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Development of ambient ionization mass spectrometry using dark current discharge with argon gas

Research Project

Project/Area Number 18K05179
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 34020:Analytical chemistry-related
Research InstitutionYokohama City University

Principal Investigator

Sekimoto Kanako  横浜市立大学, 生命ナノシステム科学研究科(八景キャンパス), 准教授 (40583399)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2020: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2019: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2018: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords質量分析 / アルゴン / 暗流 / DART(リアルタイム直接分析法) / アンビエントイオン化 / アンビエントイオン化法 / DART(リアルタイム直接分析)法 / アンビエント質量分析 / 非持続放電
Outline of Final Research Achievements

Direct analysis in real time (DART) is one of ambient ionization mass spectrometry. Although DART has been performed with a great amount of success in various fields, use of helium gas and glow discharge (classified with selfsustaining discharge) causes limitations for utility. In this study, a novel ionization technique using argon gas and atmospheric pressure dark current discharge (classified with non-selfsustaining discharge) has been developed. This technique has ionization efficiency and mechanism comparable to those of conventional DART.

Academic Significance and Societal Importance of the Research Achievements

本研究で見出された「暗流励起アルゴン」によるイオン化は,アンビエント質量分析法の1つであるリアルタイム直接分析法(DART)の問題を抜本的に解決する,安価で・低電力で・どこでも継続的に計測できる質量分析法の要素技術を提供するものである.

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (30 results)

All 2020 2019 2018 Other

All Int'l Joint Research (3 results) Journal Article (17 results) (of which Int'l Joint Research: 11 results,  Peer Reviewed: 17 results,  Open Access: 11 results) Presentation (7 results) (of which Int'l Joint Research: 4 results,  Invited: 1 results) Book (1 results) Remarks (2 results)

  • [Int'l Joint Research] 米国立海洋大気庁 地球システム調査研究所/コロラド大学/モンタナ大学(米国)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] コロラド大学/米国立海洋大気庁 地球システム調査研究所/モンタナ大学(米国)

    • Related Report
      2019 Research-status Report
  • [Int'l Joint Research] コロラド大学/米国立海洋大気庁 地球システム調査研究所/モンタナ大学(米国)

    • Related Report
      2018 Research-status Report
  • [Journal Article] Global-Scale Imaging of Volatile Organic Compounds Emitted from Western US Wildfires2020

    • Author(s)
      関本 奏子
    • Journal Title

      Journal of the Mass Spectrometry Society of Japan

      Volume: 68 Issue: 6 Pages: 86-89

    • DOI

      10.5702/massspec.20-107

    • NAID

      130007955845

    • ISSN
      1340-8097, 1880-4225, 1884-3271
    • Year and Date
      2020-12-01
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Modern mass spectrometry in atmospheric sciences: Measurement of volatile organic compounds in the troposphere using proton‐transfer‐reaction mass spectrometry2020

    • Author(s)
      Sekimoto Kanako、Koss Abigail R.
    • Journal Title

      Journal of Mass Spectrometry

      Volume: 56 Issue: 3

    • DOI

      10.1002/jms.4619

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] The nitrogen budget of laboratory-simulated western U.S. wildfires during the FIREX 2016 FireLab study2020

    • Author(s)
      Roberts James M.、Stockwell Chelsea E.、Yokelson Robert J.、de Gouw Joost、Liu Yong、Selimovic Vanessa、Koss Abigail R.、Sekimoto Kanako、Coggon Matthew M.、Yuan Bin、Zarzana Kyle J.、Brown Steven S.、Santin Cristina、Doerr Stefan H.、Warneke Carsten
    • Journal Title

      Atmospheric Chemistry and Physics

      Volume: 20 Pages: 8807-8826

    • DOI

      10.5194/acp-2020-66

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Biomass-burning-derived particles from a wide variety of fuels: Part 2: Effects of photochemical aging on particle optical and chemical properties2020

    • Author(s)
      Cappa Christopher D.、Lim Christopher Y.、Hagan David H.、Coggon Matthew、Koss Abigail、Sekimoto Kanako、de Gouw Joost、Onasch Timothy B.、Warneke Carsten、Kroll Jesse
    • Journal Title

      Atmospheric Chemistry and Physics

      Volume: 20 Pages: 8511-8532

    • DOI

      10.5194/acp-2020-137

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Oxygenated Aromatic Compounds are Important Precursors of Secondary Organic Aerosol in Biomass-Burning Emissions2020

    • Author(s)
      Akherati A.、He Y.、Coggon M.M.、Koss A.R.、Hodshire A.L.、Sekimoto K.、Warneke C.、de Gouw J.、Yee L.、Seinfeld J.H.、Onasch T.B.、Herndon S.C.、Knighton W.B.、Cappa C.D.、Kleeman M.J.、Lim C.Y.、Kroll J.H.、Pierce J.R.、Jathar S.H.
    • Journal Title

