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Development of HfO2-based ferroelectric films for Piezo MEMS applications

Research Project

Project/Area Number 18K19016
Research Category

Grant-in-Aid for Challenging Research (Exploratory)

Allocation TypeMulti-year Fund
Review Section Medium-sized Section 29:Applied condensed matter physics and related fields
Research InstitutionTokyo Institute of Technology

Principal Investigator

Funakubo Hiroshi  東京工業大学, 物質理工学院, 教授 (90219080)

Project Period (FY) 2018-06-29 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2019: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2018: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Keywords酸化ハフニウム基強誘電体 / 圧電性 / HfO2基強誘電体
Outline of Final Research Achievements

This study tries to grow thick ferroelectric HfO2 films for Piezo MEMS applications. 1 micrometer-thick ferroelectric HfO2-based films were successfully grown. Ferroelectric property of these films was almost independent of the film thickness. Moreover, epitaxial films with {100} orientation were obtained on (100)ITO//(100)YSZ and (100)ITO//(100)YSZ/(100)Si substrates. Piezoresponse of these films was 2-3 pm/V. Finally, a micrometer -thick ferroelectric films were obtained even by room temperature deposition.

Academic Significance and Societal Importance of the Research Achievements

HfO2はトランジスターのゲート酸化物で実用になっており、Si基の半導体プロセスと高い親和性を有する。従来の圧電体はこのプロセスとの親和性が低く、圧電MEMSの実用化はなかなか進んでこなかった。本研究によって、HfO2基の強誘電体が圧電MEMSで必要な1μmまでの厚膜化が実現できたこと、室温プロセスが実現できたことは、圧電MEMSへのHfO2の応用の可能性を開いた研究と言え、その社会的意義は大きい。

Report

(3 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • Research Products

    (27 results)

All 2020 2019 2018 Other

All Int'l Joint Research (1 results) Journal Article (7 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 7 results) Presentation (15 results) (of which Int'l Joint Research: 10 results,  Invited: 2 results) Remarks (2 results) Patent(Industrial Property Rights) (2 results)

  • [Int'l Joint Research] 国立宇宙物理・光学・電子研究所(メキシコ)

    • Related Report
      2019 Annual Research Report
  • [Journal Article] Room-temperature deposition of ferroelectric HfO2-based films by the sputtering method2020

    • Author(s)
      Takanor Mimura, Takao Shimizu, Hiroshi Uchida, Hiroshi Funakubo
    • Journal Title

      Applied Physics Letters

      Volume: 116 Issue: 6 Pages: 062901-062901

    • DOI

      10.1063/1.5140612

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thickness- and orientation- dependences of Curie temperature in ferroelectric epitaxial Y doped HfO2 films2020

    • Author(s)
      Takanori Mimura, Takao Shimizu, Yoshio Katsuya, Osami Sakata, Hiroshi Funakubo
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 59 Issue: SG Pages: SGGB04-SGGB04

    • DOI

      10.35848/1347-4065/ab6d84

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] NiSi2 as a bottom electrode for enhanced endurance of ferroelectric Y-doped HfO2 thin films2020

    • Author(s)
      Joel Molina-Reyes, Takuya Hoshii, Shun-Ichiro Ohmi, Hiroshi Funakubo, Atsushi Hori, Ichiro Fujiwara, Hitoshi Wakabayashi, Kazuo Tsutsui, Kuniyuki Kakushima
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 59 Issue: SG Pages: SGGB06-SGGB06

    • DOI

      10.35848/1347-4065/ab6b7c

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Preparation of near-1-mm-thick {100}-oriented epitaxial Y-doped HfO2 ferroelectric films on (100)Si substrates by an RF magnetron sputtering method2020

    • Author(s)
      Reijiro Shimura, Takanori Mimura, Takao Shimizu, Yoshitomo Tanaka, Yukari Inoue, Hiroshi Funakubo
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: -

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of the orthorhombic phase in CeO2-HfO2 solid solution epitaxial thin films and their ferroelectric properties2019

    • Author(s)
      Shiraishi T.、Choi S.、Kiguchi T.、Shimizu T.、Funakubo H.、Konno T. J.
    • Journal Title

      Applied Physics Letters

      Volume: 114 Issue: 23 Pages: 232902-232902

    • DOI

      10.1063/1.5097980

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ferroelectricity in YO1.5-HfO2 films around 1μm in thickness2019

    • Author(s)
      Takanori Mimura, Takao Shimizu, Hiroshi Funakubo
    • Journal Title

      Applied Physics Letters

      Volume: 115 Issue: 3 Pages: 032901-032901

    • DOI

      10.1063/1.5097880

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thickness-dependent crystal structure and electric properties of epitaxial ferroelectric Y2O3-HfO2 films2018

    • Author(s)
      Takanori Mimura, Takao Shimizu, Hiroshi Uchida, Osami Sakata, and Hiroshi Funakubo
    • Journal Title

      Appl. Phys. Lett.

