| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2020: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2019: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2018: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Outline of Final Research Achievements |
In this study, a method for the synthecic of ionic supramolecular metal complexes by using hydrogen bonds was developed. By combining cationic metal complexes with biguanide groups as hydrogen bond donors and anionic metal complexes with carboxylate groups as hydrogen bond acceptors, ionic supramolecular metal complexes with large cavities were successfully synthesized. It is noted that the structures are stable inspite of the high porosity structure that is linked by hydrogen bonds. Using the same hydrogen bonding motifs, the ionic complexes by the combination of metal complex cations and organic anions were also obtained. Furthermore, the structural conversions controlled by the hydrogen bonds were achieved.
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