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Direct Electrospinning of Cyclic Small Molecules for Creation of Functional Fiber Materials

Research Project

Project/Area Number 18K14087
Research Category

Grant-in-Aid for Early-Career Scientists

Allocation TypeMulti-year Fund
Review Section Basic Section 28030:Nanomaterials-related
Research InstitutionNara Institute of Science and Technology (2019)
Shinshu University (2018)

Principal Investigator

Yoshida Hiroaki  奈良先端科学技術大学院大学, 先端科学技術研究科, 助教 (40727913)

Project Period (FY) 2018-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2019: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2018: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywordsエレクトロスピニング / シクロデキストリン / 不織布 / 結晶性 / 分子混合 / エレクトロピニング / ファイバ― / ククルビツリル / 結晶性制御
Outline of Final Research Achievements

Fiber/textile is one of the closest materials in our lives. Usually, spinning process using polymer can be applied to prepare fiber/textile materials. Recently, I found that even small molecules such as cyclodextrins can be spun into nano-/micro-fiber materials. Therefore, in this research project, a biggest purpose is to improve the direct spinning technique of small molecules. As a result of 2 years project, innovative fibers which molecularly mixed more than 2 different molecules were succeeded. And, molecular arrangement (crystallinity) in the fibers was controllable by precisely adjusting spinning conditions to get fibers or storage conditions to preserve fibers. Although the spinning mechanism is still elusive, detailed investigation on spinning solution are being continued.

Academic Significance and Societal Importance of the Research Achievements

高分子繊維材料が人類の生活に与えた影響は計り知れず、依然として高機能繊維材料のニーズは大きい。本研究で進める「低分子紡糸技術」は学術適にも未だ芽生え期の研究課題ではあるが、これまで殆ど考えられたことの無いアイデアを含んでおり、新しい研究領域の種になる可能性が期待できる。天然化合物・非天然化合物に限らず、多種多様な原料から自在に繊維を得ることができるようになれば、従来にない画期的な新素材を生み出せると信じている。

Report

(2 results)
  • 2019 Final Research Report ( PDF )
  • 2018 Research-status Report
  • Research Products

    (17 results)

All 2019 2018 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 1 results) Presentation (13 results) (of which Int'l Joint Research: 6 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Elicitation of Crystallinity in Cyclodextrin Electrospinning2019

    • Author(s)
      Yoshida Hiroaki、Sakuragi Kenta
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 92 Issue: 5 Pages: 927-929

    • DOI

      10.1246/bcsj.20180362

    • NAID

      130007649784

    • ISSN
      0009-2673, 1348-0634
    • Year and Date
      2019-05-15
    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Fabrication of supramolecular cyclodextrin-fullerene nonwovens by electrospinning2019

    • Author(s)
      Yoshida Hiroaki、Kikuta Ken、Kida Toshiyuki
    • Journal Title

      Beilstein Journal of Organic Chemistry

      Volume: 15 Pages: 89-95

    • DOI

      10.3762/bjoc.15.10

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] Cucurbit[n]uril Familyの直接電解紡糸によるナノファイバー材料の開発2018

    • Author(s)
      吉田裕安材、宮澤幸樹
    • Organizer
      第67回高分子年次大会, 3Pc093
    • Related Report
      2018 Research-status Report
  • [Presentation] Insolubilization of Cyclodextrin Nonwovens by Diisocyanate Crosslinker2018

    • Author(s)
      Yoshihiro Ozawa, Hiroaki Yoshida
    • Organizer
      NANOFIBERS2018, P-9
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Development of Superhydrophobic Cyclodextrin Nonwovens by Electrospinning2018

    • Author(s)
      Yuji Sugiyama, Hiroaki Yoshida
    • Organizer
      NANOFIBERS2018、P-10
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Direct Electrospinning of Mixed Cyclodextrins2018

    • Author(s)
      Kenta Sakuragi, Hiroaki Yoshida
    • Organizer
      NANOFIBERS2018、P-12
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 低分子紡糸技術により作製したシクロデキストリン不織布の不溶化2018

    • Author(s)
      大澤吉弘、吉田裕安材
    • Organizer
      H30年度繊維学会年次大会、1D07
    • Related Report
      2018 Research-status Report
  • [Presentation] 疎水化シクロデキストリンを用いた超撥水材料の開発2018

    • Author(s)
      吉田裕安材、杉山雄士
    • Organizer
      H30年度繊維学会年次大会、1D12
    • Related Report
      2018 Research-status Report
  • [Presentation] シクロデキストリンファイバー材料のための新奇な後架橋法の提案2018

    • Author(s)
      大澤吉弘、吉田裕安材
    • Organizer
      第7回 JACI/GSCシンポジウム、C-93
    • Related Report
      2018 Research-status Report
  • [Presentation] Direct Electrospinning of Cyclodextrins for Fabrication of Functional Fiber Materials2018

    • Author(s)
      Hiroaki Yoshida
    • Organizer
      TBIS2018 International Symposium, 2018-0046
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] シクロデキストリン(CD)のみから構成される不織布の後架橋による不溶化2018

    • Author(s)
      大澤吉弘、吉田裕安材
    • Organizer
      第67回高分子討論会、1K03
    • Related Report
      2018 Research-status Report
  • [Presentation] 液中エレクトロスピニングによるシクロデキストリン不織布の作製2018

    • Author(s)
      櫻木健太、吉田裕安材
    • Organizer
      第67回高分子討論会、1K04
    • Related Report
      2018 Research-status Report
  • [Presentation] シクロデキストリン誘導体からなる超撥水材料の開発2018

    • Author(s)
      杉山雄士、吉田裕安材
    • Organizer
      第67回高分子討論会、1R18
    • Related Report
      2018 Research-status Report
  • [Presentation] Fabrication of Polymer-free Cucurbit[6]uril Nonwovens by Electrospinning2018

    • Author(s)
      Hiroaki Yoshida, Koki Miyazawa, Toshiyuki Kida
    • Organizer
      IPC2018, 6C07
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Development of Superhydrophobic Materials Composed of Cyclodextrin Derivative2018

    • Author(s)
      Yuji Sugiyama, Hiroaki Yoshida
    • Organizer
      IPC2018, 7C12
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Remarks] 吉田裕安材研究室HP

    • URL

      https://hyoshidalab.wixsite.com/home

    • Related Report
      2018 Research-status Report
  • [Patent(Industrial Property Rights)] 撥水加工材および加工製品2018

    • Inventor(s)
      海老名亮祐, 林宏和, 吉田裕安材
    • Industrial Property Rights Holder
      海老名亮祐, 林宏和, 吉田裕安材
    • Industrial Property Rights Type
      特許
    • Filing Date
      2018
    • Related Report
      2018 Research-status Report

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Published: 2018-04-23   Modified: 2021-02-19  

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