Exploration of long-lived triplet carbenes stabilized by porphyrin

• Project/Area Number: 18K19074
• Research Category: Grant-in-Aid for Challenging Research (Exploratory)
• Allocation Type: Multi-year Fund
• Review Section: Medium-sized Section 33:Organic chemistry and related fields
• Research Institution: Ritsumeikan University (2020); Kyoto University (2018-2019)
• Principal Investigator: Osuka Atsuhiro 立命館大学, 総合科学技術研究機構, 教授 (80127886)
• Project Period (FY): 2018-06-29 – 2021-03-31
• Project Status: Completed (Fiscal Year 2020)
• Budget Amount: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000); Fiscal Year 2019: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000); Fiscal Year 2018: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
• Keywords: カルベン / ポルフィリン / ラジカル / スピン非局在化 / 電子スピン共鳴 / 三重項カルベン / 電子共鳴スペクトル / 三重項ジラジカル / ナイトレニウムイオン

Outline of Final Research Achievements

A stable carbene molecule stabilized by two porphyrin units was designed. Diporphyrinylmethyl diazomethane was thought to be a promising precursor and the synthesis was attempted by nitroxylation of diporphyrinylmethylcarbamate or oxidation of diporphyrinylmethylhydrazine. Although the desired product was not isolated, the reaction outcome suggests generation of the carbene in the mixture, which was not stable enough to survive under ambient conditions.

Academic Significance and Societal Importance of the Research Achievements

本研究は、不安定化学種であるカルベンが、ポルフィリンの大きなパイ共役系に組み込まれることで熱力学的に安定化されることを期待した挑戦的な研究であり、目的としたカルベン種の単離には至らなかったが前駆体合成に至る新規合成ルートの開拓や、ポルフィリンによる開殻系化合物の安定化効果を調べる上で重要な知見を与えた。今後これらの知見を生かして新たな開殻系化合物の合成を試みたり、機能性パイ共役化合物の設計に活かされることが期待される。

Research Products

• [Int'l Joint Research] Yonsei University(韓国)
• [Int'l Joint Research] Chalmers University of Technology(スウェーデン)
• [Int'l Joint Research] Hunan Normal University(中国)
• [Journal Article] A Robust Porphyrin‐Stabilized Triplet Carbon Diradical (2021)
  • Author(s): K. Wang, P. Liu, F. Zhang, L. Xu, M. Zhou, A. Nakai, K. Kato, K. Furukawa, T. Tanaka, A. Osuka, J. Song
  • Journal Title: Angew. Chem. Int. Ed. Volume: 60 Issue: 13 Pages: 7002-7006
  • DOI: 10.1002/anie.202015356
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Helically Twisted Benzene-1,3,5-triamine-fused Porphyrin Dimers (2020)
  • Author(s): Kato Kenichi、Osuka Atsuhiro
  • Journal Title: Chemistry Letters Volume: － Issue: 5 Pages: 517-520
  • DOI: 10.1246/cl.200115
  • NAID: 130007840181
  • Peer Reviewed / Open Access
• [Journal Article] Stable meso-meso Linked 2NH-Corrole Radical Dimers as a Key Intermediate to Corrole Tape (2020)
  • Author(s): S. Ooi, B. Adinarayana, D. Shimizu, T. Tanaka, A. Osuka
  • Journal Title: Angew. Chem. Int. Ed. Volume: 59 Issue: 24 Pages: 9423-9427
  • DOI: 10.1002/anie.202002976
  • Peer Reviewed
• [Journal Article] meso-Free BIII Subporphyrins with Electron-donating Groups (2020)
  • Author(s): Y. Bekki, A. Osuka
  • Journal Title: Chem. Asian J. Volume: N/A Issue: 10 Pages: 1580-1589
  • DOI: 10.1002/asia.202000288
  • Peer Reviewed
• [Journal Article] Benzene- and pyridine-incorporated octaphyrins with different coordination modes toward two PdII centers (2020)
  • Author(s): Le Liu, Zhiwen Hu, Fenni Zhang, Yang Liu, Ling Xu, Mingbo Zhou, Takayuki Tanaka, Atsuhiro Osuka and Jianxin Song
  • Journal Title: Nature Communications Volume: 11 Issue: 1 Pages: 6206-6206
