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Fabrication of graphene/graphene-nanoribbon superconductors

Research Project

Project/Area Number 18K18986
Research Category

Grant-in-Aid for Challenging Research (Exploratory)

Allocation TypeMulti-year Fund
Review Section Medium-sized Section 28:Nano/micro science and related fields
Research InstitutionTohoku University

Principal Investigator

Katsuaki Sugawara  東北大学, 理学研究科, 准教授 (70547306)

Project Period (FY) 2018-06-29 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Fiscal Year 2019: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2018: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywordsグラフェン / グラフェンナノリボン / 超伝導 / ARPES
Outline of Final Research Achievements

To realize monolayer graphene and graphene-nanoribbon superconductors and the mechanism of superconducting transition, I have fabricated a alkali-metal-coated monolayer graphene and graphene nanoribbon by molecular-beam epitaxy and performed high-resolution angle-resolved photoemission spectroscopy (ARPES). After depositing a potassium atom onto a monolayer graphene substrate, we found not only a folded Dirac-electron state due to a periodic potential of 2x2 superstructure but also a novel free-electron like two-dimensional electron gas. It has been well known that the free-electron like state plays an important rule for a superconductivity in graphite intercalation compounds (GICs). Surprisingly, I found that the folded Dirac-electron state and free-electron like state may be hybridized near the Fermi levels. These results suggests that the superconductivity in the metal coated graphene materials is induced by hybridization between Dirac electron and free-electron like state.

Academic Significance and Societal Importance of the Research Achievements

これまで世界中の研究者誰もが原子層グラフェンの超伝導化が実現出来なかった背景を考慮すると、本研究によって、ディラック電子状態のみならず自由電子的2次元電子ガスの両方が必要であるという研究結果を得られたことは、今後グラフェンにおける新たな新規物性を誘起する上で重要な成果と考えていえる。
グラフェンやグラフェンナノリボンは「強固、軽量、高熱伝導、フレキシブル、透明、高電気伝導」と様々な機能性を有しているが、それらの一つ高電気伝導性を超伝導に置き換えることができれば、量子コンピューターなどの産業応用に多大な影響を与えるだけでなく、今後のグラフェン超伝導の研究が世界的に拡がることが期待できる。

Report

(3 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • Research Products

    (30 results)

All 2020 2019 2018

All Journal Article (13 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 13 results,  Open Access: 4 results) Presentation (15 results) (of which Int'l Joint Research: 8 results,  Invited: 7 results) Book (2 results)

  • [Journal Article] Anomalous Hall effect at the spontaneously electron-doped polar surface of PdCoO2 ultrathin films2020

    • Author(s)
      Harada T.、Sugawara K.、Fujiwara K.、Kitamura M.、Ito S.、Nojima T.、Horiba K.、Kumigashira H.、Takahashi T.、Sato T.、Tsukazaki A.
    • Journal Title

      Physical Review Research

      Volume: 2 Issue: 1 Pages: 1-6

    • DOI

      10.1103/physrevresearch.2.013282

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Conversion of a conventional superconductor into a topological superconductor by topological proximity effect2020

    • Author(s)
      Trang C. X.、Shimamura N.、Nakayama K.、Souma S.、Sugawara K.、Watanabe I.、Yamauchi K.、Oguchi T.、Segawa K.、Takahashi T.、Ando Yoichi、Sato T.
    • Journal Title

      Nature Communications

      Volume: 11 Issue: 1 Pages: 1-6

    • DOI

      10.1038/s41467-019-13946-0

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Dichotomy of superconductivity between monolayer FeS and FeSe2019

    • Author(s)
      Shigekawa Koshin、Nakayama Kosuke、Kuno Masato、Phan Giao N.、Owada Kenta、Sugawara Katsuaki、Takahashi Takashi、Sato Takafumi
    • Journal Title

      Proceedings of the National Academy of Sciences

      Volume: 116 Issue: 49 Pages: 24470-24474

    • DOI

      10.1073/pnas.1912836116

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Electronic structure of a Bi2Te3/FeTe heterostructure: Implications for unconventional superconductivity2019

    • Author(s)
      Owada Kenta、Nakayama Kosuke、Tsubono Ryuji、Shigekawa Koshin、Sugawara Katsuaki、Takahashi Takashi、Sato Takafumi
    • Journal Title

      Physical Review B

      Volume: 100 Issue: 6 Pages: 1-5

    • DOI

      10.1103/physrevb.100.064518

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dimensionality reduction and band quantization induced by potassium intercalation in 1T-HfTe22019

