Development of CO2 absorbing materials using a liquid-solid phase transition

• Project/Area Number: 18K19864
• Research Category: Grant-in-Aid for Challenging Research (Exploratory)
• Allocation Type: Multi-year Fund
• Review Section: Medium-sized Section 64:Environmental conservation measure and related fields
• Research Institution: Hokkaido University
• Principal Investigator: Noro Shin-ichiro 北海道大学, 地球環境科学研究院, 教授 (70373347)
• Project Period (FY): 2018-06-29 – 2021-03-31
• Project Status: Completed (Fiscal Year 2020)
• Budget Amount: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000); Fiscal Year 2020: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000); Fiscal Year 2019: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000); Fiscal Year 2018: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
• Keywords: 二酸化炭素分離 / 液固相転移 / イオン性物質

Outline of Final Research Achievements

Development of new ionic materials showing a liquid-solid phase transition was carried out toward efficient carbon dioxide separation. The ionic liquid including bis(trifluoromethylsulfonyl)amide (NTf2) anions formed a variety of phases, crystal, liquid and amorphous. Next, the hybrid material of porous material and amorphous ionic material was prepared. The porous material itself showed adsorption for a variety of gases including carbon dioxide, while the hybrid material exhibited enhanced carbon dioxide adsorption selectivity.

Academic Significance and Societal Importance of the Research Achievements

大気中の二酸化炭素を低コストで分離回収する技術開発は、環境問題および資源問題の観点から喫緊の課題である。本研究では、液固相転移を利用して二酸化炭素を高選択的に吸収分離するイオン性アモルファス物質の合成とその二酸化炭素分離能評価を試みた。その結果、多孔性物質と複合化することにより二酸化炭素分離能を向上させることに成功した。本成果をさらに発展させることにより、全回収コストの50～70%を占める二酸化炭素分離プロセスの省エネ化を促すと期待できる。

