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Preparation of thermoresponsive polymer/silica coated magnetite nanoparticle composite and its application for heavy metal ions recovery

Research Project

Project/Area Number 18K11716
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 64030:Environmental materials and recycle technology-related
Research InstitutionSoka University

Principal Investigator

Ida Junichi  創価大学, 理工学部, 教授 (20409783)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2020: ¥520,000 (Direct Cost: ¥400,000、Indirect Cost: ¥120,000)
Fiscal Year 2019: ¥390,000 (Direct Cost: ¥300,000、Indirect Cost: ¥90,000)
Fiscal Year 2018: ¥390,000 (Direct Cost: ¥300,000、Indirect Cost: ¥90,000)
Keywords感温性ポリマー / 磁性粒子 / 重金属回収 / 電解酸化法 / 誘導加熱 / シリカ被覆磁性ナノ粒子 / 重金属 / 有機無機複合材料 / 有機/無機複合材料 / 磁性ナノ粒子 / 有機 /無機複合材料
Outline of Final Research Achievements

In this study, a new thermoresponsive heavy metal adsorbent, which exhibit high adsorption rate, high adsorption capacity as well as low environmental impact, was successfully developed. The adsorbent does not require the use of acid of base during desorption process of adsorbed heavy metal ions, which is normally required in the process, since the control of adsorption/desorption of heavy metal ion on the adsorbent can be achieved by swinging (changing) solution temperature between 10 and 50°C. In addition, as to heating of the solution, an inductive heating property of magnetite, which is a component of the adsorbent, can be used instead of using an isothermal bath so that it is not required to heat the whole solution but is only required to realize localized heating around the adsorbent. The results indicate that it is possible to design a new heavy metal ion recovery process based on the developed adsorbent and the inductive heating in the future.

Academic Significance and Societal Importance of the Research Achievements

本研究によって、低環境負荷、かつ、重金属回収性能の高い吸着剤が開発され、誘導加熱を用いるこれまでにない重金属回収法実現の可能性も示された。今後、この吸着剤と誘導加熱を組み合わせた新たな重金属イオン回収プロセスを実現できれば、メッキ工場排水、電子機器処理廃水、汚染土壌処理等へ幅広く応用可能と考えられる。また、これにより近年深刻になりつつある、廃棄物処分場の問題や資源枯渇の問題の解決に貢献できると期待される。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (19 results)

All 2021 2020 2019 2018

All Journal Article (5 results) (of which Peer Reviewed: 4 results) Presentation (14 results) (of which Int'l Joint Research: 8 results)

  • [Journal Article] 電解酸化法を用いたシリカ被覆Fe3O4の調製におけるシリカ源濃度の影響評価と感温性ポリマー固定化への応用2021

    • Author(s)
      友永人志,林広大,松山達,井田旬一
    • Journal Title

      粉体工学会誌

      Volume: 58 Issue: 3 Pages: 111-118

    • DOI

      10.4164/sptj.58.111

    • NAID

      130008038502

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption properties of poly(NIPAM-co-AA) immobilized on silica-coated magnetite nanoparticles prepared with different acrylic acid content for various heavy metal ions2021

    • Author(s)
      Tomonaga Hitoshi、Tanigaki Yuichi、Hayashi Kodai、Matsuyama Tatsushi、Ida Junichi
    • Journal Title

      Chemical Engineering Research and Design

      Volume: 171 Pages: 213-224

    • DOI

      10.1016/j.cherd.2021.05.005

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of thermoresponsive copolymer/silica‐coated magnetite nanoparticle composite and its application for heavy metal ion recovery2020

    • Author(s)
      Tomonaga Hitoshi、Hayashi Kodai、Matsuyama Tatsushi、Ida Junichi
    • Journal Title

      Journal of Applied Polymer Science

      Volume: 138 Issue: 17 Pages: 50303-50303

    • DOI

      10.1002/app.50303

    • Related Report
      2020 Annual Research Report
  • [Journal Article] Effect of immobilization method and particle size on heavy metal ion recovery of thermoresponsive polymer/magnetic particle composites2020

    • Author(s)
      Risako Sakai, Tatsushi Matsuyama, Junichi Ida
    • Journal Title

      Colloids and Surfaces A: Physicochemical and Engineering Aspects

      Volume: 590 Pages: 124499-124499

    • DOI

      10.1016/j.colsurfa.2020.124499

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] A simple magnetite nanoparticle immobilized thermoresponsive polymer synthesis for heavy metal ion recovery2019

    • Author(s)
      Hayashi Kodai、Matsuyama Tatsushi、Ida Junichi
    • Journal Title

