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Development of thermochemical/photochemical hybrid water splitting process for hydrogen production

Research Project

Project/Area Number 18K05292
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 36020:Energy-related chemistry
Research InstitutionUniversity of Toyama

Principal Investigator

HAGIWARA Hidehisa  富山大学, 学術研究部理学系, 准教授 (30574793)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2020: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords水素 / 水分解 / 光触媒 / 熱化学水素製造
Outline of Final Research Achievements

In order to facilitate the endothermic reaction of the IS process with light energy, we investigated the photocatalytic activity of semiconductor materials for HI decomposition. It was found that Rh-substituted SrTiO3 (SrTiO3:Rh) and Co loaded TiO2 nanosheet photocatalysts showed hydrogen production from HI aqueous solution under Xe lamp irradiation. In the case of SrTiO3:Rh photocatalyst, the loading of the noble metal co-catalysts contributed to hydrogen production, and thus the HI photodegradation activity was improved by loading noble metal co-catalysts. It was also found that the co-catalyst suitable for HI photodegradation is important not only for promoting surface reaction but also for durability against HI aqueous solution.

Academic Significance and Societal Importance of the Research Achievements

地球規模のエネルギー・環境問題を解決するために、再生可能エネルギーと水から、クリーンかつ安価で大量に合成が可能な水素製造法の確立が喫緊の課題となっている。本研究で得られた成果は、水素の生成反応に用いる光触媒の表面触媒に適した貴金属助触媒の条件を明らかにしたものであり、今後の研究の進展によって、太陽光エネルギーの化学エネルギー(水素)への高効率変換の達成に寄与することが期待される。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (19 results)

All 2021 2020 2019 2018 Other

All Journal Article (3 results) (of which Peer Reviewed: 2 results) Presentation (15 results) (of which Int'l Joint Research: 2 results) Remarks (1 results)

  • [Journal Article] Photocatalytic hydrogen production from triethanolamine aqueous solution by LaTa2O7 nanosheets treated with nitrogen plasma2020

    • Author(s)
      H. Hagiwara, K. Hayakawa, I. Nozawa
    • Journal Title

      Annual Report of Hydrogen Isotope Research Center

      Volume: 39 Pages: 1-8

    • Related Report
      2020 Annual Research Report
  • [Journal Article] Hydrogen production by photocatalytic water splitting of aqueous hydrogen iodide over Pt/alkali metal tantalates2019

    • Author(s)
      H. Hagiwara, I. Nozawa, K. Hayakawa, T. Ishihara
    • Journal Title

      Sustainable Energy & Fuels

      Volume: 3 Issue: 11 Pages: 3021-3028

    • DOI

      10.1039/c9se00355j

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic water splitting over Pt-loaded TiO2 (Pt/TiO2) catalysts prepared by the polygonal barrel-sputtering method2019

    • Author(s)
      Matsubara Keisuke、Inoue Mitsuhiro、Hagiwara Hidehisa、Abe Takayuki
    • Journal Title

      Applied Catalysis B: Environmental

      Volume: 254 Pages: 7-14

    • DOI

      10.1016/j.apcatb.2019.04.075

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Presentation] 酸化物ナノシート修飾光触媒による可視光酸素生成反応2021

    • Author(s)
      萩原英久,早川克明
    • Organizer
      第127回触媒討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Co(OH)2修飾酸化チタンナノシートによる可視光酸素生成2020

    • Author(s)
      早川克明,萩原英久
    • Organizer
      触媒学会西日本支部第30回キャラクタリゼーション講習会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Photocatalytic decomposition of HI on transition metal doped SrTiO3 for solar hydrogen production2019

    • Author(s)
      H. Hagiwara, K. Hayakawa, I. Nozawa
    • Organizer
      The 8th Asia Pacific Congress on Catalysis
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] アニオン添加LaSrCoO4の電極触媒特性評価2019

    • Author(s)
      野澤一徳、萩原英久
    • Organizer
      石油学会 第24回JCPDSポスターセッション
    • Related Report
      2019 Research-status Report
  • [Presentation] 多角バレルプラズマ表面改質法で調製した窒素添加LaTa2O7‐ナノシートの光触媒活性評価2019

    • Author(s)
      早川克明,野澤一徳,萩原英久
    • Organizer
      石油学会 第24回JCPDSポスターセッション
    • Related Report
      2019 Research-status Report
  • [Presentation] アニオン添加LaSrCoO4の電極触媒性能評価2019

    • Author(s)
      野澤一徳、萩原英久
    • Organizer
      触媒学会 第124回触媒討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] 多角バレルプラズマ表面改質法で合成した窒素添加酸化物の光触媒活性2019

    • Author(s)
      早川克明、野澤一徳、萩原英久
    • Organizer
      触媒学会 第124回触媒討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] アニオン添加Co系層状ペロブスカイトの電極触媒特性評価2019

    • Author(s)
      野澤一徳、萩原英久
    • Organizer
      触媒学会西日本支部 第29回キャラクタリゼーション講習会
    • Related Report
      2019 Research-status Report
  • [Presentation] N2プラズマ処理したLaTa2O7ナノシートによる光水素生成2019

    • Author(s)
      早川克明、野澤一徳、萩原英久
    • Organizer
      触媒学会西日本支部 第29回キャラクタリゼーション講習会
    • Related Report
      2019 Research-status Report
  • [Presentation] Photocatalytic decomposition of hydrogen iodide on Ta-based oxides for solar hydrogen production2018

    • Author(s)
      Hagiwara Hidehisa、Shoman Minami、Ida Shintaro、Ishihara Tatsumi
    • Organizer
      The 8th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT8)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 可視光応答性光触媒によるヨウ化水素水溶液からの水素生成反応2018

    • Author(s)
      萩原英久、早川克明、正満みなみ
    • Organizer
      第48回石油・石油化学討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] アニオン添加複合金属酸化物の電極触媒特性評価2018

    • Author(s)
      野澤一徳、萩原英久
    • Organizer
      第48回石油・石油化学討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] アニオン添加コバルト系複合金属酸化物の電極触媒特性評価2018

    • Author(s)
      野澤一徳、萩原英久
    • Organizer
      電気化学会東海地区・北陸地区合同シンポジウム
    • Related Report
      2018 Research-status Report
  • [Presentation] アニオンを添加したCo系ペロブスカイト関連化合物の電極触媒特性評価2018

    • Author(s)
      野澤一徳、萩原英久
    • Organizer
      日本化学会近畿支部 北陸地区研究発表会
    • Related Report
      2018 Research-status Report
  • [Presentation] アニオン添加複合金属酸化物の電極触媒活性評価2018

    • Author(s)
      萩原英久、野澤一徳
    • Organizer
      第123回触媒討論会
    • Related Report
      2018 Research-status Report
  • [Remarks] 富山大学 研究推進機構 水素同位体科学研究センター

    • URL

      http://www.hrc.u-toyama.ac.jp/jp/

    • Related Report
      2019 Research-status Report 2018 Research-status Report

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Published: 2018-04-23   Modified: 2022-01-27  

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