  • DOI: 10.1038/s41467-020-20072-9
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Propeller-shaped Semi-fused Porphyrin Trimers: Molecular-symmetry- dependent Chiroptical Response (2020)
  • Author(s): K. Kato, A. Osuka
  • Journal Title: Chem. Eur. J. Volume: 26 Issue: 45 Pages: 10217-10221
  • DOI: 10.1002/chem.202002157
  • Peer Reviewed
• [Journal Article] Excited‐state Aromaticity of Gold(III) Hexaphyrins with Metalation Effect Investigated by Time‐resolved Electronic & Vibrational Spectroscopies (2020)
  • Author(s): J. Kim, T. Soya, T. Yoneda, J. Oh, S. Park, M. Lim, A. Osuka, D. Kim
  • Journal Title: Angew. Chem. Int. Ed. Volume: 59 Issue: 13 Pages: 5129-5134
  • DOI: 10.1002/anie.201913058
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Rational Synthesis of 5,10-Diazaporphyrins via Nucleophilic Substitution Reactions of α,α’-Dibromotripyrrin and Dihydrogenation to Give 5,10-Diazachlorins (2020)
  • Author(s): M. Umetani, G. Kim, T. Tanaka, D. Kim, A. Osuka
  • Journal Title: J. Org. Chem. Volume: 85 Issue: 5 Pages: 3849-3857
  • DOI: 10.1021/acs.joc.9b03467
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Cyclophane‐type Chlorin Dimers from Dynamic Covalent Chemistry of 2,18‐Porphyrinyl Dicyanomethyl Diradicals (2020)
  • Author(s): B. Adinarayana, K. Kato, D. Shimizu, T. Tanaka, K. Furukawa, A. Osuka
  • Journal Title: Angew. Chem. Int. Ed. Volume: 49 Issue: 11 Pages: 4320-4323
  • DOI: 10.1002/anie.201914480
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] meso-(2-Pyridyl)-boron(III)-subporphyrin: Perimeter Iridium(III) Coordination (2020)
  • Author(s): G. Lavarda, D. Shimizu, T. Torres, A. Osuka
  • Journal Title: Angew. Chem. Int. Ed. Volume: 59 Issue: 8 Pages: 3127-3130
  • DOI: 10.1002/anie.201914853
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Singly and Doubly Quinoxaline-fused BIII-Subporphyrins (2019)
  • Author(s): K. Kise, A. Osuka
  • Journal Title: Chem. Eur. J. Volume: 25 Issue: 68 Pages: 15493-15497
  • DOI: 10.1002/chem.201904151
  • Peer Reviewed
• [Journal Article] Singly and Doubly Neo-confused Smaragdyrins (2019)
  • Author(s): Y. Rao, W. Zhou, L. Xu, M. Zhou, B. Yin, T. Tanaka, A. Osuka, J. Song
  • Journal Title: J. Am. Chem. Soc. Volume: 141 Issue: 47 Pages: 18836-18844
  • DOI: 10.1021/jacs.9b10270
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Phenylene‐bridged Porphyrin meso‐Oxy Radical Dimers (2019)
  • Author(s): T. Yamamoto, K. Kato, D. Shimizu, T. Tanaka, A. Osuka
  • Journal Title: Chem. Asian J. Volume: 14 Issue: 22 Pages: 4031-4034
  • DOI: 10.1002/asia.201901033
  • Peer Reviewed
• [Journal Article] Quadrupolar Cyclopenta[hi]aceanthrylene‐based Electron Donor‐Acceptor‐Donor Conjugates: Charge Transfer versus Charge Separation (2019)
  • Author(s): C. Schierl, W. Alex, L. M. Mateo, B. Ballesteros, D. Shimizu, A. Osuka, T. Torres, D. M. Guldi, G. Bottari
  • Journal Title: Angew. Chem. Int. Ed. Volume: 58 Issue: 41 Pages: 14644-14652
  • DOI: 10.1002/anie.201906206
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] 5,20-Diheterohexaphyrins: metal-template-free synthesis and aromaticity switching (2019)
  • Author(s): M. Umetani, J. Kim, T. Tanaka, D. Kim, A. Osuka
  • Journal Title: Chem. Commun. Volume: 55 Issue: 71 Pages: 10547-10550
  • DOI: 10.1039/c9cc05580k
