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Clarification of relationship between catalyst structure and catalytic activity over Mo-based mixed metal oxide

Research Project

Project/Area Number 18K14058
Research Category

Grant-in-Aid for Early-Career Scientists

Allocation TypeMulti-year Fund
Review Section Basic Section 27030:Catalyst and resource chemical process-related
Research InstitutionKanagawa University

Principal Investigator

Ishikawa Satoshi  神奈川大学, 工学部, 助教 (60813350)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2020: ¥520,000 (Direct Cost: ¥400,000、Indirect Cost: ¥120,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords結晶性複合酸化物触媒 / 選択酸化 / 多元化 / 結晶性Mo3VOx複合酸化物 / ε-Keggin型ヘテロポリ酸 / 元素多様性 / 酸化触媒 / 結晶性複合酸化物 / 構造制御 / 異金属導入 / 選択酸化反応 / 添加金属 / 触媒作用場 / ミクロ細孔
Outline of Final Research Achievements

Crystalline Mo3VOx (MoVO) and ε-Keggin based microporous material (ε-MoMO) were multi-functionalized by substituting constituent element or introducing additional element without altering their crystal structure. In the case of MoVO, W and Cu were introduced and the elemental composition similar to the industrial catalyst for selective oxidation of acrolein (ACR), multi-component MoVWCuO, was realized. The resulting catalyst showed better catalytic performance than that of the industrial catalyst for ACR oxidation. In the case of ε-MoMO, we found that the addition of Fe2+ significantly enhanced the re-oxidation rate of the catalyst. The observed function was similar to that of multi-component MoVBiCoFeO as the industrial catalyst for propylene oxidation. The catalytic function of Fe2+ would be deeply understood in detail based on their crystal structure.

Academic Significance and Societal Importance of the Research Achievements

工業実触媒の色彩を帯びた結晶性複合酸化物を用いることで、工業触媒として広く用いられる多元系Mo-V複合酸化物および多元系Mo-Bi-Fe-Co複合酸化物の触媒作用を調べた。結晶性Mo3VOxの場合、結晶構造を保ったままWおよびCuを導入することで、アクロレイン選択酸化反応における工業触媒の組成を、結晶構造体で表現できた。この触媒は結晶体でありながら工業触媒より高い活性を示した。本触媒の結晶構造と触媒活性の関係を調べることで工業触媒における各構成金属の役割を明確化できた。得られた成果は将来の酸化物触媒設計における基礎学理を提供するものであり、アカデミアのみならず化学産業への波及が期待できる。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (28 results)

All 2021 2020 2019 2018 Other

All Journal Article (9 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 9 results,  Open Access: 1 results) Presentation (17 results) (of which Int'l Joint Research: 5 results,  Invited: 4 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Thermally Induced Transformation of Sb-Containing Trigonal Mo3VOx to Orthorhombic Mo3VOx and Its Effect on the Catalytic Ammoxidation of Propane2020

    • Author(s)
      Inukai Shoma、Ishikawa Satoshi、Tanabe Toyokazu、Jing Yuan、Toyao Takashi、Shimizu Ken-Ichi、Ueda Wataru
    • Journal Title

      Chemistry of Materials

      Volume: 32 Issue: 4 Pages: 1506-1516

    • DOI

      10.1021/acs.chemmater.9b04534

    • Related Report
      2020 Annual Research Report 2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of High Dimensionally Structured Mo-Fe Mixed Metal Oxide and Its Catalytic Activity for Selective Oxidation of Methanol2020

    • Author(s)
      Shimoda Kosuke、Ishikawa Satoshi、Tashiro Masaya、Kumaki Masahiro、Hiyoshi Norihito、Ueda Wataru
    • Journal Title

      Inorganic Chemistry

      Volume: 59 Issue: 8 Pages: 5252-5255

    • DOI

      10.1021/acs.inorgchem.9b03713

    • Related Report
      2020 Annual Research Report 2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Selective Oxidation of Methacrolein over Crystalline Mo3VOx Catalysts and Comparison of Their Catalytic Properties with Heteropoly Acid Catalysts2020

    • Author(s)
      Ishikawa Satoshi、Noda Nagisa、Wada Masaki、Tsurumi Shota、Ueda Wataru
    • Journal Title

