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Fabrication of Artificial Synaptic Devices Based on Polymer Ultra-Thin Films

Research Project

Project/Area Number 18K14294
Research Category

Grant-in-Aid for Early-Career Scientists

Allocation TypeMulti-year Fund
Review Section Basic Section 35030:Organic functional materials-related
Research InstitutionTohoku University

Principal Investigator

Shunsuke Yamamoto  東北大学, 工学研究科, 助教 (70707257)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2020: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2019: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2018: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords高分子超薄膜 / 交互吸着法 / 電気化学トランジスタ / 混合伝導体 / 神経模倣素子 / 共役高分子 / 抵抗変化スイッチ / 交流インピーダンス / 交互吸着 / 人工シナプス / 電子伝導 / イオン伝導
Outline of Final Research Achievements

This study focused on two types of devices (a) resistive switch type and (b) electrochemical transistor type to create an "artificial synaptic device" that mimics the transmission of information in the nerve and brain. As a result, we found that the neuromorphic behavior of (a) can be realized by using layer-by-layer film using redox-active polymer. In (b), we estimated the "information retention time", which is an index of neuromorphic behavior, using an active layer of conductive polymer mixed with an ion-conductive polymer. As a result, we found that the information retention time of the device became shorter on the addition of the ion-conductive polymer, indicating that the response speed of the neuromorphic device can be freely controlled.

Academic Significance and Societal Importance of the Research Achievements

これらの成果は神経模倣素子の設計方針の構築に寄与するだけでなく、今なお不明な点が多い動作原理の解明にも役立つ成果である。本研究の成果は、脳の動作を模倣した新型コンピュータの応用研究につながることが期待される。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (25 results)

All 2020 2019 2018 Other

All Int'l Joint Research (2 results) Journal Article (8 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 8 results) Presentation (12 results) (of which Int'l Joint Research: 3 results,  Invited: 5 results) Remarks (3 results)

  • [Int'l Joint Research] University of Cambridge(英国)

    • Related Report
      2019 Research-status Report
  • [Int'l Joint Research] ケンブリッジ大学(英国)

    • Related Report
      2018 Research-status Report
  • [Journal Article] Controlling the Neuromorphic Behavior of Organic Electrochemical Transistors by Blending Mixed and Ion Conductors2020

    • Author(s)
      Yamamoto Shunsuke、Malliaras George G.
    • Journal Title

      ACS Applied Electronic Materials

      Volume: 2 Issue: 7 Pages: 2224-2228

    • DOI

      10.1021/acsaelm.0c00203

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Layer-by-Layer Growth Control of Metal Organic Framework Thin Films Assembled on Polymer Films2020

    • Author(s)
      Hiroaki Ohara, Shunsuke Yamamoto, Daiki Kuzuhara, Tomoyuki Koganezawa, Hidetoshi Oikawa, and Masaya Mitsuishi
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 12 Issue: 45 Pages: 50784-50792

    • DOI

      10.1021/acsami.0c13016

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Titania Nanofilms from Titanium Complex-Containing Polymer Langmuir-Blodgett Films2020

    • Author(s)
      Yamamoto Shunsuke, Ono Asami, Matsui Jun, Hoshino Norihisa, Akutagawa Tomoyuki, Miyashita Tokuji, Mitsuishi Masaya
    • Journal Title

      Langmuir

      Volume: 36 Issue: 35 Pages: 10371-10378

    • DOI

      10.1021/acs.langmuir.0c01446

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Controlled Ion Permeability of Ultrathin Nanoporous SiO2 Films from Silsesquioxane-Containing Polymer Nanosheets2020

    • Author(s)
      Ishizaki Yuya、Yamamoto Shunsuke、Miyashita Tokuji、Mitsuishi Masaya
    • Journal Title

      ACS Applied Nano Materials

      Volume: 3 Issue: 8 Pages: 7454-7461

    • DOI

      10.1021/acsanm.0c01048

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of Interfacial Nanoassembly Techniques in Functional Nanomaterials2019

    • Author(s)
      Yamamoto Shunsuke
    • Journal Title

      Polymer Journal

      Volume: 51 Issue: 8 Pages: 731-738

    • DOI

      10.1038/s41428-019-0190-7

    • NAID

      40022176761

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] High-Density and Monolayer-Level Integration of π-Conjugated Units: Amphiphilic Carbazole Homopolymer Langmuir?Blodgett Films2018

    • Author(s)
      Yamamoto Shunsuke、Nishina Nanae、Matsui Jun、Miyashita Tokuji、Mitsuishi Masaya
    • Journal Title

