Development of Chiral Carbazole-Based Porphyrins
| Project/Area Number |
18K05083
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Review Section |
Basic Section 33010:Structural organic chemistry and physical organic chemistry-related
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| Research Institution | Okayama University |
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Principal Investigator |
Maeda Chihiro 岡山大学, 自然科学学域, 助教 (80581371)
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| Project Period (FY) |
2018-04-01 – 2022-03-31
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| Project Status |
Completed (Fiscal Year 2021)
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| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2020: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2019: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2018: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | ポルフィリン / カルバゾール / 近赤外吸収 / BODIPY / 固体発光 / 円二色性 / 円偏光発光 / ヘリセン / キロプティカル特性 |
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| Outline of Final Research Achievements |
Porphyrins attract considerable attentions in various fields such as photochemistry, electrochemistry, and supramolecular chemistry. We have developed carbazole-based porphyrins and BODIPY analogues which showed interesting electronic properties because they have large pi-conjugated-system. In this research, we have synthesized chiral carbazole-based porphyrins and BODIPY analogues, and the chiroptical properties were investigated.
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| Academic Significance and Societal Importance of the Research Achievements |
我々はカルバゾール骨格を組み込んだキラルな新規ポルフィリンやBODIPY類縁体の合成およびキラル光学特性の評価を行った。本研究で達成した近赤外領域でのコットン効果や固体円偏光発光に関する研究例は限られていた。また優れたキラル光学特性が期待される新規含窒素ヘリセンの開発にも成功した。本研究で得られた新しい知見は、我々だけでなく他の研究者の今後の研究にも貢献すると期待される。
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Report
(5 results)
Research Products
(29 results)
