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Mechano/Electro responsive photoluminesecent polymeric composite film

Research Project

Project/Area Number 18K05240
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 35020:Polymer materials-related
Research InstitutionUniversity of Hyogo

Principal Investigator

Kondo Mizuho  兵庫県立大学, 工学研究科, 准教授 (70447564)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2020: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords磨砕応答 / エレクトロクロミズム / 電気化学応答 / 複合化
Outline of Final Research Achievements

In this study, we have investigated the synthesis ofmechanoresponsive dyes with the ability to respond to electriochemical stimuli. The alignment control by the introduction of liquid crystallinity and the functionalization of the thin film by gelation ability were investigated. In addition, it was found that the quaternization of pyridine-terminated mechanoresponsive dyes enabled the formation of dyes that responded to electrical, mechanical, and optical stimuli.

Academic Significance and Societal Importance of the Research Achievements

ゲル化した材料では液晶性を保持できたことに加え,種々の高分子と複合化して加工性の向上と,複合材料の変形に連動した変化が確認できた。これにより重合したイオン液体との複合化による電気応答性の付与が期待できる

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (58 results)

All 2021 2020 2019 2018

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (48 results) (of which Int'l Joint Research: 13 results,  Invited: 4 results) Book (1 results)

  • [Journal Article] Mechano-induced photoluminescence colour change in an alkyltolane-terminated cyanostilbene2021

    • Author(s)
      Mizuho Kondo, Yuya Morita, Jun-ichi Nishida, Kawase Takeshi and Nobuhiro Kawatsuki
    • Journal Title

      CrystEngComm

      Volume: - Issue: 34 Pages: 5869-5869

    • DOI

      10.1039/d1ce00456e

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoinduced Exfoliation of a Polymeric N ‐Benzylideneaniline Liquid‐Crystalline Composite Based on a Photoisomerization‐Triggered Phase Transition2021

    • Author(s)
      Kondo Mizuho、Kojima Daijoro、Ootsuki Naoya、Kawatsuki Nobuhiro
    • Journal Title

      Macromolecular Chemistry and Physics

      Volume: - Issue: 12 Pages: 2100097-2100097

    • DOI

      10.1002/macp.202100097

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanoresponsive Behavior of Rod-like Liquid Crystalline Luminophores on an Alignment Layer2021

    • Author(s)
      Kondo Mizuho、Yamoto Taku、Tada Motoki、Kawatsuki Nobuhiro
    • Journal Title

      Chemistry Letters

      Volume: 50 Issue: 4 Pages: 812-815

    • DOI

      10.1246/cl.200891

    • NAID

      130008025738

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoinduced Reorientation and Photofunctional Control of Liquid Crystalline Copolymers with in Situ-Formed N-Benzylideneaniline Derivative Side Groups2020

    • Author(s)
      Ito Akari、Norisada Yunosuke、Inada Shogo、Kondo Mizuho、Sasaki Tomoyuki、Sakamoto Moritsugu、Ono Hiroshi、Kawatsuki Nobuhiro
    • Journal Title

      Langmuir

      Volume: 37 Issue: 3 Pages: 1164-1172

    • DOI

      10.1021/acs.langmuir.0c03059

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanochromic behavior of side-chain spiropyran polymer films2020

    • Author(s)
      Mizuho Kondo Shu-ichi Hirooka、Yoshiki Keiseuke、Kawatsuki Nobuhiro
    • Journal Title

      proceeding of 2020 27th International Workshop on Active-Matrix Flatpanel Displays and Devices

      Volume: - Pages: 97-98

    • DOI

      10.23919/am-fpd49417.2020.9224499

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermally stable birefringent films from a liquid crystalline polymer having side groups containing N-benzylideneaniline2020

    • Author(s)
      Mizuho Kondo, Toshiki Nishizono, Nobuhiro Kawatsuki
    • Journal Title

      mol.cryst. Liq. Cryst.