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Electron transfer reactions in sub-porphyrin-naphthyldiimide dyads (2019)
  • Author(s): B. Kucukoz, B. Adinarayana, A. Osuka, B. Albinsson
  • Journal Title: Phys. Chem. Chem. Phys. Volume: 21 Issue: 30 Pages: 16477-16485
  • DOI: 10.1039/c9cp03725j
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Acetylene and trans-Ethylene Bridged BIII-Subporphyrin Dimers (2019)
  • Author(s): Y. Bekki, S. Kang, D. Kim, A. Osuka
  • Journal Title: Chem. Asian J. Volume: 14 Issue: 13 Pages: 2230-2234
  • DOI: 10.1002/asia.201900547
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Stable Radical versus Reversible σ-Bond Formation of (Porphyrinyl)dicyanomethyl Radicals (2019)
  • Author(s): B. Adinarayana, D. Shimizu, K. Furukawa, A. Osuka
  • Journal Title: Chem. Sci. Volume: 10 Issue: 23 Pages: 6007-6012
  • DOI: 10.1039/c9sc01631g
  • Peer Reviewed
• [Journal Article] meta-and para-Phenylenediamine-fused Porphyrin Dimers: Synthesis and Magnetic Interactions in Their Dication Diradicals (2019)
  • Author(s): K. Kato and A. Osuka
  • Journal Title: Angew. Chem. Int. Ed. Volume: 58 Issue: 25 Pages: 8546-8590
  • DOI: 10.1002/anie.201901939
  • Peer Reviewed
• [Journal Article] Synthesis, Structures, and Near‐IR Absorption of Heterole‐fused Earring Porphyrins (2019)
  • Author(s): L. Wu, F. Li, Y. Rao, B. Wen, L. Xu, M. Zhou, T. Tanaka, A. Osuka, J. Song
  • Journal Title: Angew. Chem. Int. Ed. Volume: 58 Issue: 24 Pages: 8124-8128
  • DOI: 10.1002/anie.201903446
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Metalation Control of Open-Shell Character in meso-meso Linked Porphyrin meso-Oxy Radical Dimers (2018)
  • Author(s): Jun-i Yuta、Fukui Norihito、Furukawa Ko、Osuka Atsuhiro
  • Journal Title: Chem. Eur. J. Volume: 24 Issue: 7 Pages: 1528-1532
  • DOI: 10.1002/chem.201705769
  • Peer Reviewed / Open Access
• [Journal Article] A Benzene-1,3,5-Triaminyl Radical Fused with ZnII-Porphyrins: Remarkable Stability and a High-Spin Quartet Ground State (2018)
  • Author(s): Shimizu Daiki、Osuka Atsuhiro
  • Journal Title: Angew. Chem. Int. Ed. Volume: ー Issue: 14 Pages: 3733-3736
  • DOI: 10.1002/anie.201801080
  • Peer Reviewed / Open Access
• [Journal Article] Conformational Planarization versus Singlet Fission: Distinct Excited-State Dynamics of Cyclooctatetraene-Fused Acene Dimers (2018)
  • Author(s): Yamakado Takuya、Takahashi Shota、Watanabe Kazuya、Matsumoto Yoshiyasu、Osuka Atsuhiro、Saito Shohei
  • Journal Title: Angewandte Chemie International Edition Volume: 57 Issue: 19 Pages: 5438-5443
  • DOI: 10.1002/anie.201802185
  • Peer Reviewed / Open Access
• [Journal Article] Octaphyrin bis-Silicon Complexes with 38π-, 37π-, and 36π Conjugated Systems: Aromaticity Switch and Stable Radical Cation (2018)
  • Author(s): Shin-ichiro Ishida, Jinseok Kim, Daiki Shimizu, Dongho Kim, Atsuhiro Osuka
  • Journal Title: Angewandte Chemie International Edition Volume: 印刷中 Issue: 20 Pages: 5876-5880
  • DOI: 10.1002/anie.201801986
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Synthesis, Structures, and Optical Properties of Azahelicene Derivatives and Unexpected Formation of Azahepta[8]circulenes (2018)
  • Author(s): Fengkun Chen, Takayuki Tanaka, Tadashi Mori, and Atsuhiro Osuka
  • Journal Title: Chemistry A European Journal, Volume: N/A Issue: 29 Pages: 7489-7497
