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Measurement of the impurity diffusion coefficient of B in Fe by the deboronizing method

Research Project

Project/Area Number 18K18930
Research Category

Grant-in-Aid for Challenging Research (Exploratory)

Allocation TypeMulti-year Fund
Review Section Medium-sized Section 26:Materials engineering and related fields
Research InstitutionTohoku University

Principal Investigator

Sekido Nobuaki  東北大学, 工学研究科, 准教授 (10462516)

Project Period (FY) 2018-06-29 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2019: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2018: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywords鉄鋼材料 / ボロン / 拡散係数 / 固溶限 / 定量分析 / rf-GD-OES / 高周波グロー放電発光分光分析 / 拡散 / 鉄鋼 / 軽元素
Outline of Final Research Achievements

The solubility of B in Fe was determined by the diffusion-couple method using rf-GD-OES. The maximum solubility of B in γFe was about 60 ppm, while that in αFe was about 10 ppm in the Fe-B binary system.
The B diffusivity was estimated from the rate of deboronizing that occurs during annealing in a wet hydrogen atmosphere. The diffusion coefficient of B in αFe at around 1000℃ was almost the same as that in γFe. These coefficients were several orders of magnitude higher than that of the self-diffusion of Fe, but the activation energy of B diffusion in Fe was close to that of the self-diffusion of Fe. It was suggested that the deboronizing reaction was kinetically controlled by the corresponding surface reaction, not by the B diffusivity in Fe.

Academic Significance and Societal Importance of the Research Achievements

FeにおけるBの合金元素効果を理解し,また組織発達過程を計算科学により再現するためには,拡散係数は不可欠な基礎データである。過去に報告されたデータは信頼性が低いが,本研究により,正確に拡散係数の測定を難しくしている要因を明確にすることができた.今後は,表面反応を考慮した脱B現象のモデルを検討する,あるいは表面反応が活性化すると考えられる高温域で測定するという,脱Bによる拡散係数測定の精度を向上させるための指針を得ることができた.

Report

(3 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • Research Products

    (7 results)

All 2020 2019

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (5 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results)

  • [Journal Article] Evaluation of Boron Solubility in Iron Solid Solution by Radio-frequency Glow-discharge Optical Emission Spectroscopy2020

    • Author(s)
      Sekido Nobuaki、Kimura Yuta、Osanai Takumi、Miyagi Toshimi、Numakura Hiroshi、Yoshimi Kyosuke
    • Journal Title

      Tetsu-to-Hagane

      Volume: 106 Issue: 6 Pages: 292-301

    • DOI

      10.2355/tetsutohagane.TETSU-2019-114

    • NAID

      130007849755

    • ISSN
      0021-1575, 1883-2954
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] MICROSTRUCTURE EVOLUTION IN A HIGH-BORON FERRITIC STEEL DURING CREEP AT 650°C2019

    • Author(s)
      Nobuaki Sekido、Tomoyuki Hatta、Kouichi Maruyama、Kyosuke Yoshim、Mitsuharu Yonemura
    • Journal Title

      Proceedings from EPRI’s 9th International Conference on Advances in Materials Technology for Fossil Power Plants and the 2nd International 123HiMAT Conference on High-Temperature Materials

      Volume: 1 Pages: 156-161

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Presentation] MICROSTRUCTURE EVOLUTION IN A HIGH-BORON FERRITIC STEEL DURING CREEP AT 650°C2019

    • Author(s)
      Nobuaki Sekido、Tomoyuki Hatta、Kouichi Maruyama、Kyosuke Yoshim、Mitsuharu Yonemura
    • Organizer
      2nd International 123HiMAT Conference on High-Temperature Materials
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 650℃と700℃でクリープ変形したB添加9Cr鋼の組織変化2019

    • Author(s)
      関戸信彰、八田智之、土屋裕祐、丸山公一、吉見享祐、米村光治
    • Organizer
      日本鉄鋼協会 第178回秋季講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] γ鉄における B の固溶限と拡散性2019

    • Author(s)
      関戸信彰、木村勇太、宮城俊美、沼倉宏、吉見享祐
    • Organizer
      日本鉄鋼協会 第177回春季講演大会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] α-Fe中におけるBの固溶度と拡散性に関する実験的研究2019

    • Author(s)
      小山内匠、関戸信彰、吉見享祐
    • Organizer
      日本鉄鋼協会 第178回秋季講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] γ鉄におけるBの固溶限と拡散性2019

    • Author(s)
      関戸信彰, 木村勇太, 宮城俊美, 沼倉宏, 吉見享祐
    • Organizer
      日本鉄鋼協会第177回春季講演大会
    • Related Report
      2018 Research-status Report

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Published: 2018-07-25   Modified: 2021-02-19  

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