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Thermoelectric transport of non-equilibrium carriers

Research Project

Project/Area Number 18K13504
Research Category

Grant-in-Aid for Early-Career Scientists

Allocation TypeMulti-year Fund
Review Section Basic Section 13030:Magnetism, superconductivity and strongly correlated systems-related
Research InstitutionTokyo University of Science

Principal Investigator

OKAZAKI Ryuji  東京理科大学, 理工学部物理学科, 准教授 (50599602)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2020: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords熱電効果 / 輸送現象 / ゼーベック効果 / 電流効果 / 非線形伝導 / 非平衡電子状態 / ゼーベック係数 / 分子性導体 / ロジウム酸化物 / 非平衡電子物性 / 強相関電子系 / ペルチェ効果
Outline of Final Research Achievements

When the electric voltage is applied to the sample, the electrical current, which is proportional to the applied voltage, flows to the sample. In contrast to this well-known Ohm’s law, the transport phenomenon in which the flowing current is not proportional to the applied voltage is called nonlinear conduction. As seen in various nonlinear electric components such as diodes and transistors, the nonlinear conduction becomes a fundamental technology for the present electronics. In this research, we have investigated the nonlinear Seebeck effect, in which the thermopower depends on the current as similar to the current-dependent resistivity in the nonlinear conduction, and have found that the absolute value of the thermopower is increased by applying electrical current in an organic-molecular-based conductors. We also developed a temperature evaluation method for the self-heating problem.

Academic Significance and Societal Importance of the Research Achievements

非線形伝導は、近年、シリコンやゲルマニウムのような従来のバンド絶縁体だけでなく、モット絶縁体や電荷秩序絶縁体と呼ばれる強相関絶縁体において報告されており、それらの物質群では、数V/cmの電場で抵抗が1桁以上も変化する大きな非線形伝導が報告されています。それらは低電場で作動する新たなメモリ素子として応用上期待されるだけでなく、従来のメカニズムとは異なった、電場による電荷秩序の融解などの新しい非平衡物理現象を示すモデル物質としても注目されつつあり、本研究では通電時の抵抗の振る舞いだけでなく、ゼーベック係数も調べることで、そのような非平衡電子状態の知見を得ることに成功しました。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (25 results)

All 2021 2020 2019 2018 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results,  Open Access: 2 results) Presentation (12 results) (of which Int'l Joint Research: 5 results,  Invited: 2 results) Remarks (3 results)

  • [Journal Article] Crossover from itinerant to localized states in the thermoelectric oxide [Ca2CoO3]0.62[CoO2]2021

    • Author(s)
      H. Sakabayashi and R. Okazaki
    • Journal Title

      Physical Review B

      Volume: 103 Issue: 12 Pages: 125119-125119

    • DOI

      10.1103/physrevb.103.125119

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrical resistivity and thermopower of hole-doped delafossite CuCoO2 polycrystals2021

    • Author(s)
      K. Kurita, M. Yagisawa, and R. Okazaki
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 60 Issue: 1 Pages: 13001-13001

    • DOI

      10.35848/1347-4065/abd448

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Scaling in Transport Coefficients of Hole-doped CuRhO2 Single Crystals2020

    • Author(s)
      Kanji Kurita, Hokuto Sakabayashi, and Ryuji Okazaki
    • Journal Title

      JPS Conference Proceedings

      Volume: 30 Pages: 011191-011191

    • DOI

      10.7566/jpscp.30.011191

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Current-induced Giant Lattice Deformation in the Mott Insulator Ca2RuO42020

    • Author(s)
      Okazaki Ryuji、Kobayashi Kensuke、Kumai Reiji、Nakao Hironori、Murakami Youichi、Nakamura Fumihiko、Taniguchi Hiroki、Terasaki Ichiro
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 89 Issue: 4 Pages: 044710-044710

    • DOI

      10.7566/jpsj.89.044710

    • NAID

      210000158121

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Interplay between quantum paraelectricity and thermoelectricity in the photo-Seebeck effect in a SrTiO3 single crystal2019

    • Author(s)
      Yuuka Shiraishi, Kenji Tanabe, Hiroki Taniguchi, Ryuji Okazaki and Ichiro Terasaki
    • Journal Title

      Journal of Applied Physics

      Volume: 126 Issue: 4 Pages: 045111-045111

    • DOI

      10.1063/1.5106384

    • NAID

      120006765153

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Correlation in transport coefficients of hole-doped CuRhO2 single crystals2018

    • Author(s)
      K. Kurita, H. Sakabayashi, and R. Okazaki
    • Journal Title

      Phys. Rev. B

      Volume: 98 Issue: 11 Pages: 115103-115103

    • DOI

      10.1103/physrevb.99.115103

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Enhanced Seebeck coefficient by a filling-induced Lifshitz transition in KxRhO22018

    • Author(s)
      N. Ito, M. Ishii, and R. Okazaki
    • Journal Title

      Phys. Rev. B

      Volume: 99 Issue: 4 Pages: 041112-041112

    • DOI

      10.1103/physrevb.99.041112

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Spectroscopic signature of trimer Mott insulator and charge disproportionation in BaIrO32018