  • DOI: 10.1002/chem.201800617
  • Peer Reviewed / Open Access
• [Journal Article] A 1,5-Naphthyridine-Fused Porphyrin Dimer: Intense NIR Absorption and Facile Redox Interconversion with Its Reduced Congener (2018)
  • Author(s): Keisuke Fujimoto and Atsuhiro Osuka
  • Journal Title: Chemistry a European Journal Volume: 24 Issue: 25 Pages: 6530-6553
  • DOI: 10.1002/chem.201800854
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] The First Silicon(IV) Corrole Complexes: Synthesis, Structures, Properties, and Formation of a μ-Oxo Dimer (2018)
  • Author(s): Ueta Kento、Fukuda Masaya、Kim Gakhyun、Shimizu Soji、Tanaka Takayuki、Kim Dongho、Osuka Atsuhiro
  • Journal Title: Chemistry - A European Journal Volume: 印刷中 Issue: 30 Pages: 7637-7646
  • DOI: 10.1002/chem.201800165
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] “Singly and Doubly Sulfone-inserted Porphyrin Arch-tape Dimers” (2018)
  • Author(s): N. Fukui and A. Osuka
  • Journal Title: Bull. Chem. Soc. Jpn., Volume: 91 Issue: 7 Pages: 1131-1137
  • DOI: 10.1246/bcsj.20180103
  • NAID: 130007404791
  • Peer Reviewed / Open Access
• [Journal Article] “B(III)-5-Arylsubporphyrins and B(III)-subporphine” (2018)
  • Author(s): K. Kise, K. Yoshida, R. Kotani, D. Shimizu, and A. Osuka
  • Journal Title: Chem. Eur. J., Volume: 91 Issue: 72 Pages: 19136-19140
  • DOI: 10.1002/chem.201801491
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Charge-Transfer Character Drives Mobius Antiaromaticity in the Excited Triplet State of Twisted [28]Hexaphyrin (2018)
  • Author(s): Ema Fumitoshi、Tanabe Mana、Saito Shohei、Yoneda Tomoki、Sugisaki Kenji、Tachikawa Takashi、Akimoto Seiji、Yamauchi Seigo、Sato Kazunobu、Osuka Atsuhiro、Takui Takeji、Kobori Yasuhiro
  • Journal Title: The Journal of Physical Chemistry Letters Volume: 9 Issue: 10 Pages: 2685-2690
  • DOI: 10.1021/acs.jpclett.8b00740
  • Peer Reviewed / Open Access
• [Journal Article] “Porphyrin Arch-tape Dimers with Single and Double 1,2-Phenylene Insertion: Synthesis and Highly Contorted Structures” (2018)
  • Author(s): N. Fukui and A. Osuka
  • Journal Title: Angew. Chem. Int. Ed. Volume: 57 Issue: 21 Pages: 6304-6308
  • DOI: 10.1002/anie.201802494
  • Peer Reviewed / Open Access
• [Journal Article] “Investigation and Control of Single Molecular Structures of meso-meso Linked Long Porphyrin Arrays” (2018)
  • Author(s): S. H. Lee, S. Ham, S. Nam, N. Aratani, A. Osuka, and D. Kim
  • Journal Title: J. Phys. Chem. B Volume: 122 Issue: 19 Pages: 5121-5125
  • DOI: 10.1021/acs.jpcb.8b00213
  • Peer Reviewed / Open Access
• [Journal Article] “Compression of a Flapping Mechanophore Accompanied by Thermal Void Collapse in a Crystalline Phase” (2018)
  • Author(s): T. Yamakado, K. Otsubo, A. Osuka, and S. Saito
  • Journal Title: Chem. Sci. Volume: 140 Issue: 20 Pages: 6245-6248
  • DOI: 10.1021/jacs.8b03833
  • Peer Reviewed / Open Access
• [Journal Article] “Curved π-Conjugated Corannulene Dimer Diradicaloids” (2018)
  • Author(s): Q. Wang, P. Hu, T. Tanaka, T. Y. Gopalakrishna, T. S. Herng, H. Phan, W. Zeng, J. Ding, A. Osuka, C. Chi, J. Siegel, and Jishan Wu
  • Journal Title: Chem. Sci. Volume: 9 Pages: 5100-5105
  • Peer Reviewed / Open Access
• [Journal Article] “Diarylamine-fused Subporphyrins: Proof of Twisted Intramolecu-lar Charge Transfer (TICT) Mechanism” (2018)