      Langmuir

      Volume: 34 Issue: 36 Pages: 10491-10497

    • DOI

      10.1021/acs.langmuir.8b01694

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Porous SiO2 Nanofilm Formation of the Silsesquioxane-Containing Amphiphilic Block Copolymer2018

    • Author(s)
      Ishizaki Yuya、Yamamoto Shunsuke、Miyashita Tokuji、Mitsuishi Masaya
    • Journal Title

      Langmuir

      Volume: 34 Issue: 27 Pages: 8007-8014

    • DOI

      10.1021/acs.langmuir.8b01114

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Resistive switching of organic?inorganic hybrid devices of conductive polymer and permeable ultra-thin SiO2 films2018

    • Author(s)
      Yamamoto Shunsuke、Kitanaka Takahisa、Miyashita Tokuji、Mitsuishi Masaya
    • Journal Title

      Nanotechnology

      Volume: 29 Issue: 26 Pages: 26LT02-26LT02

    • DOI

      10.1088/1361-6528/aabdc6

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Presentation] 混合伝導性高分子ブレンドを用いた神経模倣素子の構築2020

    • Author(s)
      山本俊介、George G. Malliaras
    • Organizer
      第69回高分子討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Neuromorphic Devices Based on Polymer Thin-Films2020

    • Author(s)
      Shunsuke Yamamoto
    • Organizer
      令和2年度化学系学協会東北大会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] 高分子薄膜を用いた神経模倣素子の作製2019

    • Author(s)
      山本俊介
    • Organizer
      有機固体若手の会 2019冬の学校
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] Monolayer-Level Assembly of Amphiphilic Molecules with π-Conjugated Units2019

    • Author(s)
      Shunsuke Yamamoto
    • Organizer
      15th European Conference on Molecular Electronics
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Development of Hybrid Polymer Nanosheets2019

    • Author(s)
      Shunsuke Yamamoto
    • Organizer
      日本化学会 第99春季年会
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] フェロセン修飾高分子電解質超薄膜を用いた抵抗変化スイッチの電流-電圧特性2019

    • Author(s)
      渡邉 暁斗, 山本 俊介, 三ツ石 方也
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] 高分子テンプレートを用いた多孔性SiO2ナノ薄膜の作製と抵抗変化スイッチ素子への応用2018

    • Author(s)
      山本 俊介
    • Organizer
      第6回アライアンス若手研究交流会
    • Related Report
      2018 Research-status Report
  • [Presentation] Interfacial Nanoassemblies of π-Conjugated Units2018

    • Author(s)
      Shunsuke Yamamoto, Tokuji Miyashita, Masaya Mitsuishi
    • Organizer
      18th International Symposium on Advanced Organic Photonics
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] フェロセン修飾ポリエチレンイミン交互積層膜を用いた抵抗変化スイッチの作製2018

    • Author(s)
      渡邉 暁斗, 山本 俊介, 三ツ石 方也
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] Interfacial Nanoassemblies of Functional Nanomaterials2018

    • Author(s)
      Shunsuke Yamamoto, Tokuji Miyashita, Masaya Mitsuishi
    • Organizer
      平成30年度化学系学協会東北大会
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] Fabrication of Polymer Nanosheets with Bithiophene Units2018

    • Author(s)
      Shunsuke Yamamoto, Tomohiro Ikemoto, Rie Matsui, Takafumi Shimoaka, Takeshi Hasegawa, Tomoyuki Koganezawa, Jun Matsui, Tokuji Miyashita, Masaya Mitsuishi
    • Organizer
      17th International Conference on Organized Molecular Films
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] フェロセン修飾ポリエチレンイミンの合成と交互積層膜の作製2018

    • Author(s)
      渡邉 暁斗, 山本 俊介, 宮下 徳治, 三ツ石 方也
    • Organizer
      第67回高分子年次大会
    • Related Report
      2018 Research-status Report
  • [Remarks] 高分子化学をふまえて「神経のような動きをする」電子素子をつくる

    • URL

      https://www.chem-station.com/blog/2020/07/ionconductor.html

    • Related Report
      2020 Annual Research Report
  • [Remarks] 高分子を用いた神経模倣素子の応答速度制御に成功 「神経のような動き」をする電子部品の実用化に向けて

    • URL

      http://www.tohoku.ac.jp/japanese/2020/06/press20200624-01-kobunshi.html

    • Related Report
      2020 Annual Research Report
  • [Remarks] プラスチック表面への多孔質材料コーティングに成功

    • URL

      http://www.tohoku.ac.jp/japanese/2020/11/press20201104-02-mof.html

    • Related Report
      2020 Annual Research Report

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Published: 2018-04-23   Modified: 2022-01-27  

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