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Development of time resolved STM-THz-TDS system for studying the ultrafast carrier dynamics of graphene

Research Project

Project/Area Number 18K14153
Research Category

Grant-in-Aid for Early-Career Scientists

Allocation TypeMulti-year Fund
Review Section Basic Section 30020:Optical engineering and photon science-related
Research InstitutionInstitute of Physical and Chemical Research

Principal Investigator

Jaculbia Rafael  国立研究開発法人理化学研究所, 開拓研究本部, 訪問研究員 (40777299)

Project Period (FY) 2018-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2020: ¥520,000 (Direct Cost: ¥400,000、Indirect Cost: ¥120,000)
Fiscal Year 2019: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2018: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
KeywordsTerahertz / SPM / Nanomaterials / Nanospectroscopy / tip enhancement / Tip enhancement / Raman spectroscopy / Graphene / STM / Terahertz spectroscopy / Low temperature / Ultrafast spectroscopy
Outline of Final Research Achievements

In this project, three types of nanospectroscopy system was developed which utilizes Terahertz (THz) radiation and scanning probe microscopy (SPM). Owing to this combination, our setup allows for the investigation of various materials with nanoscale dimensions. In one compact arrangement, our system is composed of SPM THz time domain spectroscopy (SPM-THz-TDS), SPM optical pump-probe spectroscopy (SPM-OPTP), and SPM laser terahertz emission microscopy (SPM-LTEM). Switching between all of these setups is achieved by movement of flip mirrors and fixing other parts such as the delay stage. Moreover, we placed all of the critical components such as the THz related optics, the SPM, and other electronics inside a vacuum sealable box. This configuration was done in order to reduce the noice as well as to avoid water vapor absorption of the THz radiation. Using these setups, we have investigated low temperature grown GaAs, InAs and CVD grown graphene samples.

Academic Significance and Societal Importance of the Research Achievements

To find the practical applications of newly discovered nanomaterials, understanding their properties is crucial. Our developed setup allows us to investigate these new nanomaterials. Full understanding of these sample properties would then lead to the discovery of their practical applications.

Report

(5 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Research-status Report
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (13 results)

All 2022 2021 2020 2019 2018

All Journal Article (7 results) (of which Int'l Joint Research: 7 results,  Peer Reviewed: 7 results) Presentation (6 results) (of which Int'l Joint Research: 4 results,  Invited: 3 results)

  • [Journal Article] Orbital-resolved visualization of single-molecule photocurrent channels2022

    • Author(s)
      Imai-Imada Miyabi、Imada Hiroshi、Miwa Kuniyuki、Tanaka Yusuke、Kimura Kensuke、Zoh Inhae、Jaculbia Rafael B.、Yoshino Hiroko、Muranaka Atsuya、Uchiyama Masanobu、Kim Yousoo
    • Journal Title

      Nature

      Volume: 603 Issue: 7903 Pages: 829-834

    • DOI

      10.1038/s41586-022-04401-0

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Atomically Precise Delineation of As Antisite Defect States from Undoped Gallium Arsenide Host Lattice by Scanning Tunneling Microscopy and Spectroscopy Measurements and Density Functional Theory Calculations2022

    • Author(s)
      Balgos Maria Herminia M.、Esca?o Mary Clare S.、Jaculbia Rafael B.、Quang Nguyen Tien、Prieto Elizabeth Ann P.、Estacio Elmer S.、Salvador Arnel A.、Somintac Armando S.、Tani Masahiko、Hayazawa Norihiko、Kim Yousoo
    • Journal Title

      physica status solidi (b)

      Volume: 1 Issue: 7 Pages: 2100652-2100652

    • DOI

      10.1002/pssb.202100652

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effect of detection angle and substrate in the polarization analysis of 1D dipole emission2021

    • Author(s)
      Dasallas Lean、Jaculbia Rafael、Balois-Oguchi Maria Vanessa、Garcia Wilson、Hayazawa Norihiko
    • Journal Title

      Journal of the Optical Society of America B

      Volume: 39 Issue: 1 Pages: 307-307

    • DOI

      10.1364/josab.442109

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] True bulk As-antisite defect in GaAs(110) identified by DFT calculations and probed by STM/STS measurements2020

