• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Investigation of chemical structure of graphite edge sites maximizing its performance for Li secondary battery

Research Project

Project/Area Number 18K14312
Research Category

Grant-in-Aid for Early-Career Scientists

Allocation TypeMulti-year Fund
Review Section Basic Section 36020:Energy-related chemistry
Research InstitutionGunma University

Principal Investigator

Ishii Takafumi  群馬大学, 大学院理工学府, 助教 (50750155)

Project Period (FY) 2018-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2019: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2018: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywords炭素材料 / 表面分析 / 黒鉛 / リチウムイオン二次電池 / カーボン材料 / エッジ面
Outline of Final Research Achievements

We have developed a precise analysis technique for understanding the chemical structure of the graphite edge sites, which was considered to be the most important and difficult in this research project, within the period of this research. This technique makes it possible to distinguish phenol from ether and edge hydrogen on the edge sites by using deuterium labeling. By using this technique, it is possible to evaluate the actual chemical structure of the graphite edge sites, which is expected to make a great leap forward in the future research. Regarding these results, we have published a paper in an international journal and made a patent.

Academic Significance and Societal Importance of the Research Achievements

本研究では,黒鉛表面の化学構造を精密分析する手法の開発を達成した.開発した手法は黒鉛に限らず,炭素材料全般の表面分析に適応可能である.これまで分析が困難であった炭素材料の表面化学構造を本開発手法によってその詳細を把握することが可能となり,この成果は炭素材料の表面化学の理解に大きく貢献するものであり,リチウムイオン二次電池をはじめ炭素材料を利用する多くのデバイス,産業分野の発展に有用な知見を与えるものと期待される.

Report

(3 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • Research Products

    (7 results)

All 2020 2019 2018

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (5 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results)

  • [Journal Article] Understanding the chemical structure of carbon edge sites by using deuterium-labeled temperature-programmed desorption technique2020

    • Author(s)
      Ishii Takafumi、Ozaki Jun-ichi
    • Journal Title

      Carbon

      Volume: 161 Pages: 343-349

    • DOI

      10.1016/j.carbon.2020.01.079

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An analysis of the molecular structure of graphite by estimating the small number of edge sites2018

    • Author(s)
      Takafumi Ishii, Jun-ichi Ozaki, Takashi Kyotani
    • Journal Title

      Tanso

      Volume: 285 Issue: 285 Pages: 222-226

    • DOI

      10.7209/tanso.2018.222

    • NAID

      130007531070

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Presentation] An analysis of chemical structure of carbon edge sites by using deuterium‐labeling temperature‐programmed desorption technique2019

    • Author(s)
      Takafumi Ishii
    • Organizer
      Carbon 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] MOLECULAR UNDERSTANDING OF THE ACTIVE SITES ON BN-DOPED CARBON CATALYSTS FOR OXYGEN REDUCTION REACTION2018

    • Author(s)
      Takafumi Ishii
    • Organizer
      Carbon 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 重水素標識昇温脱離分析によるエッジ面の化学構造解析2018

    • Author(s)
      石井孝文
    • Organizer
      第45回炭素材料学会年会
    • Related Report
      2018 Research-status Report
  • [Presentation] 炭素酸化反応におけるエッジ面の化学構造変化2018

    • Author(s)
      石井孝文
    • Organizer
      第45回炭素材料学会年会
    • Related Report
      2018 Research-status Report
  • [Presentation] 昇温脱離分析による炭素材料の化学構造解析2018

    • Author(s)
      石井孝文
    • Organizer
      第11回酸化グラフェンシンポジウム
    • Related Report
      2018 Research-status Report
    • Invited

URL: 

Published: 2018-04-23   Modified: 2021-02-19  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi