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Development of Miniaturized Separation/Extraction Media with Braided Filaments

Research Project

Project/Area Number 18K05169
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 34020:Analytical chemistry-related
Research InstitutionToyohashi University of Technology

Principal Investigator

SAITO Yoshihiro  豊橋技術科学大学, 工学(系)研究科(研究院), 教授 (00303701)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2020: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2019: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2018: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords組紐 / 細繊維 / 試料前処理 / 分離カラム / 二次元クロマトグラフィー
Outline of Final Research Achievements

In this work, novel extraction/separation media on the basis of braided filaments of heat-resistant polymeric materials for sample preparation and chromatographic separations have been studied. Introducing several bundles of the filaments, various types of braids have been prepared, where other types of fibrous materials and metal wire could be inserted therein. A successful preparation of these novel extraction/separation media was confirmed, especially the resistive heating of the extraction capillary could be regarded as one of the promising approaches to the development of new miniaturized extraction technique in separation science.

Academic Significance and Societal Importance of the Research Achievements

本研究では、日本の伝統技術のひとつである組紐に注目し、近年開発された超高強度の合成細繊維を、組紐構造状に配置することにより、性能においても、その内部構造においても新規な分離・抽出媒体を作製している。また、組紐内部に通電可能な導電性の金属ワイヤー等を組み込んで、通電による抵抗加熱を達成し、微量分析に応用するために必要な分離カラム充填剤・抽出媒体としての基本性能の向上を確認している。従って、本研究成果は、学術的にも顕著な新規性を有するばかりでなく、二次元クロマトグラフィーなど分離分析分野の関連技術への応用可能性も含めた社会的意義の大きい技術であると考えらえる。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (44 results)

All 2021 2020 2019 2018

All Journal Article (16 results) (of which Peer Reviewed: 16 results,  Open Access: 15 results) Presentation (24 results) (of which Int'l Joint Research: 4 results,  Invited: 3 results) Book (4 results)

  • [Journal Article] Molecular Shape Selectivity for Polycyclic Aromatic Compoundson a Poly(4-vinylpyridine) Stationary Phase in Liquid Chromatography2021

    • Author(s)
      NAKAGAMI Koki、SHIMIZU Keiichi、SUMIYA Ohjiro、UETA Ikuo、SAITO Yoshihiro
    • Journal Title

      CHROMATOGRAPHY

      Volume: 42 Issue: 2 Pages: 91-97

    • DOI

      10.15583/jpchrom.2021.007

    • NAID

      130008061749

    • ISSN
      1342-8284, 1348-3315
    • Year and Date
      2021-06-20
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Extraction of Volatile Anticancer Drugs in Air Using a Solid-Phase Extraction Type Device Followed by Gas Chromatography–Mass Spectrometric Analysis2021

    • Author(s)
      UETA Ikuo、SUMIYA Katsunori、FUJIMURA Koji、YOSHIMURA Tomotaka、KIKUCHI Ryosuke、SAITO Yoshihiro、KAWATA Keishi
    • Journal Title

      Analytical Sciences

      Volume: 37 Issue: 2 Pages: 341-345

    • DOI

      10.2116/analsci.20P311

    • NAID

      130007983501

    • ISSN
      0910-6340, 1348-2246
    • Year and Date
      2021-02-10
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Retention Behavior of Various Aromatic Compounds on Poly(butylene terephthalate) Stationary Phase in Liquid Chromatography2020

    • Author(s)
      NAKAGAMI Koki、AMIYA Misato、SHIMIZU Keiichi、SUMIYA Ohjiro、KOIKE Ryota、UETA Ikuo、SAITO Yoshihiro
    • Journal Title

      CHROMATOGRAPHY

      Volume: 41 Issue: 3 Pages: 129-136

    • DOI

      10.15583/jpchrom.2020.017

    • NAID

      130007933312

    • ISSN
      1342-8284, 1348-3315
    • Year and Date
      2020-10-20
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Carbon Dioxide Laser Supersonic Drawing Nanofiber Sheet for Extraction of Polycyclic Aromatic Hydrocarbons in Water Samples2020

    • Author(s)
      UETA Ikuo、SEKIGUCHI Naho、SUZUKI Akihiro、KOBAYASHI Yuta、KUWABARA Tetsuo、SAITO Yoshihiro
    • Journal Title

