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Design of materials for selective separation of halogen elements and construction of recycling technology

Research Project

Project/Area Number 18K11714
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 64030:Environmental materials and recycle technology-related
Research InstitutionChiba Institute of Science

Principal Investigator

Tezuka Stoko  千葉科学大学, 危機管理学部, 准教授 (70435759)

Project Period (FY) 2018-04-01 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2020: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2019: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2018: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords層状複水酸化物 / イオン交換 / ハロゲン / 無機イオン / 吸着剤 / ハロゲン元素 / 環境材料 / 資源回収 / 分離 / リサイクル / 無機イオン吸着剤 / 吸着 / 無機イオン吸着材 / 層状化合物 / ナノシート
Outline of Final Research Achievements

Halogen, as an essential element, is indispensable to us and is used as a raw material for disinfectants and pharmaceuticals. Therefore, it is desirable to separate and recover them from natural aquatic environments and wastewater as valuable resources. This study focused on layered double hydroxide (LDH), an inorganic anion exchanger, and investigated its potential as an adsorbent for halide ions. As a result, a simple and inexpensive synthetic method for monoclinic LDH was successfully developed. In addition, information on the adsorption performance of iodide ions by various LDHs was obtained.

Academic Significance and Societal Importance of the Research Achievements

無機系吸着材に対する陰イオン吸着は陽イオンと同様の吸着メカニズムが存在している と考えられているが、実用可能な吸着容量を持つ無機系陰イオン吸着材は LDH のみであ り、未だ明確にはなっていない点が多い。そのため、本研究で報告した単斜晶系LDHの簡易合成手法、共存イオンが多量に存在する中からフッ素を回収できるLDH、ヨウ素吸着量が高いLDHは、学術的にも産業的にも有意義であるといえる。

Report

(7 results)
  • 2023 Annual Research Report   Final Research Report ( PDF )
  • 2022 Research-status Report
  • 2021 Research-status Report
  • 2020 Research-status Report
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (8 results)

All 2019 2018

All Journal Article (1 results) Presentation (7 results) (of which Int'l Joint Research: 3 results)

  • [Journal Article] 水資源の確保と保全に向けた浄化材料 高機能窒素除去材の開発と水環境修復技術への応用2018

    • Author(s)
      手束聡子
    • Journal Title

      セラミックス

      Volume: 53 Pages: 70-73

    • Related Report
      2018 Research-status Report
  • [Presentation] Anion exchange properties of monoclinic lithium-aluminum layered double hydroxides synthesized by simplified method with bayerite.2019

    • Author(s)
      Satoko Tezuka, Kouki Hoshi
    • Organizer
      Euroclay2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Anion exchange properties of magnesium aluminum layered double hydroxide based on bayerite.2019

    • Author(s)
      Satoko Tezuka
    • Organizer
      The 13th Pacific Rim Conference of Ceramic Societies (PacRim13)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] 水酸化アルミニウムを原料としたMg-Al層状複水酸化物の合成とアニオン吸着特性2019

    • Author(s)
      手束聡子
    • Organizer
      第63回粘土科学討論会発表
    • Related Report
      2019 Research-status Report
  • [Presentation] 星 光希、手束 聡子2019

    • Author(s)
      Li-Al 層状複水酸化物のアニオン吸着特性
    • Organizer
      公益社団法人日本セラミックス協会 2019年会
    • Related Report
      2018 Research-status Report
  • [Presentation] Anion exchange properties of monoclinic lithium-aluminum layered double hydroxides synthesized by simplified method with bayerite.2019

    • Author(s)
      Satoko Tezuka, Kouki Hoshi
    • Organizer
      EUROCLAY 2019
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Li-Ca-Al系層状複水酸化物のアニオン吸着特性2018

    • Author(s)
      星 光希、太田 希志乃、手束 聡子
    • Organizer
      第62回粘土科学討論会発表
    • Related Report
      2018 Research-status Report
  • [Presentation] 遷移金属を骨格に含む層状複水酸化物のヨウ化物およびヨウ素酸イオンの吸着特性2018

    • Author(s)
      手束 聡子、 星 光希、太田 希志乃
    • Organizer
      第62回粘土科学討論会
    • Related Report
      2018 Research-status Report

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Published: 2018-04-23   Modified: 2025-01-30  

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