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solution-processed oxide solar cells composed of common metals

Research Project

Project/Area Number 18K05310
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 36020:Energy-related chemistry
Research InstitutionOsaka Research Institute of Industrial Science and Technology

Principal Investigator

Tsutomu Shinagawa  地方独立行政法人大阪産業技術研究所, 森之宮センター, 主任研究員 (50416327)

Project Period (FY) 2018-04-01 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2020: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2019: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2018: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords酸化物太陽電池 / 水溶液プロセス / 亜酸化銅
Outline of Final Research Achievements

The objective of this research is to "develop highly efficient oxide solar cells that are expected to be highly versatile and low-cost using the aqueous solution process and base metals." The applicant made full use of the results and knowledge of "oxide formation by the aqueous solution process" and "construction of oxide solar cells" that the applicant has been working on, and worked on two research subjects (1) Improvement of the electrical properties of the Cu2O layer and (2) Development of a new p-type light-absorbing layer. As a result, (1) low-resistivity Cu2O could be formed by the aqueous solution deposition method, but the conversion efficiency of solar cells could not be improved. (2) We searched for weakly acidic aqueous solutions capable of depositing copper-iron oxides, and confirmed the formation of the target materials in the combination of iron sulfate and copper (copper sulfate, copper nitrate, and copper acetate).

Academic Significance and Societal Importance of the Research Achievements

ZnO/Cu2O系太陽電池は、亜鉛や銅といった無毒で大量に入手可能なベースメタルを原料とし、低コストかつ環境フレンドリーな水溶液プロセスで製造可能な「汎用型太陽電池」として注目されている。しかし、実用化には変換効率の向上が大きな課題となっており、本研究では、(1)Cu2O物性の改善、および(2)新規光吸収層開発、という2つのアプローチから、汎用型太陽電池の変換効率向上に資する研究に取り組んだ。

Report

(6 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Research-status Report
  • 2020 Research-status Report
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (7 results)

All 2022 2021 2019 2018 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Open Access: 2 results) Presentation (3 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results) Remarks (1 results)

  • [Journal Article] Template-free formation of oriented oxide nanowalls <i>via</i> topotactic-like pseudomorphic transformation: [110]-MgO(111) nanowall arrays2022

    • Author(s)
      Shinagawa Tsutomu、Izaki Masanobu
    • Journal Title

      Materials Advances

      Volume: 3 Issue: 19 Pages: 7257-7264

    • DOI

      10.1039/d2ma00493c

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Single-Orientation Nanoporous NiO Films: Spontaneous Evolution from Dense Low-Crystalline Ni(OH)<sub><i>x</i></sub> Films2022

    • Author(s)
      Shinagawa Tsutomu、Chigane Masaya、Takahashi Masanari
    • Journal Title

      Crystal Growth &amp; Design

      Volume: - Issue: 7 Pages: 4122-4132

    • DOI

      10.1021/acs.cgd.2c00028

    • Related Report
      2021 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Growth of Mg(OH)x Layered Films Stacked Parallel to the Substrates and Their Thermal Conversion to (111)-Oriented Nanoporous MgO Films2021

    • Author(s)
      Shinagawa Tsutomu、Chigane Masaya、Izaki Masanobu
    • Journal Title

      ACS Omega

      Volume: 6 Issue: 3 Pages: 2312-2317

    • DOI

      10.1021/acsomega.0c05619

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] 配向水酸化マグネシウムの加熱分解によるナノポーラス酸化マグネシウムの形成とCO2吸着特性2021

    • Author(s)
      品川勉、千金正也、伊﨑昌伸
    • Organizer
      表面技術協会144回講演大会
    • Related Report
      2021 Research-status Report
  • [Presentation] Oxide semiconductor-based flexible solar cells prepared on plastic substrates by aqueous-solution processes2019

    • Author(s)
      品川勉、千金正也、伊崎昌伸
    • Organizer
      E-MRS 2019 Fall Meeting
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Fabrication of oriented nanoporous ZnO via solution processes2018

    • Author(s)
      品川 勉
    • Organizer
      EMN-3CG2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Remarks] 大阪産業技術研究所ホームページ

    • URL

      https://orist.jp/kenkyu-bu/denshi-zairyo/sat/

    • Related Report
      2022 Annual Research Report

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Published: 2018-04-23   Modified: 2024-01-30  

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