  • Author(s): K. Kise, Y. Hong, N. Fukui, D. Shimizu, D. Kim, and A. Osuka
  • Journal Title: Chem. Eur. J. Volume: 24 Issue: 33 Pages: 8306-8310
  • DOI: 10.1002/chem.201801576
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] “Synthesis and Characterizations of meso-Nitrocorroles” (2018)
  • Author(s): K. Ueta, T. Tanaka, and A. Osuka
  • Journal Title: Chem. Lett. Volume: 47 Issue: 7 Pages: 916-919
  • DOI: 10.1246/cl.180309
  • NAID: 130007402805
  • Peer Reviewed / Open Access
• [Journal Article] “A Stable Trimethylenemethane Triplet Diradical Based on a Trimeric Porphyrin Fused π-System” (2018)
  • Author(s): K. Kato, K. Furukawa, and A. Osuka
  • Journal Title: Angew. Chem. Int. Ed Volume: 57 Pages: 9491-9494
  • Peer Reviewed
• [Journal Article] “Stable Diporphyrinyl-Aminyl Radical and Nitrenium Ion” (2018)
  • Author(s): D. Shimizu, K. Fujimoto, and A. Osuka
  • Journal Title: Angew. Chem. Int. Ed. Volume: 57 Pages: 9434-9438
  • Peer Reviewed
• [Journal Article] “meso-Functionalizations of B(III) Subporphyrin with B(III) meso-Lithiosubporphyrin” (2018)
  • Author(s): Y. Bekki, D. Shimizu, K. Fujimoto, and A. Osuka
  • Journal Title: Chem. Eur. J. Volume: 24 Issue: 48 Pages: 1-9
  • DOI: 10.1002/chem.201802339
  • Peer Reviewed / Open Access
• [Journal Article] “Macroscopically Anisotropic Structures Produced by Lightinduced Solvothermal Assembly of Porphyrin Dimers” (2018)
  • Author(s): Y. Yamamoto, Y. Nishimura, S. Tokonami, N. Fukui, T. Tanaka, A. Osuka, H. Yorimitsu, and T. Iida
  • Journal Title: Sci. Rep. Volume: 8 Issue: 1 Pages: 11108-11108
  • DOI: 10.1038/s41598-018-28311-2
  • NAID: 120006539601
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] “Conjugated double helices via self-dimerization of α,α’-Dianilinotripyrrins” (2018)
  • Author(s): M. Umetani, T. Tanaka, and A. Osuka
  • Journal Title: J. Phys. Chem. Lett. Volume: 9 Issue: 33 Pages: 6853-6859
  • DOI: 10.1039/c8sc02739k
  • NAID: 120006534587
  • Peer Reviewed / Open Access
• [Journal Article] “Near-Infrared S2 Fluorescence from Deprotonated Mobius Aromatic [32]heptaphyrin” (2018)
  • Author(s): J. Oh Kim, Y. Hong, T. Kim, W.-Y. Cha, T. Yoneda, T. Soya, A. Osuka, and D. Kim
  • Journal Title: J. Phys. Chem. Lett. Volume: 9 Pages: 4527-4531
  • Peer Reviewed / Open Access
• [Journal Article] “Solvent and Structural Fluctuations Induced Symmetry-Breaking Charge Transfer in a Porphyrin Triad” (2018)
  • Author(s): T. Kim, W. Kim, H. Mori, A. Osuka, and D. Kim
  • Journal Title: J. Phys. Chem. C Volume: 122 Pages: 19409-19415
  • Peer Reviewed / Open Access
• [Journal Article] “A Stable Antiaromatic 5,20-Dibenzoyl [28]Hexaphyrin(1.1.1.1.1.1): Core AuIII-Metalation and Subsequent Peripheral BIII-Metalation” (2018)
  • Author(s): S.-i. Ishida, T. Soya, and A. Osuka
  • Journal Title: Angew. Chem. Int. Ed Volume: 130 Issue: 41 Pages: 13828-13831
  • DOI: 10.1002/anie.201808513
  • Peer Reviewed / Open Access
• [Journal Article] “Stable Face-to-Face Singlet Diradicaloids: Doubly u-Hydroxo-Bridged Triply-Linked Corrole Dimer Ga(III) Complexes” (2018)
  • Author(s): S. Ooi, D. Shimizu, K. Furukawa, T. Tanaka, and A. Osuka
  • Journal Title: Angew. Chem. Int. Ed Volume: 57 Issue: 45 Pages: 14916-14920
  • DOI: 10.1002/anie.201810200
  • Peer Reviewed / Open Access