    • Author(s)
      Nakata Y.、Sugawara K.、Chainani A.、Yamauchi K.、Nakayama K.、Souma S.、Chuang P.-Y.、Cheng C.-M.、Oguchi T.、Ueno K.、Takahashi T.、Sato T.
    • Journal Title

      Physical Review Materials

      Volume: 3 Issue: 7 Pages: 1-6

    • DOI

      10.1103/physrevmaterials.3.071001

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Monolayer VTe2: Incommensurate Fermi surface nesting and suppression of charge density waves2019

    • Author(s)
      Sugawara Katsuaki、Nakata Yuki、Fujii Kazuki、Nakayama Kosuke、Souma Seigo、Takahashi Takashi、Sato Takafumi
    • Journal Title

      Physical Review B

      Volume: 99 Issue: 24 Pages: 1-6

    • DOI

      10.1103/physrevb.99.241404

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Vortex-induced quantum metallicity in the mono-unit-layer superconductor NbSe22019

    • Author(s)
      Ichinokura Satoru、Nakata Yuki、Sugawara Katsuaki、Endo Yukihiro、Takayama Akari、Takahashi Takashi、Hasegawa Shuji
    • Journal Title

      Physical Review B

      Volume: 99 Issue: 22 Pages: 1-7

    • DOI

      10.1103/physrevb.99.220501

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Weak localization in bilayer graphene with Li-intercalation/desorption2018

    • Author(s)
      Y. Endo, S. Ichinokura, R. Akiyama, A. Takayama, K. Sugawara, K. Nomura, T. Takahashi, S. Hasegawa,
    • Journal Title

      J. Phys.: Condens. Matter

      Volume: 30 Issue: 30 Pages: 3057011-7

    • DOI

      10.1088/1361-648x/aaccc4

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ultrathin Bismuth Film on High-Temperature Cuprate Superconductor Bi2Sr2CaCu2O8+δ as a Candidate of a Topological Superconductor2018

    • Author(s)
      Shimamura Natsumi、Sugawara Katsuaki、Sucharitakul Sukrit、Souma Seigo、Iwaya Katsuya、Nakayama Kosuke、Trang Chi Xuan、Yamauchi Kunihiko、Oguchi Tamio、Kudo Kazutaka、Noji Takashi、Koike Yoji、Takahashi Takashi、Hanaguri Tetsuo、Sato Takafumi
    • Journal Title

      ACS Nano

      Volume: 12 Issue: 11 Pages: 10977-10983

    • DOI

      10.1021/acsnano.8b04869

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ultrathin Bismuth Film on 1T-TaS2: Structural Transition and Charge-Density-Wave Proximity Effect2018

    • Author(s)
      Yamada Keiko、Souma Seigo、Yamauchi Kunihiko、Shimamura Natsumi、Sugawara Katsuaki、Trang Chi Xuan、Oguchi Tamio、Ueno Keiji、Takahashi Takashi、Sato Takafumi
    • Journal Title

      Nano Letters

      Volume: 18 Issue: 5 Pages: 3235-3240

    • DOI

      10.1021/acs.nanolett.8b01003

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Selective Fabrication of Mott-Insulating and Metallic Monolayer TaSe22018

    • Author(s)
      Y. Nakata, T. Yoshizawa, K. Sugawara, Y. Umezawa, T. Takahashi and T. Sato
    • Journal Title

      ACS Applied Nano Materials

      Volume: 印刷中 Issue: 4 Pages: 1456-1460

    • DOI

      10.1021/acsanm.8b00184

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Anisotropic band splitting in monolayer NbSe2: implications for superconductivity and charge density wave2018

    • Author(s)
      Nakata Yuki、Sugawara Katsuaki、Ichinokura Satoru、Okada Yoshinori、Hitosugi Taro、Koretsune Takashi、Ueno Keiji、Hasegawa Shuji、Takahashi Takashi、Sato Takafumi
    • Journal Title

      npj 2D Materials and Applications

      Volume: 2 Issue: 1 Pages: 1-6

    • DOI

      10.1038/s41699-018-0057-3

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Pseudogap, Fermi arc, and Peierls-insulating phase induced by 3D?2D crossover in monolayer VSe22018

    • Author(s)
      Umemoto Yuki、Sugawara Katsuaki、Nakata Yuki、Takahashi Takashi、Sato Takafumi
    • Journal Title