      Volume: -

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photomechanical materials driven by photoisomerization or photodimerization2020

    • Author(s)
      Mizuho Kondo
    • Journal Title

      Polymer Journal

      Volume: -

    • NAID

      40022335654

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Controlling the Emergence and Shift Direction of Mechanochromic Luminescence Color of a Pyridine‐Terminated Compound2019

    • Author(s)
      Kondo Mizuho、Yamoto Taku、Miura Seiya、Hashimoto Mayuko、Kitamura Chitoshi、Kawatsuki Nobuhiro
    • Journal Title

      Chemistry - An Asian Journal

      Volume: 14 Issue: 3 Pages: 471-479

    • DOI

      10.1002/asia.201801647

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Hydrogen-Bonded Photoreactive Polymer Liquid Crystal Containing Pyridyl-Terminated N-Benzylideneaniline2018

    • Author(s)
      Kondo Mizuho、Taijiro Kojima、Kawatsuki Nobuhiro
    • Journal Title

      J. Photopolym. Sci. Tech.

      Volume: 31 Pages: 305-309

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Presentation] 多重刺激応答性を有する磨砕応答色素の発色・発光色変化2021

    • Author(s)
      近藤瑞穂
    • Organizer
      近畿化学協会・機能性色素部会。第102回例会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] シッフべースとフェニル安息香酸を側鎖に有する高分子液晶フィルムのハイブリッド光配向2021

    • Author(s)
      植松丈裕・土井ななか・近藤瑞穂・川月喜弘
    • Organizer
      日本化学会春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 光で動くフィルム,動きを色で知るフィルム2021

    • Author(s)
      近藤瑞穂
    • Organizer
      膜工学シンポジウム
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] シッフ塩基とビフェニルカルボン酸を側鎖に有する高分子液晶コポリマーフィルムのハイブリッド光配向2021

    • Author(s)
      植松丈裕・土井ななか・近藤瑞穂・川月喜弘
    • Organizer
      第70回高分子学会年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] In situ 形成したシッフ塩基を末端に有する高分子液晶フィルムの光配向とそのパターン化2021

    • Author(s)
      酒井郁佳・西薗宗輝・近藤瑞穂・川月喜弘
    • Organizer
      第70回高分子学会年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] シッフ塩基を有する高分子液晶フィルムの光配向と光不活性化2021

    • Author(s)
      山口ひなの・伊藤朱里・則定優之介・近藤瑞穂・川月喜弘
    • Organizer
      第70回高分子学会年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 水素結合型N-ベンジリデンアニリン高分子液晶複合体を用いた光剥離型接着剤の繰り返し特性評価2020

    • Author(s)
      宋思佳・近藤瑞穂・川月喜弘
    • Organizer
      第69回高分子学会年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 配向膜フリー液晶セルでの偏光ホログラム形成2020

    • Author(s)
      藤田享平・脇奈穂美・近藤瑞穂・小野浩司・佐々木友之・野田浩平・坂本盛嗣・川月喜弘
    • Organizer
      第69回高分子学会年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 一軸配向したN-ベンジリデンアニリン架橋液晶高分子フィルムの架橋密度による光運動性調査2020

    • Author(s)
      二塚 凜・小寺晃一・近藤瑞穂・深江亮平・ 川月喜弘
    • Organizer
      第66回高分子研究発表会(神戸)
    • Related Report
      2020 Annual Research Report
  • [Presentation] 側鎖に安息香酸とアルデヒドを有する高分子液晶配向フィルムの機能性付与2020

    • Author(s)
      則定優之介・近藤瑞穂・川月喜弘
    • Organizer
      第66回高分子研究発表会(神戸)
    • Related Report
      2020 Annual Research Report
  • [Presentation] 側鎖にスピロピランを有するメカノクロミック高分子フィルムの種々の機械刺激に対する応答性2020

    • Author(s)
      廣岡秀一・今井沙織・近藤瑞穂・川月喜弘
    • Organizer
      第66回高分子研究発表会(神戸)
    • Related Report
      2020 Annual Research Report
  • [Presentation] 多色発光を示す磨砕応答性色素の高分子フィルムを用いた準安定色の固定化2020

    • Author(s)
      森田優也・近藤瑞穂・川月喜弘
    • Organizer
      第66回高分子研究発表会(神戸)
    • Related Report
      2020 Annual Research Report
  • [Presentation] N-ベンジリデンアニリン高分子液晶を用いた光-力変換2020

    • Author(s)
      近藤瑞穂・二塚凜・植松丈裕・宋思佳・深江亮平・川月喜弘
    • Organizer
      第69回高分子学会討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 側鎖にN-ベンジリデンアニリンを有する高分子液晶配向フィルムの光学特性制御2020

    • Author(s)
      西薗宗輝・近藤瑞穂・ 川月喜弘
    • Organizer
      2020年 日本液晶学会 オンライン研究発表会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 架橋密度の異なる一軸配向性N-ベンジリデンアニリン架橋液晶高分子2020

    • Author(s)
      二塚凜・小寺晃一・近藤瑞穂・深江亮平・川月喜弘
    • Organizer
      2020年 日本液晶学会 オンライン研究発表会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 光安定な偏光ホログラムの作製2020

    • Author(s)
      藤田享平・近藤瑞穂・小野浩司・佐々木友之・野田浩平・坂本盛嗣・川月喜弘
    • Organizer
      2020年 日本液晶学会 オンライン研究発表会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 二官能性N-ベンジリデンアニリンを用いた光反応性高分子液晶接着剤2020

    • Author(s)
      近藤瑞穂
    • Organizer
      第6回兵庫県立大学 知の交流シンポジウム2020連携セミナー
    • Related Report
      2020 Annual Research Report
  • [Presentation] Mechanochromic behavior of side-chain spiropyran polymer films2020

    • Author(s)
      Shu-ichi Hirooka Mizuho Kondo Keiseuke Yoshiki and Nobuhiro Kawatsuki
    • Organizer
      0 27th International Workshop on Active-Matrix Flatpanel Displays and Devices (AM-FPD)
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高分子・色素分散高分子を用いた機械刺激応答性表面を有する薄膜2020

    • Author(s)
      近藤瑞穂
    • Organizer
      高分子表面研究会
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] N-ベンジリデンアニリンを側鎖に有する液晶高分子薄膜の配向制御と光学特性変化2020

    • Author(s)
      伊藤 朱里,近藤 瑞穂,川月 喜弘
    • Organizer
      日本化学会 第100春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] 側鎖に N-ベンジリデンアニリンを有する高分子液晶配向フィルムの非光反応化及び異なる N-ベンジリデンアニリンの再形成2020

    • Author(s)
      西薗 宗輝,近藤 瑞穂,川月喜弘,高塚 啓文,酒井 丈也
    • Organizer
      日本化学会 第100春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] 光と力を繋ぐ液晶高分子フィルム2019

    • Author(s)
      近藤瑞穂
    • Organizer
      高分子研究発表会(神戸),
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] N-ベンジリデンアニリン高分子液晶複合体を用いた光剥離接着剤の接着特性評価2019

    • Author(s)
      児島大二郎,近藤瑞穂,松田聡, 川月喜弘
    • Organizer
      第57回日本接着学会年次大会
    • Related Report
      2019 Research-status Report
  • [Presentation] ベンジリデンアニリンを架橋部に有する液晶高分子フィルムの光屈曲挙動2019

    • Author(s)
      山口航,近藤瑞穂,深江亮平,川月喜弘
    • Organizer
      高分子研究発表会(神戸)
    • Related Report
      2019 Research-status Report
  • [Presentation] 一軸配向したN-ベンジリデンアニリン架橋液晶高分子フィルムの光屈曲挙動2019

