| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2020: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
|
|---|
| Outline of Final Research Achievements |
We have developed inclusion methods with high selectivity and wide guest scope for organic molecules and rare metals by controlling the guest recognition space of molecular crystals of cyclic host molecules, calixarene (CA) and cyclodextrin (CD) using chemical modifications and third components. Notable achievements include 1) expansion of guest-scope and selective inclusion of alkane isomers by salt crystal formation of thiacalixarene with diethylamine, 2) enantioselective inclusion of amino acids with CD crystals in the presence of bulky sulfonic acid, 3) selective collection of lanthanide ions with the crystals of tetramethylammonium salt of calixarene diphosphonic acid.
|
