| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2020: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2019: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2018: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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| Outline of Final Research Achievements |
We develop a general approach for the formation of continuous MOF crystal films using metal ion-doped substrate through controlling the rates of nucleation and growth. The rates of nucleation and growth of MOF crystals can be controlled by the rates of dissolution of doped metal ions from the substrate and complexation at the interface between the reaction solution and the substrate. By controlling the nucleation and growth rates, the crystal size can be controlled, resulting in the formation of continuous MOF crystal films consisting of size-controlled each crystal. This approach can be applicable not only to various types of MOFs but also to coordination polymers.
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