    • Author(s)
      二塚凜,近藤瑞穂,深江亮平,川月喜弘
    • Organizer
      高分子研究発表会(神戸)
    • Related Report
      2019 Research-status Report
  • [Presentation] 水素結合型N-ベンジリデンアニリン高分子液晶複合体の光相転移挙動と光剥離型接着剤への応用2019

    • Author(s)
      児島大二郎,近藤瑞穂,松田聡,川月喜弘
    • Organizer
      高分子研究発表会(神戸)
    • Related Report
      2019 Research-status Report
  • [Presentation] 安息香酸とフェニルアルデヒド及びフッ素を側鎖に有する液晶性ブロックコポリマーフィルムの光誘起性複屈折パターンの作製2019

    • Author(s)
      伊藤朱里,稲田翔伍,近藤瑞穂,川月喜弘
    • Organizer
      第68回高分子学会年次大会,
    • Related Report
      2019 Research-status Report
  • [Presentation] フッ素を導入したブロック共重合体のインクジェットによる微細な光配向性パターニングフィルムのその場作製2019

    • Author(s)
      西薗宗輝,稲田翔伍,近藤瑞穂,川月 喜弘
    • Organizer
      第68回高分子学会年次大会,
    • Related Report
      2019 Research-status Report
  • [Presentation] 側鎖に異なる光反応基を持つブロックコポリマーの光配向2019

    • Author(s)
      則定優之介,近藤瑞穂,川月喜弘
    • Organizer
      第68回高分子学会年次大会,
    • Related Report
      2019 Research-status Report
  • [Presentation] 側鎖型スピロピラン高分子薄膜の磨砕応答性への影響2019

    • Author(s)
      廣岡秀一,近藤瑞穂,川月喜弘
    • Organizer
      第68回高分子学会年次大会,
    • Related Report
      2019 Research-status Report
  • [Presentation] 安息香酸とその場作製したN-ベンジリデンアニリンを側鎖に有する高分子液晶フィルムの光配向制御2019

    • Author(s)
      伊藤朱里,稲田翔伍,近藤瑞穂,川月喜弘
    • Organizer
      2019年日本液晶学会討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] 液晶性メカノクロミック色素の配向膜による配向制御と角度依存性2019

    • Author(s)
      多田幹生,近藤瑞穂,川月喜弘
    • Organizer
      2019年日本液晶学会討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] 高い熱安定性を有するN-ベンジリデンアニリン高分子液晶の光配向2019

    • Author(s)
      西薗宗輝,近藤瑞穂,川月喜弘
    • Organizer
      2019年日本液晶学会討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] 側鎖に安息香酸とアルデヒドを有する高分子液晶フィルムの複屈折評価2019

    • Author(s)
      則定優之介,近藤瑞穂,川月喜弘
    • Organizer
      第68回高分子討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] 側鎖にスピロピランを有する磨砕/光応答性高分子材料の作製と評価2019

    • Author(s)
      廣岡秀一,近藤瑞穂,川月喜弘
    • Organizer
      第68回高分子討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] Photoinduced bending behavior of uniaxial alighned crosslibnked N-benzylideneaniline liquid crysttaline polymer films2019

    • Author(s)
      Mizuho Kondo,Rin Nizuka,Koichi Kotera,Wataru Yamaguchi,Ryohei Fukae,Nobuhiro Kawatsuki
    • Organizer
      The 23th International Symposium on Advanced Display Materials and Devices (ADMD)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Photoinduced birefringence pattern based on selective induction of photoreactivity with inkjet technology2019

    • Author(s)
      Akari Ito,Shogo Inada,Mizuho Kondo,Nobuhiro Kawatsuki
    • Organizer
      The 23th International Symposium on Advanced Display Materials and Devices (ADMD)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Thermally stable birefringent film using liquid crystalline polymer with N-benzylideneaniline -containing side groups2019