• [Journal Article] Super-octazethrene: An Open-shell Graphene-Like Molecule Possessing Large Diradical Character but Still with Reasonable Stability (2018)
  • Author(s): W. Zeng, T. Y. Gopalakrishna, H. Phan, T. Tanaka, T. . Herng, J. Ding, A. Osuka, and J. Wu
  • Journal Title: J. Am. Chem. Soc. Volume: 140 Issue: 43 Pages: 14054-14058
  • DOI: 10.1021/jacs.8b09075
  • Peer Reviewed / Open Access
• [Journal Article] “Quadruply Twisted Huckel Aromatic Dodecaphyrin” (2018)
  • Author(s): T. Soya, H. Mori, and A. Osuka
  • Journal Title: Angew. Chem. Int. Ed. Volume: 57 Issue: 48 Pages: 15882-15886
  • DOI: 10.1002/anie.201811433
  • Peer Reviewed / Open Access
• [Journal Article] “meso-Triaryl-substituted Smaragdyrins: Facile Aromaticity Switching” (2018)
  • Author(s): D. Xie, Y. Liu, Y. Rao, G. Kim, M. Zhou, D. Yu, L. Xu, B. Yin, S. Liu, T. Tanaka, N. Aratani, A. Osuka, Q. Liu, D. Kim, and J. Song
  • Journal Title: J. Am. Chem. Soc. Volume: 140 Issue: 48 Pages: 16553-16559
  • DOI: 10.1021/jacs.8b07973
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Subporpholactone, Subporpholactam, Imidazolosubporphyrin, and Iridium Complexes of Imidazolosubporphyrin: Formation of Iridium Carbene Complexes (2017)
  • Author(s): Yoshida Kota、Osuka Atsuhiro
  • Journal Title: Angew. Chem. Int. Ed. Volume: 57 Issue: 1 Pages: 338-342
  • DOI: 10.1002/anie.201711166
  • Peer Reviewed / Open Access
• [Journal Article] Porphyrin-Based Air-Stable Helical Radicals (2017)
  • Author(s): Kato Kenichi、Furukawa Ko、Mori Tadashi、Osuka Atsuhiro
  • Journal Title: Chem. Eur. J. Volume: 24 Issue: 3 Pages: 572-575
  • DOI: 10.1002/chem.201705291
  • Peer Reviewed / Open Access
• [Presentation] Metalation-induced formation of novel fused porphyrinoid dimers from tetrabromo-[36]octaphyrin via transannular bond formation (2021)
  • Author(s): Akito Nakai, Takayuki Tanaka, Atsuhiro Osuka
  • Organizer: 日本化学会第101春季年会
• [Presentation] Synthesis of Novel Peripherally Fused Corannulenes via Quintuple Amination Reactions and Their Structural and Electronic Perturbations (2021)
  • Author(s): Koki Kise, Shota Ooi, Takayuki Tanaka, Atsuhiro Osuka
  • Organizer: 日本化学会第101春季年会
• [Presentation] Metalation-induced formation of novel fused porphyrinoid dimers from tetrabromo-[36]octaphyrin via transannular bond formation (2020)
  • Author(s): Akito Nakai, Takayuki Tanaka, Atsuhiro Osuka
  • Organizer: 錯体化学会第70回討論会
• [Presentation] Aza-crown-ether-incorporated subporphyrins with unique affinities to metal ions (2020)
  • Author(s): Koki Kise, Takayuki Tanaka, Atsuhiro Osuka
  • Organizer: 錯体化学会第70回討論会
• [Presentation] 超ポルフィリンの化学 (2020)
  • Author(s): 大須賀篤弘
  • Organizer: 有機合成新春講演会
  • Invited
• [Presentation] meta- and para-Phenylenediamine-fused Porphyrin Dimers: Synthesis and Magnetic Interactions in Their Dication Diradicals (2019)
  • Author(s): Kenichi Kato, Atsuhiro Osuka,
  • Organizer: ISNA-18
  • Int'l Joint Research
• [Presentation] Stable (BIII-Subporphyrin-5-yl)dicyanomethyl Radicals (2019)
  • Author(s): Bellamkonda Adinarayana, Daiki Shimizu, Atsuhiro Osuka
  • Organizer: ISNA-18
  • Int'l Joint Research
• [Presentation] Synthesis and properties of fused subporphyrins with β-nitrogen atoms (2019)
  • Author(s): Koki Kise, Atsuhiro Osuka
  • Organizer: ISNA-18
  • Int'l Joint Research
• [Presentation] Syntheses and Properties of Novel Sandwich Complexes Using Gold(III) Hexaphyrin as a Ligand (2019)