      Volume: 113 Issue: 10 Pages: 102901-102901

    • DOI

      10.1063/1.5040018

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Presentation] HfO2基薄膜のZr, Yドープによる結晶相変化と強誘電相の安定性2020

    • Author(s)
      田代裕貴、三村和仙、清水荘雄、勝矢良雄、坂田修身、木口賢紀、白石貴久、今野豊彦、舟窪浩
    • Organizer
      第58回セラミックス基礎科学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] エピタキシャルHfO2基膜を用いた直方晶相安定化の調査2020

    • Author(s)
      三村和仙、清水荘雄、舟窪浩
    • Organizer
      第67回応用物理学会春季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] スパッタリング法によるHfO2基強誘電体厚膜の室温製膜とその電気特性評価2020

    • Author(s)
      志村礼司郎、三村和仙、舘山明紀、清水荘雄、舟窪浩
    • Organizer
      第67回応用物理学会春季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Robust ferroelectricity in thick HfO2-based film2019

    • Author(s)
      Takao Shimizu, Takanori Mimura, Hiroshi Funakubo
    • Organizer
      STAC-11 (The 11th International Conference on the Science and Technology for Advanced Ceramics)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Robust Ferroelectricity in Y-Doped HfO2 Films2019

    • Author(s)
      Takao Shimizu, Takanori Mimura, Hiroshi Funakubo
    • Organizer
      F2cπ2 2019 (Joint ISAF-ICE-EMF-IWPM-PFM meeting 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thickness-dependent crystal structure of epitaxial ferroelectric 0.07YO1.5-0.93HfO2 and HZO films2019

    • Author(s)
      Takanori Mimura, Takao Shimizu, Hiroshi Funakubo
    • Organizer
      ISIF 2019 (7th International Symposium on Intagrated Functionalities)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thickness- and orientation-dependence of Curie temperature of ferroelectric epitaxial HfO2 based films2019

    • Author(s)
      T. Mimura, T. Shimizu, Y. Katsuya, O. Sakata, H. Funakubo
    • Organizer
      SSDM 2019 (2019 International Conference on Solid State Devices and Materials)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] スパッタリング法を用いたY:HfO2強誘電体膜の室温成膜2019

    • Author(s)
      三村和仙、清水荘雄、舟窪浩
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] HfO2基薄膜の電界誘起相転移2019

    • Author(s)
      田代裕貴、三村和仙、清水荘雄、勝矢良雄、坂田修身、木口賢紀、白石貴久、今野豊彦、舟窪浩
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Preparation and characterization of Y, Zr-doped HfO2 thin films by PLD method2019

    • Author(s)
      Yu-ki Tashiro, Takanori Mimura, Takao Shimizu, Hiroshi Funakubo
    • Organizer
      CJFMA11 (The 11th China and Japan Symposium on Ferroelectric Materials and Their Applications)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] The phase stability and epitaxial growth of HfO2-based ferroelectric materials2019

    • Author(s)
      Takao Shimizu, Takanori Mimura, Hiroshi Funakubo
    • Organizer
      PACRIM13 (The 13th Pacific Rim Conference of Ceramic Societies)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Preparation and Characterization of Y, Zr-doped HfO2 Thin Film by PLD Method2019

    • Author(s)
      Yu-ki Tashiro, Takanori Mimura, Takao Shimizu, Hiroshi Funakubo
    • Organizer
      19th US-Japan Seminar on Dielectric and Piezoelectric Ceramics
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Recent Progress on Ferroelectric HfO2 Epitaxial Films2019

    • Author(s)
      Takao Shimizu, Takanori Mimura, Hiroshi Funakubo
    • Organizer
      19th US-Japan Seminar on Dielectric and Piezoelectric Ceramics
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Stability of Ferroelectric Orthorhombic Phase in Epitaxial HfO2-based Films2019

    • Author(s)
      Takanori Mimura, Takao Shimizu, Yoshio Katsuya, Osami Sakata, Hiroshi Funakubo
    • Organizer
      19th US-Japan Seminar on Dielectric and Piezoelectric Ceramics
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Phase stability and property control of ferroelectric HfO2 films2019

    • Author(s)
      Hiroshi Funakubo, Takanori Mimura, Takao Shimizu,
    • Organizer
      MRM2019 (Materials Research Meeting 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Remarks] 東京工業大学 物質理工学院 材料系材料コース 舟窪研究室

    • URL

      http://f-lab.iem.titech.ac.jp/f-lab.htm

    • Related Report
      2019 Annual Research Report
  • [Remarks] 東京工業大学 物質理工学院 材料系 材料コース 舟窪研究室

    • URL

      http://f-lab.iem.titech.ac.jp/f-lab.htm

    • Related Report
      2018 Research-status Report
  • [Patent(Industrial Property Rights)] 強誘電性薄膜の製造方法、強誘電性薄膜、及びその用途2019

    • Inventor(s)
      舟窪浩、清水荘雄、三村和仙、中村美子
    • Industrial Property Rights Holder
      舟窪浩、清水荘雄、三村和仙、中村美子
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2019-086836
    • Filing Date
      2019
    • Related Report
      2019 Annual Research Report
  • [Patent(Industrial Property Rights)] 圧電体の製造方法、圧電体、及び圧電体素子又は装置2019

    • Inventor(s)
      舟窪浩、清水荘雄、三村和仙、中村美子
    • Industrial Property Rights Holder
      舟窪浩、清水荘雄、三村和仙、中村美子
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2019-086840
    • Filing Date
      2019
    • Related Report
      2019 Annual Research Report

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Published: 2018-07-25   Modified: 2021-02-19  

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