      CHROMATOGRAPHY

      Volume: 41 Issue: 2 Pages: 85-89

    • DOI

      10.15583/jpchrom.2020.002

    • NAID

      130007870136

    • ISSN
      1342-8284, 1348-3315
    • Year and Date
      2020-06-20
    • Related Report
      2020 Annual Research Report 2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Titanium Dioxide as a Packing Material for Micro-Packed Column in Gas Chromatography2020

    • Author(s)
      UETA Ikuo、SAKAMOTO Masataka、TANI Kazue、SAITO Yoshihiro
    • Journal Title

      CHROMATOGRAPHY

      Volume: 41 Issue: 2 Pages: 97-101

    • DOI

      10.15583/jpchrom.2020.008

    • NAID

      130007870138

    • ISSN
      1342-8284, 1348-3315
    • Year and Date
      2020-06-20
    • Related Report
      2020 Annual Research Report 2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Polyethylene Terephthalate Nanofiber Sheet as the Novel Extraction Medium for the Determination of Phthalates in Water Samples2020

    • Author(s)
      UETA Ikuo、SEKIGUCHI Naho、SUZUKI Akihiro、KOBAYASHI Yuta、KUWABARA Tetsuo、SAITO Yoshihiro
    • Journal Title

      Analytical Sciences

      Volume: 36 Issue: 2 Pages: 277-281

    • DOI

      10.2116/analsci.19P317

    • NAID

      130007796149

    • ISSN
      0910-6340, 1348-2246
    • Year and Date
      2020-02-10
    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Braid configuration designed for fiber-packed capillary in microscale sample preparation2020

    • Author(s)
      Nakagami Koki、Monobe Tomoya、Sumiya Ohjiro、Takashima Kazunori、Ueta Ikuo、Saito Yoshihiro
    • Journal Title

      Journal of Chromatography A

      Volume: 1613 Pages: 460694-460694

    • DOI

      10.1016/j.chroma.2019.460694

    • Related Report
      2020 Annual Research Report 2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] On-Line Coupling of Gas Chromatography-Gas Chromatography for the Determination of Coumarin in Kerosene2019

    • Author(s)
      NAKAGAMI Koki、SUMIYA Ohjiro、TAKAHASHI Kazuya、KOBAYASHI Akira、UETA Ikuo、SAITO Yoshihiro
    • Journal Title

      CHROMATOGRAPHY

      Volume: 40 Issue: 3 Pages: 135-141

    • DOI

      10.15583/jpchrom.2019.003

    • NAID

      130007741851

    • ISSN
      1342-8284, 1348-3315
    • Year and Date
      2019-10-20
    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Purge-and-trap Determination of Ammonia in Water Samples Using Needle-type Extraction Coupled with Gas Chromatography–Barrier Discharge Ionization Detection2019

    • Author(s)
      UETA Ikuo、FUJIKAWA Hiroto、FUJIMURA Koji、SAITO Yoshihiro
    • Journal Title

      Analytical Sciences

      Volume: 35 Issue: 7 Pages: 759-762

    • DOI

      10.2116/analsci.19P016

    • NAID

      130007676979

    • ISSN
      0910-6340, 1348-2246
    • Year and Date
      2019-07-10
    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Purge-and-Trap Extraction with a Miniaturized Extraction Capillary for the Determination of Aqueous Formic Acids in Ion Chromatography2019

    • Author(s)
      UETA, Ikuo; KAJIMOTO, Masayuki and SAITO, Yoshihiro
    • Journal Title

      CHROMATOGRAPHY

      Volume: 40 Issue: 1 Pages: 33-37

    • DOI

      10.15583/jpchrom.2019.001

    • NAID

      130007611601

    • ISSN
      1342-8284, 1348-3315
    • Year and Date
      2019-02-20
    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Spherical Polyimide Particles as a Novel Stationary Phase in Liquid Chromatography2018

    • Author(s)
      SUMIYA, Ohjiro; TAZAWA, Toshiaki; NAKAGAMI, Koki; SHIRAI, Yuki; MORIUCHI, Koji; UETA, Ikuo and SAITO, Yoshihiro
    • Journal Title

