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Development of a game-changing isotope analysis method using absorption saturation phenomena in an optical cavity

Research Project

Project/Area Number 18K14162
Research Category

Grant-in-Aid for Early-Career Scientists

Allocation TypeMulti-year Fund
Review Section Basic Section 31010:Nuclear engineering-related
Research InstitutionNagoya University (2019-2020)
Japan Atomic Energy Agency (2018)

Principal Investigator

Kuwahara Akira  名古屋大学, 工学研究科, 助教 (50732418)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2020: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords同位体分析 / レーザー分光 / キャビティリングダウン分光 / 光共振器 / 吸収飽和 / プラズマ分光分析 / プラズマ / 放射性廃棄物 / 同位体シフト
Outline of Final Research Achievements

A novel laser spectroscopic system consisting of an optical cavity has been developed to achieves high sensitivity and high wavelength resolution by causing absorption saturation. In this study, we demonstrated the feasibility of absorption saturation by experimental and theoretical approaches. First, we confirmed experimentally that the peak intensity of an absorption profile decreased by a few percent due to absorption saturation of an atomic-electronic transition at the incident beam intensity of 2 mW into the optical cavity. Next, two numerical models of cavity ring-down spectroscopy were proposed and their results suggest that the initial saturation and its relaxation process in a ring-down signal can be observed under a few mW of the incident laser beam intensity.

Academic Significance and Societal Importance of the Research Achievements

従来の同位体分析では、サンプルを装置に導入する前の人手による前処理作業が分析コストや被ばくリスクの増加をもたらしている。本研究では、人手を要さずにサンプル分析を実現するため、高温プラズマとレーザー分光を組み合わせ、特定条件下で出現する物理現象を駆使する新しい分析法について、原理実証を行った。本手法は、化学分離等の専門的知識や付帯設備を必要とせず、単一装置のみで分析を完結できる利点もあり、原子力工学分野以外への適用も期待できる。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (7 results)

All 2021 2020 2019 2018 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (4 results) (of which Int'l Joint Research: 1 results,  Invited: 2 results) Remarks (1 results)

  • [Journal Article] Temperature difference between gas species in absorption measurements using diode laser absorption spectroscopy and its effect on temperature reduction2021

    • Author(s)
      Akira Kuwahara, Yasuaki Aiba, Takuya Nankawa, Makoto Matsui
    • Journal Title

      Atomic Spectroscopy

      Volume: - Issue: 3

    • DOI

      10.46770/as.2021.006

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High spectral resolution of diode laser absorption spectroscopy for isotope analysis using a supersonic plasma jet2018

    • Author(s)
      Akira Kuwahara, Yasuaki Aiba, Shinya Yamasaki, Takuya Nankawa, Makoto Matsui
    • Journal Title

      Journal of Analytical Atomic Spectrometry

      Volume: 33 Issue: 7 Pages: 1150-1153

    • DOI

      10.1039/c8ja00120k

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Presentation] 同位体分析を目的とした超音速プラズマ中のストロンチウム蛍光スペクトル測定2021

    • Author(s)
      桑原彬、早川禎一郎、澤田佳代、榎田洋一
    • Organizer
      日本原子力学会2021年春の年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] アークジェットによる運動方向を制御したアルゴンプラズマを対象としたレーザー誘起蛍光分光システムの開発2020

    • Author(s)
      早川禎一郎、桑原彬、澤田佳代、榎田洋一
    • Organizer
      日本原子力学会中部支部第52回研究発表会
    • Related Report
      2020 Annual Research Report
  • [Presentation] New Approach for Isotope Analysis Using Supersonic Plasma Jet Combined with Laser Absorption Spectroscopy2019

    • Author(s)
      Akira Kuwahara
    • Organizer
      7th Annual Conference of AnalytiX-2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 超音速プラズマ風洞を利用した革新的な元素・同位体分析技術2019

    • Author(s)
      桑原彬
    • Organizer
      未来2020
    • Related Report
      2019 Research-status Report
    • Invited
  • [Remarks] 榎田・澤田研究室

    • URL

      https://erre.energy.nagoya-u.ac.jp/about/

    • Related Report
      2019 Research-status Report

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Published: 2018-04-23   Modified: 2022-01-27  

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