    • Author(s)
      Toshiki Nishizono,Mizuho Kondo,Nobuhiro Kawatsuki
    • Organizer
      The 23th International Symposium on Advanced Display Materials and Devices (ADMD)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Directional mechanochromic luminescent behavior of liquid crystalline luminophore on homeotropic aligned films2019

    • Author(s)
      Motoki Tada
    • Organizer
      The 8th TKU-ECUST-OPU-KIST-UH-IHU-KMITL-UTAR-TNU Joint Symposium on Advanced Materials and Applications (JSAMA-8)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Preparation of uniaxial aligned crosslinked NBA liquid crystalline polymer films by two-step crosslinking method2019

    • Author(s)
      Wataru Yamaguchi
    • Organizer
      The 8th TKU-ECUST-OPU-KIST-UH-IHU-KMITL-UTAR-TNU Joint Symposium on Advanced Materials and Applications (JSAMA-8)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Mechanochormic luminescent behavior of cyanostilbene liquid crystal containing phenylamide or phenylester terminal2019

    • Author(s)
      Mizuho Kondo
    • Organizer
      The 8th TKU-ECUST-OPU-KIST-UH-IHU-KMITL-UTAR-TNU Joint Symposium on Advanced Materials and Applications (JSAMA-8)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Photomechanical effect of uniaxial aligned crosslinked NBA liquid crystalline polymer films2019

    • Author(s)
      Rin Nizuka
    • Organizer
      The 8th TKU-ECUST-OPU-KIST-UH-IHU-KMITL-UTAR-TNU Joint Symposium on Advanced Materials and Applications (JSAMA-8)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Mechanical property of photoexfoliable polymeric adhesion composed adhesion composed of N-benzylideneaniline liquid crystal2019

    • Author(s)
      Daijiro KOJIMA,Mizuho KONDO,Nobuhiro KAWATSUKI
    • Organizer
      The 4th FZU-OPU Joint International Symposium on Photocatalysis, Photofunctional Materials and Nano-Science & Technology
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Mechanoinduced Color change in Side-chain Spiropyran Polymethacrylate2019

    • Author(s)
      Shu-ichi Hirooka,Mizuho Kondo,Nobuhiro Kawatsuki
    • Organizer
      The 4th FZU-OPU Joint International Symposium on Photocatalysis, Photofunctional Materials and Nano-Science & Technology
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Directional Mechanochromic Behavior of Liquid Crystalline Polymeric Composite2019

    • Author(s)
      Mizuho Kondo, Motoki Tada, Nobuhiro Kawatsuki
    • Organizer
      The 4th FZU-OPU Joint International Symposium on Photocatalysis, Photofunctional Materials and Nano-Science & Technology
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Directional Mechanoinduced Color Change Behavior of Liquid Crystalline Luminophore on Photoaligned Layer2018

    • Author(s)
      Mizuho Kondo, Taku Yamoto, Nobuhiro Kawatsuki
    • Organizer
      27th International Liquid Crystal Conference (ILCC2018)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Mechanoinduced change in photoluminescent color of halogen-bonded fluorene complex2018

    • Author(s)
      Ryosuke Ikeuchi, Mizuho Kondo, Nobuhiro Kawatsuki
    • Organizer
      22nd International Symposium on Advanced Display Materials & Devices (ADMD2018)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 分子末端にピリジン環を有するオリゴチオフェンにおける磨砕応答とイオン液体中における発光挙動2018

    • Author(s)
      池内伶介・近藤瑞穂・柿部剛史・岸肇・川月喜弘
    • Organizer
      接着学会第14回関西支部若手の会
    • Related Report
      2018 Research-status Report
  • [Book] 光機能性有機・高分子材料における新たな息吹2019

    • Author(s)
      市村國宏
    • Total Pages
      333
    • Publisher
      シーエムシー出版
    • ISBN
      9784781314143
    • Related Report
      2019 Research-status Report

URL: 

Published: 2018-04-23   Modified: 2022-01-27  

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