4,4'-Dinonyl-2,2'-Bipyridine: Concerted Phenomena Between Electronic Absorption and Electrochemical Properties2019

    • Author(s)
      A. Hori, K. Kubo, Y. Kim, T. Kadoya, J. Yamada
    • Organizer
      The 20th RIES-HOKUDAI International Symposium
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] κ型有機超伝導体のTc以上で現れる特異的偏光応答のスペクトル分解特性2019

    • Author(s)
      中川紘一,佐藤貴裕,土屋聡,山田順一,戸田泰則
    • Organizer
      日本物理学会2019年秋季大会
    • Related Report
      2019 Research-status Report
  • [Presentation] 非対称ジチオレン金属錯体が発現する可視光・近赤外領域における協奏的エレクトロクロミック挙動の解明2019

    • Author(s)
      堀葵,久保和也,キムユナ,角屋智史,田原圭志朗,玉置信之,中村貴義,山田順一
    • Organizer
      第13回分子科学討論会2019名古屋
    • Related Report
      2019 Research-status Report
  • [Presentation] κ-(BEDT-TTF)2Cu[N(CN)2]Brの超伝導状態に対するスペクトル分解ポンププローブ分光2019

    • Author(s)
      土屋聡,Tomaz Mertelj,Dragan Mihailovic,山田順一,戸田泰則
    • Organizer
      日本物理学会第74回年次大会
    • Related Report
      2018 Research-status Report
  • [Presentation] ビピリジンとジチオレン配位子誘導体からなる分極性非対称白金錯体のエレクトロクロミック特性2019

    • Author(s)
      堀葵,久保和也,キムユナ,森田朝子,友田千尋,角屋智史,野呂真一郎,玉置信之,中村貴義,山田順一
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Research-status Report
  • [Presentation] Determination of The Charge Injection Barrier at Organic Semiconductor/Metal Interface Using Accumulated Charge Measurement2018

    • Author(s)
      H. Tajima, T. Kadoya, J. Yamada
    • Organizer
      International Conference on Science and Technology of Synthetic Metals (ICSM 2018)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Determination of charge injection barrier at organic semiconductor/metal interface using accumulated charge measurement2018

    • Author(s)
      H. Tajima, T. Kadoya, J. Yamada
    • Organizer
      43rd International Conference on Coordination Chemistry (ICCC 2018)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Halogen substitution effects on molecular arrangement and transistor properties of asymmetrical benzothienobenzothiophene derivatives2018

    • Author(s)
      T. Kadoya, S. Mano, K. Tahara, K. Sugimoto, K. Kubo, M. Abe, H. Tajima, J. Yamada
    • Organizer
      43rd International Conference on Coordination Chemistry (ICCC 2018)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Development of New Electrochromic Materials Based on Unsymmetrical Platinum Dithiolene Complexes2018

    • Author(s)
      K. Kubo, Y. Kim, A. Morita, T. Kadoya, S. Noro, T. Nakamura, J. Yamada
    • Organizer
      43rd International Conference on Coordination Chemistry (ICCC 2018)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Anisotropic Superconductivity and Dimensional Crossover in Organic Superconductor β-(BDA-TTP)2SbF62018

    • Author(s)
      S. Yasuzuka, H. Koga, Y. Yamamura, K. Saito, S. Uji, T. Terashima, H. Akutsu, J. Yamada
    • Organizer
      43rd International Conference on Coordination Chemistry (ICCC 2018)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Electrochromic Properties of Thin Film Devices Based on Low-Molecular-Weight Unsymmetrical Platinum Dithiolene Complexes2018

    • Author(s)
      K. Kubo, Y. Kim, A. Morita, A. Hori, C. Tomota, T. Kadoya, S. Noro, N. Tamaoki, T. Nakamura, J. Yamada
    • Organizer
      The 8th TOYOTA RIKEN International Workshop on Organic Semiconductors, Conductors, and Electronics
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Anion polarity-induced several novel electronic states in organic conductors2018

    • Author(s)
      H. Akutsu, F. Nishiyama, S. Ito, T. Kadoya, K. Ishihara, J. Yamada, S. Nakatsuji, Y. Nakazawa
    • Organizer
      The 8th TOYOTA RIKEN International Workshop on Organic Semiconductors, Conductors, and Electronics
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Investigation of Transfer Integrals in the Radical-Cationic BTBT-type Semiconductors2018

    • Author(s)
      T. Kadoya, Y. Koyama, R. Oki, Y. Kiyota, T. Higashino, K. Kubo, T. Mori, J. Yamada
    • Organizer
      The 8th TOYOTA RIKEN International Workshop on Organic Semiconductors, Conductors, and Electronics
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] BDH-TTPとその類縁体を用いた有機電界効果トランジスタの作製と特性2018

    • Author(s)
      西本拓史,猪井翔太,角屋智史,久保和也,田島裕之,西川浩之,山田順一
    • Organizer
      第12回分子科学討論会2018福岡
    • Related Report
      2018 Research-status Report
  • [Presentation] 蓄積電荷測定による有機/金属界面の電荷注入障壁測定2018

    • Author(s)
      宮本裕太,谷村利精,大塚理人,角屋智史,山田順一,横松得滋,前中一介,小簑剛,田島裕之
    • Organizer
      第12回分子科学討論会2018福岡
    • Related Report
      2018 Research-status Report
  • [Presentation] π共役系を縮小した新規TTP,DTEDT系導体の合成,構造と物性2018

    • Author(s)
      木下直哉,Mohamad Safuwan bin Alias,白旗崇,山本貴,内藤俊雄,山田順一,御崎洋二
    • Organizer
      2018年日本化学会中国四国支部大会
    • Related Report
      2018 Research-status Report
  • [Remarks] 機能性物質学Ⅱ分野(講座)ホームページ

    • URL

      http://scimw.sci.u-hyogo.ac.jp/material/funct_mat2/index-j.html

    • Related Report
      2020 Annual Research Report
  • [Remarks] 機能性物質学II分野(講座)ホームページ

    • URL

      https://www.sci.u-hyogo.ac.jp/material/funct_mat2/index-j.html

    • Related Report
      2019 Research-status Report
  • [Remarks] 機能性物質学Ⅱ分野(講座)ホームページ

    • URL

      http://www.sci.u-hyogo.ac.jp/material/funct_mat2/index-j.html

    • Related Report
      2018 Research-status Report

URL: 

Published: 2018-04-23   Modified: 2022-01-27  

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