  • Author(s): Akito Nakai, Shin-ichiro Ishida, Atsuhiro Osuka
  • Organizer: ISNA-18
• [Presentation] メゾ位とベータ位の修飾に基づくドナー・アクセプター型サブポルフィリンの合成と物性 (2019)
  • Author(s): 黄瀬光稀・大須賀篤弘
  • Organizer: 第30回基礎有機化学討論会
• [Presentation] メゾ位に電子供与性の置換基を持つサブポルフィリン (2019)
  • Author(s): 戸次洋佑・大須賀篤弘
  • Organizer: 第30回基礎有機化学討論会
• [Presentation] ジアリールアミン縮環ポルフィリン二量体の合成と物性 (2019)
  • Author(s): 加藤研一・大須賀篤弘
  • Organizer: 第30回基礎有機化学討論会
• [Presentation] ヘキサフィリンπ-ルテニウム錯体の合成と物性 (2019)
  • Author(s): 中井彬人・石田真一郎・大須賀篤弘
  • Organizer: 錯体化学会第６９討論会
• [Presentation] Stable Porphyrin Radicals (2019)
  • Author(s): 大須賀篤弘
  • Organizer: ISNA-18
  • Int'l Joint Research / Invited
• [Presentation] Fusion Chemistry of Porphyrinoids (2019)
  • Author(s): Atsuhiro Osuka
  • Organizer: ACPP-1
  • Int'l Joint Research / Invited
• [Presentation] Stable Porphyrin Radicals (2019)
  • Author(s): Atsuhiro Osuka
  • Organizer: 18th ACC
  • Int'l Joint Research / Invited
• [Presentation] ジポルフィリニルアミニルラジカル－ニッケル二核錯体とその配位誘起スピンクロスオーバー挙動 (2019)
  • Author(s): 清水大貴・大須賀篤弘
  • Organizer: 日本化学会第99春季年会
• [Presentation] 求核置換反応を用いた5,10-ジアザポルフィリンの合成 (2019)
  • Author(s): 梅谷将隆・田中隆行・大須賀篤弘
  • Organizer: 日本化学会第99春季年会
• [Presentation] ジアリールアミン縮環ポルフィリン二量体の合成とジカチオンジラジカル種における分子内磁性相互作用 (2019)
  • Author(s): 加藤研一・大須賀篤弘
  • Organizer: 日本化学会第99春季年会
• [Presentation] メゾ位にジフェニルアミノ基を有するコロール誘導体の合成 (2019)
  • Author(s): 植田賢人・田中隆行・大須賀篤弘
  • Organizer: 日本化学会第99春季年会
• [Presentation] 単一分子蛍光による力解析に向けた柔軟なV字型メカノフォアの開発 (2019)
  • Author(s): 山角拓也・後藤祐真・Martin Vacha・齊藤尚平・大須賀篤弘
  • Organizer: 日本化学会第99春季年会
• [Presentation] キノキサリン縮環サブポルフィリン類の合成と物性 (2019)
  • Author(s): 黄瀬光稀・大須賀篤弘
  • Organizer: 日本化学会第99春季年会
• [Presentation] π拡張した発光性7員環オキセピンの励起状態における構造平面化 (2019)
  • Author(s): 小谷亮太・Liu Pengpeng・齊藤尚平・大須賀篤弘
  • Organizer: 日本化学会第99春季年会
• [Presentation] ヘキサフィリン金二核錯体を配位子とした新規なダブルデッカー錯体の合成と物性 (2019)
  • Author(s): 中井彬人・石田真一郎・大須賀篤弘
  • Organizer: 日本化学会第99春季年会
• [Presentation] 羽ばたく蛍光分子の金属錯体形成および刺激応答性 (2019)
  • Author(s): 北鹿渡秀嗣・齊藤尚平・大須賀篤弘
  • Organizer: 日本化学会第99春季年会
• [Presentation] 新規ヘテロ[8]サーキュレン分子の合成とその物性 (2019)
  • Author(s): 松尾悠佑・黄瀬光稀・田中隆行・大須賀篤弘
  • Organizer: 日本化学会第99春季年会
• [Presentation] ８の字型オクタフィリンGe二核錯体の合成とそのキラル特性 (2019)
  • Author(s): 水藤泰介・井澤主水・清水大貴・田中隆行・大須賀篤弘
  • Organizer: 日本化学会第99春季年会
• [Presentation] ペリレンイミド骨格をもつ羽ばたく蛍光分子の開発と励起状態ダイナミクス (2019)
  • Author(s): 木村 僚・劉 鵬鵬・倉持 光・田原太平・齊藤尚平・大須賀篤弘
  • Organizer: 日本化学会第99春季年会
• [Presentation] アセチレン及びトランスエチレン架橋サブポルフィリン二量体の合成と物性 (2019)
  • Author(s): 戸次洋佑・大須賀篤弘
  • Organizer: 日本化学会第99春季年会
• [Presentation] Stable Porphyrin Radicals (2018)
  • Author(s): Atsuhiro Osuka,Kenichi Kato, Daiki Shimizu
  • Organizer: ICPP10
  • Int'l Joint Research / Invited
• [Presentation] u-Oxo-Bridged Dimers of Metallocorroles (2018)
  • Author(s): Takayuki Tanaka,Kento Ueta,Shota Ooi,Atsuhiro Osuka
  • Organizer: ICPP10
  • Int'l Joint Research / Invited
• [Presentation] 1,2-Phenylene-Inserted porphyrin Arch-Tape Dimers (2018)
  • Author(s): Norihito Fukui,Atsuhiro Osuka
  • Organizer: ICPP10
  • Int'l Joint Research
• [Presentation] A Benzene-1,3,5-triaminyl Radical Fused with Zn(Ⅱ)-Porphyrins;Rmarkable Stability and High Spin Quartet Ground State (2018)
  • Author(s): Daiki Shimizu,Atsuhiro Osuka
  • Organizer: ICPP10
  • Int'l Joint Research
• [Presentation] Stable Trimethylenemethane Diradicak Embedded in Porphyrin-Based Fused π-Framework (2018)