    • Author(s)
      R. Okazaki, S. Ito, K. Tanabe, H. Taniguchi, Y. Ikemoto, T. Moriwaki, and I. Terasaki
    • Journal Title

      Phys. Rev. B

      Volume: 98 Issue: 20 Pages: 205131-205131

    • DOI

      10.1103/physrevb.98.205131

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Quantum paramagnet near spin-state transition2018

    • Author(s)
      K. Tomiyasu, N. Ito, R. Okazaki, Y. Takahashi, M. Onodera, K. Iwasa, T. Nojima, T. Aoyama, K. Ohgushi, Y. Ishikawa, T. Kamiyama, S. Ohira-Kawamura, M. Kofu and S. Ishihara
    • Journal Title

      Advanced Quantum Technology

      Volume: 2018 Issue: 3 Pages: 1800057-1800057

    • DOI

      10.1002/qute.201800057

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Enhanced thermopower via spin-state modification2018

    • Author(s)
      Takahashi Hidefumi、Ishiwata Shintaro、Okazaki Ryuji、Yasui Yukio、Terasaki Ichiro
    • Journal Title

      Physical Review B

      Volume: 98 Issue: 2 Pages: 024405-024405

    • DOI

      10.1103/physrevb.98.024405

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Presentation] Nonlinear conduction detected by the harmonic measurement in an organic molecular conductor α-(BEDT-TTF)2I32021

    • Author(s)
      M. Ishii, R. Okazaki, M. Tamura
    • Organizer
      APS March Meeting 2021
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高温領域におけるCa3Co4O9の面内異方性測定2020

    • Author(s)
      坂林北斗, 歌川響, 岡崎竜二
    • Organizer
      日本物理学会第75回年次大会(2020年)
    • Related Report
      2019 Research-status Report
  • [Presentation] 高調波測定による非線形伝導現象の検出と発熱の検証2020

    • Author(s)
      石井まゆ, 神田直輝, 箱田優華, 岡崎竜二
    • Organizer
      日本物理学会第75回年次大会(2020年)
    • Related Report
      2019 Research-status Report
  • [Presentation] Scaling in transport coefficients of hole-doped CuRhO2 single crystals2019

    • Author(s)
      K. Kurita, H. Sakabayashi, and R. Okazaki
    • Organizer
      International Conference on Strongly Correlated Electron Systems 2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] CuCoO2多結晶の合成と熱電特性2019

    • Author(s)
      栗田寛士, 八木沢昌也, 岡崎竜二
    • Organizer
      日本物理学会2019年秋季大会(物性)
    • Related Report
      2019 Research-status Report
  • [Presentation] 層状ロジウム酸化物K0.5RhO2の輸送・磁気特性2019

    • Author(s)
      石井まゆ, 伊藤菜緒子, 岡崎竜二, 安井幸夫
    • Organizer
      日本物理学会2019年秋季大会(物性)
    • Related Report
      2019 Research-status Report
  • [Presentation] 層状ロジウム酸化物の熱電効果2019

    • Author(s)
      岡崎竜二
    • Organizer
      第二回コバルト研究会, 東北大学
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] CuRh1-yMgyO2単結晶における低温での電気抵抗率と熱起電力の相関2019

    • Author(s)
      栗田寛士, 坂林北斗, 岡崎竜二
    • Organizer
      日本物理学会第74回年次大会(2019年), 九州大学
    • Related Report
      2018 Research-status Report
  • [Presentation] Transport properties in the layered Rh oxide KxRhO22018

    • Author(s)
      Naoko Ito, Mayu Ishii, Ryuji Okazaki
    • Organizer
      The 3rd Asian Conference on Thermoelectrics (ACT3) & The 5th Micro & Nanoscale Heat Transfer and Energy Workshop (MNHTE2018), Taiwan
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Thermoelectric properties of CuRh1-yMgyO2 single crystals2018

    • Author(s)
      Kanji Kurita, Hokuto Sakabayashi, Ryuji Okazaki
    • Organizer
      The 3rd Asian Conference on Thermoelectrics (ACT3) & The 5th Micro & Nanoscale Heat Transfer and Energy Workshop (MNHTE2018), Taiwan
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 単結晶CuRh1-yMgyO2の熱電特性2018

    • Author(s)
      栗田寛士, 坂林北斗, 岡崎竜二
    • Organizer
      日本物理学会2018年秋季大会, 同志社大学
    • Related Report
      2018 Research-status Report
  • [Presentation] Seebeck effect in Ca2RuO4 under current2018

    • Author(s)
      Ryuji Okazaki
    • Organizer
      基盤S研究会「NESS 2018」, 京都大学
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Remarks] 研究室のホームページ

    • URL

      https://www.rs.tus.ac.jp/okazakilab/

    • Related Report
      2020 Annual Research Report
  • [Remarks] 研究者ホームページ

    • URL

      https://www.rs.tus.ac.jp/okazakilab/

    • Related Report
      2019 Research-status Report
  • [Remarks] 研究者ホームページ

    • URL

      https://www.rs.tus.ac.jp/okazakilab/index.html

    • Related Report
      2018 Research-status Report

URL: 

Published: 2018-04-23   Modified: 2022-01-27  

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