      Environmental Science & Technology

      Volume: 54 Issue: 14 Pages: 8568-8579

    • DOI

      10.1021/acs.est.0c01345

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Accurate identification of dimers from a-pinene oxidation using high-resolution collision-induced dissociation mass spectrometry2020

    • Author(s)
      Kanako Sekimoto, Daisuke Fukuyama and Satoshi Inomata
    • Journal Title

      Journal of Mass Spectrometry

      Volume: 55 Issue: 6

    • DOI

      10.1002/jms.4508

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Atmospheric Pressure Dark-Current Argon Discharge Ionization with Comparable Performance to Direct Analysis in Real Time Mass Spectrometry2019

    • Author(s)
      Kanako Sekimoto, Motoshi Sakakura, Hiroshi Hike, Takatomo Kawamukai, Teruhisa Shiota and Mitsuo Takayama
    • Journal Title

      Mass Spectrometry

      Volume: 8 Issue: 1 Pages: A0075-A0075

    • DOI

      10.5702/massspectrometry.A0075

    • NAID

      130007733877

    • ISSN
      2186-5116, 2187-137X
    • Year and Date
      2019-10-25
    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Secondary organic aerosol formation from biomass burning emissions2019

    • Author(s)
      Christopher Y. Lim, David H. Hagan, Christopher D. Cappa, Matthew M. Coggon, Abigail R. Koss, Kanako Sekimoto, Joost de Gouw, Carsten Warneke and Jesse H. Kroll
    • Journal Title

      Atmospheric Chemistry and Physics

      Volume: 19 Issue: 19 Pages: 12797-12809

    • DOI

      10.5194/acp-19-12797-2019

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] OH-chemistry of non-methane organic gases (NMOG) emitted from laboratory and ambient biomass burning smoke: evaluating the influence of furans and oxygenated aromatics on ozone and secondary NMOG formation2019

    • Author(s)
      M.M. Coggon, C.Y. Lim, A.R. Koss, K. Sekimoto, B. Yuan, J.B. Gilman, D. Hagan, V. Selimovic, K.J. Zarzana, S.S. Brown, J.M. Roberts, M. Muller, R.J. Yokelson, A. Wisthaler, J. Krechmer, J. Jimenez, C. Cappa, J.H. Kroll, J. de Gouw and C. Warneke
    • Journal Title

      Atmospheric Chemistry and Physics

      Volume: 19 Issue: 23 Pages: 14875-14899

    • DOI

      10.5194/acp-19-14875-2019

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Intramolecular hydrogen transfer from the alpha-carbon (Ca) and backbone amide nitrogen (Nb) to form c- and y-ions in negative-ion CID of peptide2019

    • Author(s)
      Asaki Kagoshima, Kanako Sekimoto and Mitsuo Takayama
    • Journal Title

      Journal of the American Society for Mass Spectrometry

      Volume: 30 Issue: 9 Pages: 1592-1600

    • DOI

      10.1007/s13361-019-02245-z

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] 大気圧化学イオン化の原理2019

    • Author(s)
      関本 奏子
    • Journal Title

      Journal of Plasma and Fusion Research

      Volume: 6 Pages: 262-266

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] A library of proton-transfer reactions of H3O+ ions used for trace gas detection2019

    • Author(s)
      Demetrios Pagnonins, Kanako Sekimoto and Joost de Gouw
    • Journal Title

      Journal of the American Society for Mass Spectrometry

      Volume: 印刷中

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Primary emissions of glyoxal and methylglyoxal from laboratory measurements of open biomass burning2018

    • Author(s)
      Zarzana Kyle J.、Selimovic Vanessa、Koss Abigail R.、Sekimoto Kanako、Coggon Matthew M.、Yuan Bin、Dub? William P.、Yokelson Robert J.、Warneke Carsten、de Gouw Joost A.、Roberts James M.、Brown Steven S.
    • Journal Title

      Atmospheric Chemistry and Physics

      Volume: 18 Issue: 20 Pages: 15451-15470

    • DOI

      10.5194/acp-18-15451-2018

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] High- and low-temperature pyrolysis profiles describe volatile organic compound emissions from western US wildfire fuels2018

    • Author(s)
      Sekimoto Kanako、Koss Abigail R.、Gilman Jessica B.、Selimovic Vanessa、Coggon Matthew M.、Zarzana Kyle J.、Yuan Bin、Lerner Brian M.、Brown Steven S.、Warneke Carsten、Yokelson Robert J.、Roberts James M.、de Gouw Joost
    • Journal Title

