Development of high radiation absorbing and high refractive polymers based on bismuth, the heaviest stable element
| Project/Area Number |
18K14269
|
|---|
| Research Category |
Grant-in-Aid for Early-Career Scientists
|
| Allocation Type | Multi-year Fund |
|---|
| Review Section |
Basic Section 35010:Polymer chemistry-related
|
|---|
| Research Institution | Yamagata University |
|---|
Principal Investigator |
|
|---|
| Project Period (FY) |
2018-04-01 – 2020-03-31
|
| Project Status |
Completed (Fiscal Year 2019)
|
| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2019: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2018: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
|
|---|
| Keywords | ビスマス / 高屈折率ポリマー / ネットワークポリマー / ラジカル重合 / チオール-エン反応 / 屈折率プラスチック / 光学材料 / 有機-無機ハイブリッド材料 / 高分子合成 / 高分子構造・物性 |
|---|
| Outline of Final Research Achievements |
To develop novel high refractive index polymers, we investigated the synthesis and polymerization of bismuth-containing monomers. For example, styrylebismuthine was obtained as a stable monomer. Its thermal homopolymerization proceeded efficiently without solvents under nitrogen. In addition, we prepared polymer films based on the polymerization, and evaluated the optical properties. As a result, the refractive index (nD) of the polymer film was 1.69.
|
| Academic Significance and Societal Importance of the Research Achievements |
これまで有機材料との複合がほとんど検討されてこなかったビスマスという元素を、ポリマーと分子レベルで複合することで、その機能性材料としての可能性を提唱できた。
|
Report
(3 results)
Research Products
(7 results)