      CHROMATOGRAPHY

      Volume: 39 Issue: 3 Pages: 105-111

    • DOI

      10.15583/jpchrom.2018.010

    • NAID

      130007503288

    • ISSN
      1342-8284, 1348-3315
    • Year and Date
      2018-10-20
    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Separation of Triglycerides in Oils and Fats by Comprehensive Two-Dimensional Liquid Chromatography and the Determination of the Fatty Acid Composition in Gas Chromatography2018

    • Author(s)
      T. Sato, Y. Saito, A. Kobayashi, I. Ueta
    • Journal Title

      CHROMATOGRAPHY

      Volume: 39 Issue: 2 Pages: 67-74

    • DOI

      10.15583/jpchrom.2018.004

    • NAID

      130007403280

    • ISSN
      1342-8284, 1348-3315
    • Year and Date
      2018-06-20
    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Simultaneous Derivatization and Extraction of Volatile Amines with Fiber-Packed Needle and Subsequent Analysis in Gas Chromatography2018

    • Author(s)
      K. Nakagami, T. Tazawa, O. Sumiya, I. Ueta, Y. Satio
    • Journal Title

      CHROMATOGRAPHY

      Volume: 39 Issue: 2 Pages: 75-81

    • DOI

      10.15583/jpchrom.2018.005

    • NAID

      130007403283

    • ISSN
      1342-8284, 1348-3315
    • Year and Date
      2018-06-20
    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Polyimide Filaments as a Novel Stationary Phase in Packed-Capillary Gas Chromatography2018

    • Author(s)
      K. Nakagami, O. Sumiya, T. Tazawa, T. Monobe, M. Watanabe, I. Ueta, Y. Saito
    • Journal Title

      CHROMATOGRAPHY

      Volume: 39 Issue: 2 Pages: 91-96

    • DOI

      10.15583/jpchrom.2018.008

    • NAID

      130007403276

    • ISSN
      1342-8284, 1348-3315
    • Year and Date
      2018-06-20
    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Retention Behavior of Polycyclic Aromatic Compounds in a Novel Polymer-Based Stationary Phase Liquid Chromatography2018

    • Author(s)
      SUMIYA, Ohjiro; NAKAGAMI, Koki; KOIKE, Ryota; UETA, Ikuo and SAITO, Yoshihiro
    • Journal Title

      CHROMATOGRAPHY

      Volume: 39 Issue: 2 Pages: 97-103

    • DOI

      10.15583/jpchrom.2018.009

    • NAID

      130007403277

    • ISSN
      1342-8284, 1348-3315
    • Year and Date
      2018-06-20
    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Determination of Volatile Amines Using Needle-Type Extraction Coupled with Gas Chromatography-Barrier Discharge Ionization Detection2018

    • Author(s)
      UETA, Ikuo; NAKAMURA, Yohei; FUJIKAWA, Hiroto; FUJIMURA, Koji and SAITO, Yoshihiro
    • Journal Title

      Chromatographia

      Volume: 82 Issue: 1 Pages: 317-323

    • DOI

      10.1007/s10337-018-3653-7

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] 組紐構造を有する新規試料前処理媒体2020

    • Author(s)
      中神光喜、物部寛也、隅谷王士郎、小池凌太、清水佳一、髙島和則、植田郁生、齊戸美弘
    • Organizer
      第27回クロマトグラフィーシンポジウム
    • Related Report
      2020 Annual Research Report
  • [Presentation] 合成細繊維を組紐状に配列したLC用新規試料前処理媒体2020

    • Author(s)
      中神光喜、隅谷王士郎、清水佳一、小池凌太、植田郁生、齊戸美弘
    • Organizer
      日本分析化学会第69年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 合成細繊維を用いた試料前処理2020

    • Author(s)
      中神光喜、植田郁生、齊戸美弘
    • Organizer
      第31回クロマトグラフィー科学会議
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] チューブ状炭酸マグネシウムを用いた試料前処理2020

    • Author(s)
      小池凌太, 隅谷王士郎, 清水佳一, 中神光喜, 植田郁生, 齊戸美弘
    • Organizer
      第27回クロマトグラフィーシンポジウム
    • Related Report
      2019 Research-status Report
  • [Presentation] 組紐構造を有する新規試料前処理媒体2020

