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Realization of multiferroics by mesopore-induced lattice distortion and spin-phonon coupling

Research Project

Project/Area Number 18K05279
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 36010:Inorganic compounds and inorganic materials chemistry-related
Research InstitutionTokyo University of Science

Principal Investigator

Suzuki Norihiro  東京理科大学, 研究推進機構総合研究院, 講師 (10595888)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2020: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2019: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2018: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords無機工業化学 / セラミックス / ナノ材料 / 多孔体 / マルチフェロイック / チタン酸ユウロピウム / 歪み / ゾルーゲル法
Outline of Final Research Achievements

Aiming to realizing the multiferroics (i.e., simultaneous occurrence of ferroelectricity and ferromagnetism) by the porosity-derived crystal lattice distortion, a mesoporous EuTiO3 thin film was fabricated by the surfactant-assisted sol-gel method. Mosaic-like lattice distortion was introduced in the crystallized framework, while surface of the framework was amorphalized, which formed the core-shell structure. Unlike antiferromagnetic bulk, synthesized porous thin film showed ferromagnetic behavior. Amorphous surface layer as well as the lattice distortion of EuTiO3 crystal may cause the ferromagnetism.

Academic Significance and Societal Importance of the Research Achievements

多孔体化およびアモルファス化により、バルクとは異なる物性をもたらすという新しいコンセプトを提案することができた。特にアモルファス化が材料物性に対し、ポジティブに働くという希有な例にたどり着くことができた点が、学術的に意義深い。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (2 results)

All 2021 2019

All Presentation (2 results)

  • [Presentation] 多孔性EuTiO3薄膜の作製とマルチフェロイック化への試み2021

    • Author(s)
      鈴木孝宗
    • Organizer
      日本化学会第101春期年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Strain Engineeringのツールとしてのナノ細孔誘起歪み2019

    • Author(s)
      鈴木孝宗
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Research-status Report

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Published: 2018-04-23   Modified: 2022-01-27  

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