      ACS Catalysis

      Volume: 10 Issue: 18 Pages: 10535-10545

    • DOI

      10.1021/acscatal.0c02530

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Influence of the structure of trigonal Mo-V-M3rd oxides (M3rd; -, Fe, Cu, W) on catalytic performances in selective oxidations of ethane, acrolein, and allyl alcohol2019

    • Author(s)
      Satoshi Ishikawa, Toru Murayama, Benjamin Katryniok, Franck Dumeignil, Marcia Araque, Svetlana Heyte, Sebastien Paul, Yudai Yamada, Mizuki Iwazaki, Nagisa Noda, Wataru Ueda
    • Journal Title

      Applied Catalysis A: General

      Volume: 584 Pages: 117151-117151

    • DOI

      10.1016/j.apcata.2019.117151

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Thermal Behavior, Crystal Structure, and Solid-State Transformation of Orthorhombic Mo-V Oxide under Nitrogen Flow or in Air2019

    • Author(s)
      Masahiro Sadakane, Katsunori Kodato, Nobuhiro Yasuda, Satoshi Ishikawa, Wataru Ueda
    • Journal Title

      ACS Omega

      Volume: 4 Issue: 8 Pages: 13165-13171

    • DOI

      10.1021/acsomega.9b01212

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Redox-Active Zeolitic Transition Metal Oxides Based on ε-Keggin Units for Selective Oxidation2019

    • Author(s)
      Zhenxin Zhang, Satoshi Ishikawa, Qianqian Zhu, Toru Murayama, Masahiro Sadakane, Michikazu Hara, Wataru Ueda
    • Journal Title

      Inorganic Chemistry

      Volume: 58 Issue: 9 Pages: 6283-6293

    • DOI

      10.1021/acs.inorgchem.9b00502

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] High dimensionally structured W-V oxides as highly effective catalysts for selective oxidation of toluene2019

    • Author(s)
      Toru Murayama, Satoshi Ishikawa, Norihito Hiyoshi, Yoshinori Goto, Zhenxin Zhang, Takashi Toyao, Ken-ichi Shimizu, Shutoku Lee, Wataru Ueda
    • Journal Title

      Catalysis Today

      Volume: in press Pages: 60-66

    • DOI

      10.1016/j.cattod.2019.08.023

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis of a Crystalline Orthorhombic Mo-V-Cu Oxide for Selective Oxidation of Acrolein2019

    • Author(s)
      Satoshi Ishikawa, Yudai Yamada, Chuntian Qiu, Yoshito Kawahara, Norihito Hiyoshi, Akihiro Yoshida, Wataru Ueda
    • Journal Title

      Chemistry of Materials

      Volume: 31 Issue: 4 Pages: 1408-1417

    • DOI

      10.1021/acs.chemmater.8b04962

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Multi-dimensional Crystal Structuring of Complex Metal Oxide Catalysts of Group V and VI Elements by Unit-Assembling2019

    • Author(s)
      Satoshi Ishikawa, Zhenxin Zhang, Toru Murayama, Norihito Hiyoshi, Masahiro Sadakane, Wataru Ueda
    • Journal Title

      Topics in Catalysis

      Volume: 印刷中 Issue: 17-20 Pages: 1157-1168

    • DOI

      10.1007/s11244-018-1077-0

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Presentation] アクロレイン選択酸化反応用工業触媒としての 多元系Mo-V 複合酸化物の触媒活性場の考察2021

    • Author(s)
      石川 理史・山田 雄大・樫尾 直樹・下田 光祐・野田 渚紗・村山 徹・上田 渉
    • Organizer
      第127回触媒討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] メタクロレイン酸化とアクロレイン酸化における結晶性Mo3VOx複合酸化物の触媒活性差に関する考察2020

    • Author(s)
      野田 渚紗・石川 理史・上田 渉
    • Organizer
      第126回触媒討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] エタン酸化反応における結晶性斜方晶Mo3VOx複合酸化物の触媒活性場2020

    • Author(s)
      青木 和沙・石川 理史・上田 渉
    • Organizer
      第126回触媒討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] {Mo6O21}6-5員環ユニットを基盤としたMoおよびW酸化物の合成と 酸化触媒機能2020

    • Author(s)
      下田 光祐・宮沢 真維・石川 理史・上田 渉
    • Organizer
      第126回触媒討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Oxidation Catalysis over Crystalline Mo3VOx Catalysts2020

