| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2019: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2018: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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| Outline of Final Research Achievements |
In this study, metal chlorides of the early 4d/5d-transition-metals, i.e., Zr(IV), Nb(V), Mo(V), Hf(IV), Ta(V), and W(VI), were stoichiometrically introduced into a tetraphenylmethane-core dendritic-phenylazomethine generation 4 dendrimer in the presence of an optimal amount of organic ligands such as pyridine and 3-chloropyridine. The coordinative interactions between the metal chlorides and the imines in the dendrimers indicated a positive correlation for the Lewis acidity of the metals. Moreover, it was clearly demonstrated for the first time that heterometallic assemblies of defined composition contain four kinds of early 4d/5d-transition-metals, such as Ta(V), Nb(V), Mo(V), and Zr(IV), which was confirmed by UV-vis titration, XPS, and HAADF-STEM/EDS measurements. The results of this study should provide access to new routes to produce nanomaterials composed of heterometallic early 4d/5d-transition metals.
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