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Development of pressure-sensitive adhesive technologies that has both dismantability and high heat resistance for recycling

Research Project

Project/Area Number 18K11723
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 64030:Environmental materials and recycle technology-related
Research InstitutionOsaka Research Institute of Industrial Science and Technology

Principal Investigator

Hideki Tachi  地方独立行政法人大阪産業技術研究所, 和泉センター, 主幹研究員 (60359429)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2020: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords粘着剤 / 易剥離 / 易解体 / ポリイミド / 耐熱性 / シリコーン / 縮合系高分子 / 接着剤 / リサイクル
Outline of Final Research Achievements

In this study, we developed an easy-peelable pressure-sensitive adhesive (PSA) technology with high heat resistant that can be used for recycling. We synthesized photolabile crosslinkers that have both polymerizable and photodegradable moieties in a single molecule. Using these crosslinkers, we were able to prepare PSAs with dismantleability. We found that the PSAs were stable up to 200°C, and that the peel strength decreased with photo-irradiation and heating above 250°C. It was found that these PSAs can be used as an easy-peelable PSAs adhesive with heat resistance.

Academic Significance and Societal Importance of the Research Achievements

本研究により、これまでに報告例のなかった耐熱性と解体性を併せ持つ、解体性粘着剤の実用化への指針を得ることができた。この粘着剤は、ある程度の耐熱性を有しながら、光照射または高温での加熱によって解体性を発現させることが可能であり、新しい易解体性材料としての可能性を見出した。本研究成果は、粘着剤にとどまらず様々な高分子材料の解体性と耐熱性向上に展開が可能であることから、従来の粘・接着技術への利用のみならず、多くの分野(家電、自動車、建材、航空宇宙等)へ応用が可能であるため、循環型社会構築を目指すための材料の一つになりえるためその社会的意義は大きい。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (12 results)

All 2020 2019 2018

All Journal Article (3 results) (of which Peer Reviewed: 1 results) Presentation (8 results) (of which Int'l Joint Research: 1 results,  Invited: 4 results) Book (1 results)

  • [Journal Article] Photodegradation of Networked Polymers Composed of Photolabile Crosslinkers2020

    • Author(s)
      陶山寛志、舘 秀樹
    • Journal Title

      Journal of Networkpolymer,Japan

      Volume: 41 Issue: 6 Pages: 260-264

    • DOI

      10.11364/networkedpolymer.41.6_260

    • NAID

      130007958871

    • ISSN
      2433-3786, 2434-2149
    • Year and Date
      2020-11-10
    • Related Report
      2020 Annual Research Report
  • [Journal Article] Multifunctional Methacryloyloximes: Molecules Playing the Role of Monomer, Photoinitiator, and Photolabile Units2018

    • Author(s)
      Suyama Kanji,Tachi Hideki
    • Journal Title

      Journal of Photopolymer Science and Technology

      Volume: 31 Issue: 4 Pages: 517-522

    • DOI

      10.2494/photopolymer.31.517

    • NAID

      130007481552

    • ISSN
      0914-9244, 1349-6336
    • Year and Date
      2018-06-25
    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] 解体性接着材料2018

    • Author(s)
      舘秀樹
    • Journal Title

      接着の技術

      Volume: 38(1) Pages: 53-55

    • Related Report
      2018 Research-status Report
  • [Presentation] 様々な外部刺激に応答する解体性材料の開発2020

    • Author(s)
      舘 秀樹
    • Organizer
      第238回フォトポリマー講演
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] 外部刺激に応答する粘・接着の開発2020

    • Author(s)
      舘 秀樹
    • Organizer
      接着・接合技術コンソーシアム 第8回企業ワークショップ
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] オキシムエステル型光分解性架橋剤からなる架橋樹脂の光分解2019

    • Author(s)
      陶山寛志,舘秀樹
    • Organizer
      第68回高分子討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] マイクロカプセル化潜在性化合物を用いる超音波剥離粘着剤の開発2019

    • Author(s)
      舘秀樹,陶山寛志
    • Organizer
      グリーンケミストリー研究会-近未来の環境を考える高分子素材
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] 光分解性架橋剤を用いる光重合と光分解の制御2018

    • Author(s)
      舘秀樹,陶山寛志
    • Organizer
      日本接着学会 第56回年次大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Multifunctional Methacryloyloximes: Molecules Playing the Role of Monomer, Photoinitiator, and Photolabile Units2018

    • Author(s)
      Kanji Suyama, Hideki Tachi
    • Organizer
      The 35th International Conference of Photopolymer Science and Technology
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 三官能光分解性架橋剤を組み込んだ架橋樹脂の合成と光反応2018

    • Author(s)
      舘秀樹,陶山寛志
    • Organizer
      第67回高分子討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] マイクロカプセル化潜在性化合物を用いる超音波剥離粘着剤の開発2018

    • Author(s)
      舘秀樹,陶山寛志
    • Organizer
      第67回高分子討論会
    • Related Report
      2018 Research-status Report
  • [Book] 光機能性有機・高分子材料における新たな息吹2019

    • Author(s)
      市村國宏,舘秀樹,陶山寛志
    • Total Pages
      333
    • Publisher
      シーエムシー出版
    • ISBN
      9784781314143
    • Related Report
      2018 Research-status Report

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Published: 2018-04-23   Modified: 2022-01-27  

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