      Nano Research

      Volume: 12 Issue: 1 Pages: 165-169

    • DOI

      10.1007/s12274-018-2196-4

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Presentation] 原子層TiSe2-xの高分解能ARPES2020

    • Author(s)
      菅原克明, 中田優樹, 川上竜平, 佐藤匠, 田口大樹, 加藤剛臣, 高橋隆, 佐藤宇史
    • Organizer
      日本物理学会2020年年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Electronic structure of monolayer VTe2 film studed by ARPES2020

    • Author(s)
      K. Sugawara, Y. Nakata, K. Fujii, K. Nakayama, Seigo Souma, T. Takahashi, and T. Sato
    • Organizer
      The 3rd Symposium for The Core Research Clusters for Materials Science and Spintronics
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] High-resolution ARPES studies of atomic-layer TMDs controlled crystal structure2019

    • Author(s)
      K. Sugawara
    • Organizer
      Carrier doping in two-dimensional layered materials、Centro Congressi Federico II
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Electronic structure of atomic-layer VSe2 studied by ARPES2019

    • Author(s)
      K. Sugawara, Y. Umemoto, Y. Nakata, T. Takahashi, and T. Sato
    • Organizer
      Recent Progress in Graphene Research 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] VX2(X=Se, Te)原子層薄膜のCDW相転移:高分解能ARPES2019

    • Author(s)
      菅原克明, 中田優樹, 藤井和樹, 中山耕輔, 相馬清吾, 高橋隆, 佐藤宇史
    • Organizer
      日本物理学会2019年秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 原子層VSe2の高分解能ARPES2019

    • Author(s)
      菅原克明, 中田優樹, 梅本侑煇,高橋隆, 佐藤宇史
    • Organizer
      第32回日本放射光学会年会・放射光科学合同シンポジウム
    • Related Report
      2018 Research-status Report
  • [Presentation] Electronic structure of monolayer VSe2 studied by high-resolution ARPES2019

    • Author(s)
      Katsuaki Sugawara, Yuki Umemoto, Yuki Nakata, T. Takahashi, and T. Sato
    • Organizer
      The 2nd Symposium for World Leading Research Centers
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] High-resolution ARPES studies of group-V atomic-layer transition metal dichlcogenides2019

    • Author(s)
      K. Sugawara
    • Organizer
      2nd International Workshop on 2D Materials
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] グラフェン上の遷移金属ダイカルコゲナイド原子層の高分解能ARPES2019

    • Author(s)
      菅原克明
    • Organizer
      日本物理学会第74回年次大会
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] 2層グラフェン上のTaSe2原子層の高分解能ARPES2018

    • Author(s)
      菅原克明, 中田優樹, 吉澤拓也, 梅本侑煇, 高橋隆, 佐藤宇史
    • Organizer
      日本物理学会2018年秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Electronic structure of monolayer TiSe2 studied by high-resolution ARPES2018

    • Author(s)
      Katsuaki Sugawara, Yuki Nakata, Yuki Umemoto, T. Takahashi, and T. Sato
    • Organizer
      The 14th International Conference on Atomically Controlled Surfaces, Interfaces and Nanostructures and The 26th International Colloquium on Scanning Probe Microscopy
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Superconducting graphene2018

    • Author(s)
      K. Sugawara, T. Takahashi
    • Organizer
      12th International Conference on Materials and Mechanisms of Superconductivity and High Temperature Superconductors
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 遷移金属ダイカルコゲナイド原子層の高分解能ARPES2018

    • Author(s)
      菅原克明
    • Organizer
      第1回新奇二次元デバイス・物質科学ワークショップ
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] High-resolution ARPES studies of 2D materials related superconductors2018

    • Author(s)
      K. Sugawara
    • Organizer
      First International Workshop on 2D Materials
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] High-resolution ARPES studies of atomic-layer transition metal dichlcogenides2018

    • Author(s)
      K. Sugawara
    • Organizer
      3RD-JPAN-EU FLAGSHIP WORKSHOP ON GRAPHENE AND RELATED 2D MATERILS
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Book] グラフェンから広がる二次元物質の新技術と応用2020

    • Author(s)
      菅原 克明,高橋 隆,佐藤 宇史
    • Publisher
      エヌ・ティー・エス
    • Related Report
      2019 Annual Research Report
  • [Book] 放射光利用の手引き、第4部2019

    • Author(s)
      菅原克明, 高橋隆
    • Publisher
      アグネ技術センター
    • Related Report
      2019 Annual Research Report 2018 Research-status Report

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Published: 2018-07-25   Modified: 2021-02-19  

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