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The study of ammonia production catalyst for automatic fertilization using green chemistry technique

Research Project

Project/Area Number 18K11720
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 64030:Environmental materials and recycle technology-related
Research InstitutionSendai National College of Technology

Principal Investigator

ENDO TOMOAKI  仙台高等専門学校, 総合工学科, 教授・副校長'(研究・産学連携担当) (60369915)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2020: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsアンモニア / 三次元ボールミル / フラーレン / γ-シクロデキストリン / 施肥装置 / シクロデキストリン / 包接錯体 / C60 / バイキャップ型包接錯体 / アンモニア合成 / ジルコニア容器 / 3次元ボールミル
Outline of Final Research Achievements

For the purpose of producing ammonia from nitrogen a new catalyst developed. This bicap type complex catalyst formed of C60 and γ-cyclodextrin (γ-CyD) can synthesized using a three-dimensional ball mill and was obtained on a gram scale. Furthermore, using this complex catalyst, we have done to establish a process for producing ammonia from nitrogen. In order to develop a higher performance catalyst for the future, we have been synthesized derivatives chemically decorated with C60 and synthesized a bicap complex consisting of the derivative and γ-CyD using a three-dimensional ball mill.
In addition, in order to support the catalyst on the polymers, a compound in which a highly reactive substituent was introduced at the 6-position of γ-CyD was synthesized, and the formation of a complex with C60 was confirmed.

Academic Significance and Societal Importance of the Research Achievements

アンモニアは肥料として食料生産に欠かせないものであるが、一部の根粒細菌以外は、空気中の窒素をアンモニアに変換できない。そのためアンモニアは化学的に合成しなければならず、製造法として約100年前にハーバー・ボッシュ法が確立されているが、地球で使用される多くのエネルギーがこのために使用されている。本研究では、自然エネルギーのみを用いるアンモニアの製造プロセスを確立し、これを施肥装置に組み入れることによって圃場設置型の自動施肥装置として発展させる。アンモニア生産のエネルギーを省力化し、自動施肥装置により砂漠化の防止により、昨今の異常気象への対応、食料問題の解消を目指した研究である。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (8 results)

All 2020 2019 2018 Other

All Int'l Joint Research (1 results) Journal Article (1 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 1 results) Presentation (5 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results) Book (1 results)

  • [Int'l Joint Research] Universiti Malaysia Terengganu(マレーシア)

    • Related Report
      2020 Annual Research Report
  • [Journal Article] Data on synthesis and characterization of new p-nitro stilbene Schiff bases derivatives as an electrochemical DNA potential spacer2020

    • Author(s)
      HANIS Yusoff, Irshad Ul Haq Bhat, ZAFIRAH IZHAM, Tomoaki ENDO, Hiroshi Fukumura, Eunsang Kwon, Shin-Ichiro Yoshida, Asnuzilawati Asari, Uwaisulqarni, M. Osman, Mohd, Sukeri Mohd Yusof,
    • Journal Title

      Data in Brief

      Volume: 30 Pages: 105568-105568

    • DOI

      10.1016/j.dib.2020.105568

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Synthesis of aromatic compounds with Three-dimensional Ball Mill2020

    • Author(s)
      ENDO, Tomoaki; NAGAO, Fumiyoshi; NAGAO, Tomoharu; YAMAOKA, Yasuaki; KWON, Eunsang; NAGAHIRO, Shinichiro
    • Organizer
      第100回日本化学会春年会
    • Related Report
      2019 Research-status Report
  • [Presentation] The Three-dimensional Ball Mill (3DBM) for the Synthesis of Aromatic Compounds2019

    • Author(s)
      Tomoaki Endo, Daisuke Nagao, Fumiyoshi Nagao, Eunsang Kwon, Shin-ichiro Nagahiroa
    • Organizer
      The 18th International Symposium on Nobel Aromatic Compounds
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Organic Synthesis with Three-dimensional Ball Mill using Liquid Materials as Starting Materials2019

    • Author(s)
      Tomoaki Endo, Daisuke Nagao, Fumiyoshi Nagao, Yasuaki Yamaoka, Eunsanng Kwon, Shin-ichiro Nagahiro
    • Organizer
      第99回日本化学会春年会
    • Related Report
      2018 Research-status Report
  • [Presentation] Efficient and Convenient Mechanochemical Synthesis using Three-Dimensional Ball Mill2018

    • Author(s)
      Tomoaki Endo, Daisuke Nagao, Fumiyoshi Nagao, Yasuaki Yamaoka, Eunsang Kwon, Shin-ichiro Nagahiro
    • Organizer
      The 14th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-14)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Three-Dimensional Ball Mill for New Mechanochemical Synthesis Method2018

    • Author(s)
      Tomoaki Endo, Daisuke Nagao, Fumiyoshi Nagao, Eunsang Kwon and Shin-ichiro Nagahiro
    • Organizer
      International Congress on Pure & Applied Chemistry Langkawi (ICPAC Langkawi) 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Book] すぐにできる!双方向オンライン授業 : Zoom、Teams、Googleソフトを活用して、質の高い講義と化学実験を実現2020

    • Author(s)
      編著者, 福村 裕史, 飯箸 泰宏, 後藤 顕一, 著者, 白水 始, 伊藤 克治, 山岡 靖明, 遠藤 智明,
    • Total Pages
      87
    • Publisher
      化学同人
    • ISBN
      9784759820430
    • Related Report
      2020 Annual Research Report

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Published: 2018-04-23   Modified: 2022-03-04  

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