    • Author(s)
      Escano Mary Clare、Balgos Maria Herminia、Nguyen Tien Quang、Prieto Elizabeth Ann、Estacio Elmer、Salvador Arnel、Somintac Armando、Jaculbia Rafael、Hayazawa Norihiko、Kim Yousoo、Tani Masahiko
    • Journal Title

      Applied Surface Science

      Volume: 511 Pages: 145590-145590

    • DOI

      10.1016/j.apsusc.2020.145590

    • Related Report
      2020 Research-status Report 2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] EXPRESS: Controlling the Resonance Raman Effect in Tip-Enhanced Raman Spectroscopy Using a Thin Insulating Film2020

    • Author(s)
      Jaculbia Rafael、Hayazawa Norihiko、Imada Hiroshi、Kim Yousoo
    • Journal Title

      Applied Spectroscopy

      Volume: 11 Issue: 11 Pages: 1391-1397

    • DOI

      10.1177/0003702820938366

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Single-molecule resonance Raman effect in a plasmonic nanocavity2020

    • Author(s)
      Jaculbia Rafael B.、Imada Hiroshi、Miwa Kuniyuki、Iwasa Takeshi、Takenaka Masato、Yang Bo、Kazuma Emiko、Hayazawa Norihiko、Taketsugu Tetsuya、Kim Yousoo
    • Journal Title

      Nature Nanotechnology

      Volume: 15 Issue: 2 Pages: 105-110

    • DOI

      10.1038/s41565-019-0614-8

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Atomically-resolved interface imaging and terahertz emission measurements of gallium arsenide epilayers2019

    • Author(s)
      Balgos M. H.、Jaculbia R.、Prieto E. A.、Tani M.、Estacio E.、Salvador A.、Somintac A.、Hayazawa N.、Kim Y.
    • Journal Title

      Journal of Applied Physics

      Volume: 126 Issue: 23 Pages: 235706-235706

    • DOI

      10.1063/1.5118815

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Tip-enhanced Resonance Raman spectroscopy and imaging of a single molecule2020

    • Author(s)
      Rafael B. Jaculbia
    • Organizer
      SPP Physics Conference, Online
    • Related Report
      2020 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Tip-enhanced Raman spectroscopy and imaging of a single molecule in ultrahigh vacuum and low temperature environments2020

    • Author(s)
      Rafael B. Jaculbia
    • Organizer
      The Philippine-American Academy of Science and Engineering, Online
    • Related Report
      2020 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Vibrationally resolved imaging of a single molecule using tip-enhanced Resonance Raman spectroscopy2019

    • Author(s)
      Jaculbia, Rafael; Imada, Hiroshi; Miwa, Kuniyuki; Yang, Bo; Kazuma, Emiko; Hayazawa, Norihiko; Kim, Yousoo
    • Organizer
      10th International Conference on Advanced Vibrational Spectroscopy
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Vibrational symmetry of a single molecule revealed by tip-enhanced Raman spectroscopy2019

    • Author(s)
      Rafael B. Jaculbia, Hiroshi Imada, Kuniyuki Miwa, Takeshi Iwasa, Masato Takenaka, Bo Yang, Emiko Kazuma, Norihiko Hayazawa, Tetsuya Taketsugu, Yousoo Kim
    • Organizer
      80th JSAP autumn meeting
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Single molecule tip-enhanced Resonance Raman spectroscopy in low temperature environments2019

    • Author(s)
      Rafael B. Jaculbia, Hiroshi Imada, Kuniyuki Miwa, Takeshi Iwasa, Masato Takenaka, Bo Yang, Emiko Kazuma, Norihiko Hayazawa, Tetsuya Taketsugu, Yousoo Kim
    • Organizer
      Philippine-Japan Conference on Photonics and Optical Materials
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] Investigation of the adsorption structure of CuPc on NaCl/Ag(111) using STM2018

    • Author(s)
      Rafael Jaculbia
    • Organizer
      14th International Conference on Atomically Controlled Surfaces, Interfaces and Nanostructures (ACSIN-14)&26th International Colloquium on Scanning Probe Microscopy (ICSPM26), Sendai, Japan
    • Related Report
      2018 Research-status Report

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Published: 2018-04-23   Modified: 2023-01-30  

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