      Powder Technology

      Volume: 355 Pages: 183-190

    • DOI

      10.1016/j.powtec.2019.07.007

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Presentation] Characterization of Silica-Coated Fe3O4 Prepared Under Various Conditions Using Electrooxidation Method and Immobilization of Thermoresponsive Polymer2020

    • Author(s)
      Hitoshi Tomonaga, Kodai Hayashi, Tatsushi Matsuyama, Junichi Ida
    • Organizer
      American Institute Chemical Engineering (AIChE) Annual Meeting 2020
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 各種条件で調製したシリカ被覆Fe3Oの特性評価と感温性ポリマーの固定化2020

    • Author(s)
      友永人志, 林広大, 松山達, 井田旬一
    • Organizer
      粉体工学会 2020年度春期研究発表会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 電解酸化法によるシリカ被覆Fe3O4ナノ粒子の調製と感温性ポリマー固定化への応用2020

    • Author(s)
      友永人志, 林広大, 井田旬一, 松山達
    • Organizer
      化学工学会第51回秋期大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 感温性ポリマー/シリカ被覆Fe3O4複合体の調製と重金属イオン回収能の評価2020

    • Author(s)
      友永人志,林広大,松山達,井田旬一
    • Organizer
      粉体工学会 2020年度秋季研究発表会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Facile synthesis of polymer/magnetite nanoparticle composite2019

    • Author(s)
      Kodai Hayashi, Tatsushi Matsuyama and Junichi Ida
    • Organizer
      The 18th Asian Pacific Confederation of Chemical Engineering Congress. (APCChE 2019)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Thermoresponsive Copolymer Immobilized on Silica Coated Magnetite and Its Application for Heavy Metal Ions Recovery2019

    • Author(s)
      Hitoshi Tomonaga, Kodai Hayashi, Tatsushi Matsuyama, Junichi Ida
    • Organizer
      The 18th Asian Pacific Confederation of Chemical Engineering Congress. (APCChE 2019)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Facile synthesis of polymer/magnetite nanoparticle composite2019

    • Author(s)
      Kodai Hayashi, Junichi Ida and Tatsushi Matsuyama
    • Organizer
      American Institute Chemical Engineering (AIChE) Annual Meeting 2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Thermoresponsive Copolymer Immobilized on Silica Coated Magnetite and Its Application for Heavy Metal Ions Recovery2019

    • Author(s)
      Hitoshi Tomonaga, Kodai Hayashi, Tatsushi Matsuyama, Junichi Ida
    • Organizer
      American Institute Chemical Engineering (AIChE) Annual Meeting 2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] 電解酸化法によるシリカ被覆Fe3O4ナノ粒子の調製と感温性ポリマー固定化担体への応用2019

    • Author(s)
      友永人志, 松山達, 井田旬一
    • Organizer
      粉体工学会 2019年度秋季研究発表会
    • Related Report
      2019 Research-status Report
  • [Presentation] 感温性ポリマー固定化マグネタイトナノ粒子の合成と誘導加熱を用いた重金属イオン回収への応用2019

    • Author(s)
      林広大. 松山達. 井田旬一
    • Organizer
      粉体工学会 2019年度秋季研究発表会
    • Related Report
      2019 Research-status Report
  • [Presentation] New materials development based on powder technology and their application for various environmental problems2019

    • Author(s)
      Junichi Ida
    • Organizer
      2nd International Conference on Exhibition on Powder Technology Indonesia. (ICePTi 2019)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] A Simple Synthesis Method of Thermoresponsive Polymer Immobilized Magnetite Nanoparticles for Heavy Metal Ions Recovery2018

    • Author(s)
      Kodai Hayashi, Junichi Ida and Tatsushi Matsuyama
    • Organizer
      International Symposium on Chemistry and Materials Sciences(ISCM) 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] A Simple Synthesis Method of Thermoresponsive Polymer Immobilized Magnetite Nanoparticles for of Heavy Metal Ions Recovery2018

    • Author(s)
      12.Kodai Hayashi, Junichi Ida and Tatsushi Matsuyama
    • Organizer
      2018 American Institute of Chemical Engineering (AIChE) Annual Meeting
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 重金属イオン回収能を有する感温性ポリマー修飾マグネタイトナノ粒子合成法の簡略化2018

    • Author(s)
      林広大, 井田旬一, 松山達
    • Organizer
      化学工学会第50回秋季大会
    • Related Report
      2018 Research-status Report

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Published: 2018-04-23   Modified: 2022-01-27  

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