  • Author(s): Kenichi Kato,Ko Fukuzawa,Atsuhiro Osuka
  • Organizer: ICPP10
  • Int'l Joint Research
• [Presentation] Synthesis of Novel Heteroporphyrinoids Using Dibromotripyrrin as a Precursor (2018)
  • Author(s): Masataka Umetani,Takayuki Tanaka,AtsuhiroOsuka
  • Organizer: ICPP10
  • Int'l Joint Research
• [Presentation] meso-Aryl Corrole Silicon(Ⅳ)Complexes (2018)
  • Author(s): Kento Ueta,Masaya Fukuda,Gakhyun Kim,Soji Shimizu,Takayuki Tanaka,Dongho Kim,Atsuhiro Osuka
  • Organizer: ICPP10
  • Int'l Joint Research
• [Presentation] Synthesis and Characterization of Diarylamine-Fused Subporphyrins (2018)
  • Author(s): Koki Kise,AtsuhironOsuka
  • Organizer: ICPP10
  • Int'l Joint Research
• [Presentation] Synthesis and Properties of Phenylene-Bridged Porphyrin meso-Oxy Radical Oligomers (2018)
  • Author(s): Takayuki Yamamoto,Daiki Shimizu,Ko Furukawa,Atsuhiro Osuka
  • Organizer: ICPP10
  • Int'l Joint Research
• [Presentation] Fusion Chemistry of Porphyrinoids (2018)
  • Author(s): 大須賀篤弘
  • Organizer: 有機合成化学協会中国四国支部パネル討論会
  • Invited
• [Presentation] Synthesis and Properties of Quadruply Twisted Huckel Aromatic Molecules (2018)
  • Author(s): Takanori Soya, Atsuhiro Osuka
  • Organizer: CURO-Pi Ⅲ
  • Int'l Joint Research
• [Presentation] "ポルフィリンによって安 定化されたアミニルラジカルの 合成と物性" (2018)
  • Author(s): 清水大貴・大須賀篤弘
  • Organizer: 第29回基礎有機化学討論会
• [Presentation] メゾーメゾ結合コロール二量体の酸化反応機構 (2018)
  • Author(s): 大井翔太・田中隆行・大須賀篤弘
  • Organizer: 第29回基礎有機化学討論会
• [Presentation] ジブロモトリピリンを前駆体に用いた新しいヘテロポルフィリノイド合成 (2018)
  • Author(s): 梅谷将隆・田中隆行・大須賀篤弘
  • Organizer: 第29回基礎有機化学討論会
• [Presentation] ポルフィリンを基盤とした縮環電子系によるトリメチレンメタン三重項ジラジカルの大幅な安定化とその物性 (2018)
  • Author(s): 加藤研一・古川貢・大須賀篤弘
  • Organizer: 第29回基礎有機化学討論会
• [Presentation] メゾ-ニトロコロールの合成と物性 (2018)
  • Author(s): 植田賢人・田中隆行・大須賀篤弘
  • Organizer: 第29回基礎有機化学討論会
• [Presentation] 二か所および三か所のメゾ位が無置換のサブポルフィリンの合成と物性解明 (2018)
  • Author(s): 黄瀬光稀・吉田康太・小谷亮太・清水大貴・大須賀篤弘
  • Organizer: 第29回基礎有機化学討論会
• [Presentation] テトラアミノジベンゾCOT前駆体を用いたフェナジン縮環FLAP分子の合成 (2018)
  • Author(s): 櫛田亜希・阿知波亮・齊藤尚平・大須賀篤弘
  • Organizer: 第29回基礎有機化学討論会
• [Presentation] メゾ－メゾ直結ヘキサフィリン二量体の合成 (2018)
  • Author(s): 中井彬人・井澤主水・大須賀篤弘
  • Organizer: 第29回基礎有機化学討論会
• [Presentation] メゾリチオ化を鍵とした新規メゾ位修飾サブポルフィリンの合成と物性 (2018)
  • Author(s): 戸次洋佑・清水大貴・藤本圭佑・大須賀篤弘
  • Organizer: 第29回基礎有機化学討論会
• [Presentation] Stable Porphyrin Radicals (2018)
  • Author(s): Atsuhiro Osuka
  • Organizer: the 3rd annual Anslyn-Iverson-Sessler (AIS) Lecture
  • Int'l Joint Research / Invited
• [Presentation] Stable Porphyrin Radicals (2018)
  • Author(s): Atsuhiro Osuka
  • Organizer: 10th Singapore International Chemistry Conference (SICC10)
  • Int'l Joint Research / Invited
• [Presentation] A Benzene-1,3,5-Triaminyl Radical Fused with Zn(II)-Porphyrins: Remarkable Stability and High Spin Quartet Ground State (2018)
  • Author(s): Daiki Shimizu, Atsuhiro Osuka
  • Organizer: 10th Singapore International Chemistry Conference (SICC10)
  • Int'l Joint Research
• [Presentation] A Stable Trimethylenemethane Triplet Diradical Based on a Trimeric Porphyrin Fused π-System (2018)
  • Author(s): Kenichi Kato, Ko Furukawa, Atsuhiro Osuka
  • Organizer: 10th Singapore International Chemistry Conference (SICC10)
  • Int'l Joint Research
• [Presentation] コロール典型元素錯体2018 (2018)
  • Author(s): 田中隆行・植田賢人・大井翔太・大須賀篤弘
  • Organizer: 第45回有機典型元素化学討論会