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Drastic reduction in thermal conductivity of binary or ternary group-IV alloy by introduction of multiple phonon scattering centers

Research Project

Project/Area Number 18K13786
Research Category

Grant-in-Aid for Early-Career Scientists

Allocation TypeMulti-year Fund
Review Section Basic Section 21050:Electric and electronic materials-related
Research InstitutionShizuoka University

Principal Investigator

Shimura Yosuke  静岡大学, 電子工学研究所, 助教 (40768941)

Project Period (FY) 2018-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsゲルマニウム / スズ / 熱電変換 / 結晶成長 / 多結晶 / 薄膜 / X線非弾性散乱 / ナノドット / フォノン
Outline of Final Research Achievements

In order to improve the efficiency of thermoelectric device, impact of introduction of Sn atoms into a polycrystalline SiGe alloy on thermal conductivity was investigated. The crystallization of the SiGeSn polycrystalline was mediated by Sn nanodots formed on SiO2. It was found that introduction of Sn is expected to reduce thermal conductivity without degrading other properties, such as electric conductivity and Seebeck coefficient. Inelastic X-ray scattering revealed that the reduction in thermal conductivity is due to the modulation of the local structure, which is observed only in alloy, vibration by Sn atoms.

Academic Significance and Societal Importance of the Research Achievements

本研究で得られた、Sn導入によって混晶中の局所構造の振動が変調されることを実験的に観測した結果は、混晶の熱電変換素子への応用に向けた材料設計指針の基礎となる知見である。また、安全なSi、Ge、およびSnからなる混晶を組成を制御しながら絶縁膜上に形成する手法は、論理回路などと同一基板上への熱電変換素子の組み込みに不可欠であり、IoTデバイスなどへの本成果の応用が期待される。

Report

(3 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • Research Products

    (10 results)

All 2019 2018 Other

All Int'l Joint Research (3 results) Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (6 results) (of which Int'l Joint Research: 5 results,  Invited: 1 results)

  • [Int'l Joint Research] imec(ベルギー)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] 国立台湾科技大学(その他の国・地域)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] imec(ベルギー)

    • Related Report
      2018 Research-status Report
  • [Journal Article] Reduced thermal conductivity of a Ge1-xSnx layer formed on a self-assembled Sn nanodot template2018

    • Author(s)
      Utsumi Junya、Ishimaru Tomokuni、Hayakawa Yasuhiro、Shimura Yosuke
    • Journal Title

      Semiconductor Science and Technology

      Volume: 33 Issue: 12 Pages: 124004-124004

    • DOI

      10.1088/1361-6641/aadc00

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Presentation] Group-IV Alloys Containing Sn2019

    • Author(s)
      Yosuke Shimura, Junya Utsumi, Masaki Okado, Kako Iwamoto, and Hirokazu Tatsuoka
    • Organizer
      1st Joint Workshop on Nanostructures
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] The impact of crystallinity and Sn composition of Ge1-xSnx on various properties in thermoelectric2019

    • Author(s)
      Junya Utsumi, Hirokazu Tatsuoka, and Yosuke Shimura
    • Organizer
      1st Joint Workshop on Nanostructures
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Evaluation of Phonon Density of State by Inelastic X-ray Scattering2019

    • Author(s)
      Kako Iwamoto, Masaki Okado, Junya Utsumi, Hirokazu Tatsuoka, and Yosuke Shimura
    • Organizer
      1st Joint Workshop on Nanostructures
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Polycrystalline GeSn Layer Formed on Self-assembled Sn Nanodots2019

    • Author(s)
      Yosuke Shimura, Junya Utsumi, Tomokuni Ishimaru, and Yasuhiro Hayakawa
    • Organizer
      5th International Conference on Nanoscience and Nanotechnology (ICONN2019)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Reduced Thermal Conductivity of Ge1-xSnx layer Formed on Self-assembled Sn Nanodots Template2018

    • Author(s)
      Junya Utsumi, Tomokuni Ishimaru, Yasuhiro Hayakawa, and Yosuke Shimura
    • Organizer
      Joint ISTDM/ICSI 2018 Conference
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 熱伝導率低減に向けた自己整合Snナノドット上多結晶Ge1-xSnx層形成2018

    • Author(s)
      内海隼也、石丸知邦、早川泰弘、志村洋介
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Research-status Report

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Published: 2018-04-23   Modified: 2021-02-19  

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