      Atmospheric Chemistry and Physics

      Volume: 18 Issue: 13 Pages: 9263-9281

    • DOI

      10.5194/acp-18-9263-2018

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Ab initio investigations of stable geometries of the atmospheric negative ion NO3-(HNO3)2 and its monohydrate2018

    • Author(s)
      Atsuko Ueda, Yukiumi Kita, Kanako Sekimoto and Masanori Tachikawa
    • Journal Title

      Methods and Applications of Quantum Systems in Chemistry and Physics

      Volume: None Pages: 193-202

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Non-methane organic gas emissions from biomass burning: identification, quantification, and emission factors from PTR-ToF during the FIREX 2016 laboratory experiment2018

    • Author(s)
      A. R. Koss, K. Sekimoto, J. B. Gilman, V. Selimovic, M. M. Coggon, K. J. Zarzana, B. Yuan, B. M. Lerner, S. S. Brown, J. L. Jimenez, J. Krechmer, J. M. Roberts, C. Warneke, R. J. Yokelson and J. de Gouw
    • Journal Title

      Atmospheric Chemistry and Physics

      Volume: 18 Issue: 5 Pages: 3299-3319

    • DOI

      10.5194/acp-18-3299-2018

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Characterization of a catalyst-based conversion technique to measure total particulate nitrogen and organic carbon and comparison to a particle mass measurement instrument2018

    • Author(s)
      Stockwell Chelsea E.、Kupc Agnieszka、Witkowski Bart?omiej、Talukdar Ranajit K.、Liu Yong、Selimovic Vanessa、Zarzana Kyle J.、Sekimoto Kanako、Warneke Carsten、Washenfelder Rebecca A.、Yokelson Robert J.、Middlebrook Ann M.、Roberts James M.
    • Journal Title

      Atmospheric Measurement Techniques

      Volume: 11 Issue: 5 Pages: 2749-2768

    • DOI

      10.5194/amt-11-2749-2018

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Parameterization of volatile organic compound emissions from western US wildfires2020

    • Author(s)
      Kanako Sekimoto, Matthew Coggon, Georgios Gkatzelis and Carsten Warneke
    • Organizer
      AGU Fall Meeting 2020
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Accurate identification of dimers from alpha-pinene oxidation using high-resolution collision-induced dissociation mass spectrometry2020

    • Author(s)
      Kanako Sekimoto, Daisuke Fukuyama and Satoshi Inomata
    • Organizer
      JpGU-AGU Joint Meeting 2020
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 北米西部の山火事で発生する揮発性有機化合物の地球イメージング2020

    • Author(s)
      関本 奏子
    • Organizer
      第68回質量分析総合討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 大気圧負極性コロナ放電によるイオン生成の制御と応用2019

    • Author(s)
      関本 奏子
    • Organizer
      第67回質量分析総合討論会
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] High- and low-temperature pyrolysis profiles describe volatile organic compound emissions from western US wildfire fuels2018

    • Author(s)
      ◯Kanako Sekimoto, Abigail R. Koss, Jessica B. Gilman, Vanessa Selimovic, Matthew M. Coggon, Kyle J. Zarzana, Bin Yuan, Brian M. Lerner, Steven S. Brown, Carsten Warneke, Robert J. Yokelson, James M. Roberts and Joost de Gouw
    • Organizer
      2018 joint 14th iCACGP Quadrennial Symposium and 15th IGAC Science Conference
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Development of a new ambient ionization mass spectrometry using dark current discharge with argon gas2018

    • Author(s)
      Teruhisa Shiota, ◯Kanako Sekimoto, Motoshi Sakakura, Hiroshi Hike, Takatomo Kawamukai, Mitsuo Takayama
    • Organizer
      The 66th ASMS Conference on Mass Spectrometry
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 暗流励起アルゴンを用いたアンビエント質量分析法の開発2018

    • Author(s)
      ◯関本 奏子, 坂倉 幹始,比毛 浩,川向 孝知,塩田 晃久,高山 光男
    • Organizer
      第66回質量分析総合討論会
    • Related Report
      2018 Research-status Report
  • [Book] “Direct Analysis in Real Time”, Ambient Ionization Mass Spectrometry in Life Sciences2019

    • Author(s)
      Kanako Sekimoto
    • Total Pages
      292
    • Publisher
      Elsevier
    • ISBN
      9780128172209
    • Related Report
      2019 Research-status Report
  • [Remarks] 横浜市立大学理学部・関本奏子准教授が、2019年度日本質量分析学会 奨励賞を受賞

    • URL

      https://www.yokohama-cu.ac.jp/news/2019/191021_sekimoto_kanako.html

    • Related Report
      2019 Research-status Report
  • [Remarks] 大気汚染物質を生成する「ホンモノ」と生成しない「ニセモノ」を見分ける

    • Related Report
      2019 Research-status Report

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Published: 2018-04-23   Modified: 2022-01-27  

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