    • Author(s)
      中神光喜, 物部寛也, 隅谷王士郎, 小池凌太, 清水佳一, 髙島和則, 植田郁生, 齊戸美弘
    • Organizer
      第27回クロマトグラフィーシンポジウム
    • Related Report
      2019 Research-status Report
  • [Presentation] Poly(4-vinyl pyridine)固定相を用いたLC における分子形状選択性2020

    • Author(s)
      清水佳一, 中神光喜, 小池凌太, 隅谷王士郎, 植田郁生, 齊戸美弘
    • Organizer
      第27回クロマトグラフィーシンポジウム
    • Related Report
      2019 Research-status Report
  • [Presentation] LCにおけるpyrazine類の特異的保持挙動2020

    • Author(s)
      隅谷王士郎, 大塚 健, 清水佳一, 小池凌太, 中神光喜, 植田郁生, 齊戸美弘
    • Organizer
      第27回クロマトグラフィーシンポジウム
    • Related Report
      2019 Research-status Report
  • [Presentation] 灯油中クマリンの迅速定量法の開発2020

    • Author(s)
      中神光喜, 小林曜, 隅谷王士郎, 高橋和哉, 植田郁生, 齊戸美弘
    • Organizer
      第27回クロマトグラフィーシンポジウム 2020年
    • Related Report
      2019 Research-status Report
  • [Presentation] Poly(butylene terephthalate)固定相を用いた多環芳香族化合物の保持挙動2020

    • Author(s)
      中神光喜, 網谷美里, 隅谷王士郎, 清水佳一, 小池凌太, 植田郁生, 齊戸美弘
    • Organizer
      第27回クロマトグラフィーシンポジウム
    • Related Report
      2019 Research-status Report
  • [Presentation] 繊維充填型試料前処理針を用いた揮発性アミンの抽出および誘導体化2019

    • Author(s)
      中神光喜, 隅谷王士郎, 植田郁生, 齊戸美弘
    • Organizer
      日本分析化学会第68年会
    • Related Report
      2019 Research-status Report
  • [Presentation] Polymer-Coated Fibrous Polyimide as an Extraction Medium in Microscale Sample Preparation and the On-Line Coupling to Liquid Chromatography2019

    • Author(s)
      NAKAGAMI, Koki; SUMIYA, Ohjiro; UETA, Ikuo and SAITO, Yoshihiro
    • Organizer
      49th International Symposium on High Performance Liquid Phase Separations and Related Techniques (HPLC2019 Kyoto)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Retention Behavior of Polycyclic Aromatic Compounds in Polymer-Based Stationary Phases on Liquid Chromatography2019

    • Author(s)
      SUMIYA, Ohjiro; NAKAGAMI, Koki; KOIKE, Ryota; TAZAWA, Toshiaki; UETA, Ikuo and SAITO, Yoshihiro
    • Organizer
      49th International Symposium on High Performance Liquid Phase Separations and Related Techniques (HPLC2019 Kyoto)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] ポリマー被覆ポリイミド繊維を抽出媒体に用いた小型試料前処理2019

    • Author(s)
      中神光喜, 隅谷王士郎, 植田郁生, 齊戸美弘
    • Organizer
      第30回クロマトグラフィー科学会議
    • Related Report
      2019 Research-status Report
  • [Presentation] ポリマーベース固定相を用いたHPLCにおける芳香族化合物の保持挙動2019

    • Author(s)
      隅谷王士郎, 中神光喜, 小池凌太, 田澤寿明, 植田郁生, 齊戸美弘
    • Organizer
      第30回クロマトグラフィー科学会議
    • Related Report
      2019 Research-status Report
  • [Presentation] Miniaturized Sample Preparation Devices with Fibrous Polymeric Extraction Media2018

    • Author(s)
      SAITO, Yoshihiro; NAKAGAMI, Koki; SUMIYA, Ohjiro and UETA, Ikuo
    • Organizer
      2018 Sino-Japanese Joint Symposium on Separation Sciences
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Gas Chromatographic Determination of Volatile Organic Compounds with Needle-Type Extraction Device2018