    • Author(s)
      Satoshi Ishikawa・Wataru Ueda
    • Organizer
      錯体化学会第70回討論会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Oxidation Catalysis over Crystalline Mo3VOx Catalysts for Selective oxidation of Ethane and Acrolein2020

    • Author(s)
      Satoshi Ishikawa・Wataru Ueda
    • Organizer
      KSIEC-JPI joint symposium
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 結晶性Mo3VOxへのGaの導入とプロパンアンモ酸化活性2020

    • Author(s)
      石川 理史・田中 良裕・上田 渉
    • Organizer
      第50回石油・石油化学討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Mo-V系複合酸化物を用いたアクロレイン選択酸化反応におけるプロモーター元素の機能2020

    • Author(s)
      石川 理史, 山田 雄大, 樫尾 直樹, 上田 渉
    • Organizer
      第125回触媒討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] 結晶性 Mo3VOx への骨格金属置換および異金属導入に立脚した選択酸化活性制御2019

    • Author(s)
      石川 理史, 上田 渉
    • Organizer
      日本結晶学学会 令和元年度 年会
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] 三方晶Mo3VOxへのSbのイオン交換と熱処理による斜方晶 Mo3VOx構造への結晶構造変化およびプロパンアンモ酸化活性2019

    • Author(s)
      石川 理史, 犬飼 将槙, 上田 渉
    • Organizer
      第124回触媒討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] Selective oxidation of alkane and unsaturated aldehyde over crystalline Mo3VOx catalyst2019

    • Author(s)
      Satoshi Ishikawa
    • Organizer
      ETH-ICAT joint symposium on catalysis
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis of high dimensionally structured mixed metal oxide by an assembly of structural units from giant polyoxometalate2019

    • Author(s)
      Satoshi Ishikawa, Wataru Ueda
    • Organizer
      Kick-Off Meeting of EPSRC-JSPS Core-to-Core Collaboration
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] 高次な構造を有する複合酸化物触媒を用いたプロパン選択酸化反応2019

    • Author(s)
      石川 理史, 松本 克也, 下田 光祐, 上田 渉
    • Organizer
      第7回 次世代天然ガス利用を考える若手勉強会 2019年7月13日 次世代天然ガス利用を考える若手勉強会,石油学会ジュニアソサイティ( JPIJS)
    • Related Report
      2019 Research-status Report
  • [Presentation] Introduction of Sb into trigonal Mo3VOx oxide and its crystal structure transformation to orthorhombic Mo3VOx structure by heat treatment2019

    • Author(s)
      Satoshi Ishikawa, Shoma Inukai, Toyokazu Tanabe, Wataru Ueda
    • Organizer
      12th NGCS
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Sbを含む結晶性三方晶Mo3VOx複合酸化物の熱処理による斜方晶Mo3VOx構造への結晶構造変化およびプロパンアンモ酸化反応2019

    • Author(s)
      石川 理史, 犬飼 将槙, 上田 渉
    • Organizer
      石油学会 第68回研究発表会
    • Related Report
      2019 Research-status Report
  • [Presentation] 結晶性Mo3VOx複合酸化物触媒へのCuの導入とアクロレイン選択酸化反応2018

    • Author(s)
      山田雄大,石川理史,上田 渉
    • Organizer
      石油学会第61回年会
    • Related Report
      2018 Research-status Report
  • [Presentation] Synthesis of crystalline orthorhombic Mo-V-Cu oxide for selective oxidation of acrolein to acrylic acid2018

    • Author(s)
      Y. Yamada, S. Ishikawa, C. Qiu, W. Ueda
    • Organizer
      The 8th Tokyo Conference on Advanced Catalytic Science and Technology
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Book] Complex Oxides (Chapter 7: New Crystalline Complex Metal Oxide Catalysts with Porous, Acidic, and Redox Properties)2019

    • Author(s)
      Satoshi Ishikawa, Zhenxin Zhang, Toru Murayama, Masahiro Sadakane, Wataru Ueda
    • Total Pages
      240
    • Publisher
      World Scientific Publishing Company
    • ISBN
      9789813278578
    • Related Report
      2018 Research-status Report
  • [Remarks]

    • URL

      http://apchem2.kanagawa-u.ac.jp/uedalab/

    • Related Report
      2020 Annual Research Report

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Published: 2018-04-23   Modified: 2022-01-27  

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