    • Author(s)
      UETA, Ikuo and SAITO, Yoshihiro
    • Organizer
      2018 China-Japan-Korea symposium on Analytical Chemistry
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 針型試料前処理デバイスを用いた揮発性アミンの抽出・誘導体化およびそのGC分析2018

    • Author(s)
      中神 光喜, 田澤 寿明, 隅谷 王士郎, 植田 郁生, 齊戸 美弘
    • Organizer
      第25回クロマトグラフィーシンポジウム
    • Related Report
      2018 Research-status Report
  • [Presentation] 新規ポリマ-ベース固定相を用いたLCにおける多環芳香族化合物の保持挙動2018

    • Author(s)
      隅谷 王士郎, 中神 光喜, 小池 凌太, 植田 郁生, 齊戸 美弘
    • Organizer
      第25回クロマトグラフィーシンポジウム
    • Related Report
      2018 Research-status Report
  • [Presentation] ポリイミド繊維を固定相に用いたガスクロマトグラフィー2018

    • Author(s)
      中神 光喜, 隅谷 王士郎, 植田 郁生, 齊戸 美弘
    • Organizer
      日本分析化学会第67年会
    • Related Report
      2018 Research-status Report
  • [Presentation] 新規ポリマ-ベース固定相を用いたHPLCにおける多環芳香族化合物の保持挙動2018

    • Author(s)
      隅谷 王士郎, 中神 光喜, 小池 凌太, 植田 郁生, 齊戸 美弘
    • Organizer
      日本分析化学会第67年会
    • Related Report
      2018 Research-status Report
  • [Presentation] 繊維状ポリイミドを固定相に用いたガスクロマトグラフィー2018

    • Author(s)
      中神 光喜, 隅谷 王士郎, 植田 郁生, 齊戸 美弘
    • Organizer
      第49回中化学関係学協会支部連合秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 新規ポリマ-ベース固定相を用いた液体クロマトグラフィーにおける多環芳香族化合物の保持挙動2018

    • Author(s)
      隅谷 王士郎, 中神 光喜, 小池 凌太, 植田 郁生, 齊戸 美弘
    • Organizer
      第49回中化学関係学協会支部連合秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] ポリマー被覆したポリイミド繊維を抽出媒体に用いた試料前処理とLCのオンライン結合2018

    • Author(s)
      中神 光喜, 隅谷 王士郎, 渡部 暢, 植田 郁生, 齊戸 美弘
    • Organizer
      第29回クロマトグラフィー科学会議
    • Related Report
      2018 Research-status Report
  • [Presentation] ポリイミド粒子を固定相に用いた液体クロマトグラフィー2018

    • Author(s)
      隅谷 王士郎, 中神 光喜, 田澤 寿明, 植田 郁生, 齊戸 美弘
    • Organizer
      第29回クロマトグラフィー科学会議
    • Related Report
      2018 Research-status Report
  • [Book] Pure and Functionalized Carbon Based Nanomaterials: Analytical, Biomedical, Civil and Environmental Engineering Applications2020

    • Author(s)
      Yoshihiro SAITO, Koki NAKAGAMI, Ohjiro SUMIYA, Ikuo UETA
    • Total Pages
      382
    • Publisher
      CRC Press
    • ISBN
      9781138491694
    • Related Report
      2020 Annual Research Report
  • [Book] 超微量分析入門2019

    • Author(s)
      井上 満, 植田郁生, 齊戸美弘, 高橋隆子, 深澤亮一, 堀江正一
    • Total Pages
      200
    • Publisher
      オーム社
    • ISBN
      9784274700859
    • Related Report
      2019 Research-status Report
  • [Book] Solid Phase Extraction2019

    • Author(s)
      UETA, Ikuo and SAITO, Yoshihiro
    • Total Pages
      510
    • Publisher
      Elsevier Science B. V.
    • ISBN
      9780128169063
    • Related Report
      2019 Research-status Report
  • [Book] Methods of Therapeutic Drug Monitoring including Pharmacogenetics2019

    • Author(s)
      SAITO, Yoshihiro and NAKAGAMI, Koki
    • Total Pages
      360
    • Publisher
      Elsevier Science B. V.
    • ISBN
      9780444640666
    • Related Report
      2019 Research-status Report

URL: 

Published: 2018-04-23   Modified: 2022-01-27  

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