Research Products

• [Journal Article] A Synchronous Change in Fluid Space and Encapsulated Anions in a Crystalline Polymethylene Unit Containing Metal-Organic Framework (2020)
  • Author(s): Zheng Xin、Sato Hiroyasu、Takahashi Kiyonori、Noro Shin-ichiro、Nakamura Takayoshi
  • Journal Title: Crystal Growth & Design Volume: 20 Issue: 6 Pages: 3596-3600
  • DOI: 10.1021/acs.cgd.0c00334
  • Peer Reviewed / Open Access
• [Journal Article] Controlling the gate-sorption properties of solid solutions of Werner complexes by varying component ratios (2020)
  • Author(s): Noro Shin-ichiro、Song Yu、Tanimoto Yutaro、Hijikata Yuh、Kubo Kazuya、Nakamura Takayoshi
  • Journal Title: Dalton Transactions Volume: 49 Issue: 27 Pages: 9438-9443
  • DOI: 10.1039/d0dt01355b
  • Peer Reviewed / Open Access
• [Journal Article] Understanding the interactions between the bis(trifluoromethylsulfonyl)imide anion and absorbed CO2 using X-ray diffraction analysis of a soft crystal surrogate (2020)
  • Author(s): Zheng Xin、Fukuhara Katsuo、Hijikata Yuh、Pirillo Jenny、Sato Hiroyasu、Takahashi Kiyonori、Noro Shin-ichiro、Nakamura Takayoshi
  • Journal Title: Communications Chemistry Volume: 3 Issue: 1 Pages: 143-143
  • DOI: 10.1038/s42004-020-00390-1
  • Peer Reviewed / Open Access
• [Journal Article] Coordinated Water as New Binding Sites for the Separation of Light Hydrocarbons in Metal-Organic Frameworks with Open Metal Sites (2020)
  • Author(s): Pia Vervoorts, Andreas Schneemann, Inke Hante, Jenny Pirillo, Yuh Hijikata, Takashi Toyao, Kenichi Kon, Ken-ichi Shimizu, Takayoshi Nakamura, Shin-ichiro Noro* and Roland A. Fischer*
  • Journal Title: ACS Appl. Mater. Interfaces Volume: 12 Issue: 8 Pages: 9448-9456
  • DOI: 10.1021/acsami.9b21261
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Dielectric and Sorption Responses of Hydrogen-Bonding Network of Amorphous C60(OH)12 and C60(OH)36 (2019)
  • Author(s): Shota Uchikawa, Ayumi Kawasaki, Norihisa Hoshino, Takashi Takeda, Shin-ichiro Noro,* Kiyonori Takahashi, Takayoshi Nakamura, Nozomi Sato, Ken Kokubo, Hidehiro Sakurai, and Tomoyuki Akutagawa*
  • Journal Title: J. Phys. Chem. C Volume: 123 Issue: 38 Pages: 23545-23553
  • DOI: 10.1021/acs.jpcc.9b06951
  • NAID: 120006887716
  • Peer Reviewed
• [Journal Article] Incorporation of Multinuclear Copper Active Sites into Nitrogen-Doped Graphene for Electrochemical Oxygen Reduction (2018)
  • Author(s): Masaru Kato, Marika Muto, Naohiro Matsubara, Yohei Uemura, Yuki Wakisaka, Tsubasa Yoneuchi, Daiju Matsumura, Tomoko Ishihara, Takashi Tokushima, Shin-ichiro Noro, Satoru Takakusagi, Kiyotaka Asakura, and Ichizo Yagi
  • Journal Title: ACS Appl. Energy Mater. Volume: 1 Issue: 5 Pages: 2358-2364
  • DOI: 10.1021/acsaem.8b00491
  • NAID: 120006887744
  • Peer Reviewed
• [Journal Article] Chemo-chromism in an orthogonal dabco-based Co(ii) network assembled by methanol-coordination and hydrogen bond formation (2018)
  • Author(s): Shiga Misaki、Kawaguchi Shogo、Fujibayashi Masaru、Nishihara Sadafumi、Inoue Katsuya、Akutagawa Tomoyuki、Noro Shin-ichiro、Nakamura Takayoshi、Tsunashima Ryo
  • Journal Title: Dalton Transactions Volume: 47 Issue: 23 Pages: 7656-7662
  • DOI: 10.1039/c8dt01220b
  • Peer Reviewed
• [Presentation] アルギネートポリマーによって賦形された多孔性金属錯体のガス吸着特性に対する乾燥法の影響 (2021)
  • Author(s): 谷本憂太郎、野呂真一郎
  • Organizer: 日本化学会第101春季年会(2021)
• [Presentation] Multiple Structural and Phase Transformations of a Flexible Coordination Polymer with Fluorinated Anion (2021)
  • Author(s): Xin Zheng, Kiyonori Takahashi, Takayoshi Nakamura, Shin-ichiro Noro
  • Organizer: 日本化学会第101春季年会(2021)
• [Presentation] Metal Complex Based Adsorption Materials for Environmental Remediation and Energy Saving (2021)
  • Author(s): Shin-ichiro Noro
  • Organizer: International academic webinar: Materials Chemistry for Better Future
  • Int'l Joint Research / Invited
• [Presentation] Synthesis and Adsorption Properties of Three-Dimensional Fluorinated Dianion-Bridged Porous Metal Complexes (2020)
  • Author(s): AnQi Wang, Kiyonori Takahashi, Takayoshi Nakamura, Shin-ichiro Noro
  • Organizer: 第71会コロイドおよび界面化学討論会
• [Presentation] 高効率室温二酸化炭素分離へ向けた5員複素環を有する柔軟性金属錯体の合成 (2020)
  • Author(s): 杉浦みのり、高橋仁徳、中村貴義、野呂真一郎
  • Organizer: 第71会コロイドおよび界面化学討論会
• [Presentation] 環境汚染物質除去のためのアルギネートポリマーMOF複合体の合成 (2020)
  • Author(s): 谷本憂太郎、野呂真一郎
  • Organizer: 化学系学協会北海道支部2020年冬季研究発表会
• [Presentation] アルコキシ基を有する多孔性Zr錯体の合成と吸着特性 (2020)
  • Author(s): 原田健杜、大関隆志、伊藤彰則、野呂真一郎
  • Organizer: 化学系学協会北海道支部2020年冬季研究発表会
• [Presentation] Introduction of Hydroxy Groups into One-Dimensional Metal Complexes and Their Impact on Adsorption Properties (2019)
  • Author(s): AnQi Wang, Kiyonori Takahashi, Ichiro Hisaki, Takayoshi Nakamura, Shin-ichiro Noro “Introduction of Hydroxy Groups into One-Dimensional Metal Complexes and Their Impact on Adsorption Properties
  • Organizer: 錯体化学会第69回討論会
• [Presentation] 室温低濃度二酸化炭素分離へ向けた柔軟性金属錯体の合成 (2019)
  • Author(s): 杉浦みのり、高橋仁徳、久木一朗、中村貴義、野呂真一郎
  • Organizer: 錯体化学会第69回討論会
• [Presentation] Effect of Uptake/Release of Coordinated Molecules on Gate-Opening Adsorption Behavior in Coordination Polymer (2019)
  • Author(s): Xin Zheng, Kiyonori Takahashi, Ichiro Hisaki, Takayoshi Nakamura, Shin-ichiro Noro “Effect of Uptake/Release of Coordinated Molecules on Gate-Opening Adsorption Behavior in Coordination Polymer
  • Organizer: 錯体化学会第69回討論会
• [Presentation] ピペラジンを含む金属錯体の合成と二酸化炭素吸着特性 (2019)
  • Author(s): 張思、高橋仁徳、久木一朗、中村貴義、野呂真一郎
  • Organizer: 錯体化学会第69回討論会
• [Presentation] Perfluoroalkyl基を有する多孔性Zr錯体固溶体のガス吸着特性 (2019)
  • Author(s): 伊藤彰則、大関隆志、高橋仁徳、久木一朗、中村貴義、野呂真一郎
  • Organizer: 日本化学会北海道支部2019年夏季研究発表会
• [Presentation] 光反応性4-スチリルピリジン配位子を有するウェルナークラスレートの合成と性質 (2019)
  • Author(s): 張雲雅、高橋仁徳、久木一朗、中村貴義、野呂真一郎
  • Organizer: 日本化学会北海道支部2019年夏季研究発表会
• [Presentation] 2-アミノピリミジン架橋一次元金属錯体の合成及び二酸化炭素吸着特性評価 (2019)
  • Author(s): 孟宇、鈴木和重、高橋仁徳、久木一朗、中村貴義、野呂真一郎
  • Organizer: 日本化学会北海道支部2019年夏季研究発表会
• [Presentation] 4-スチリルピリジン配位子を有するウェルナー型錯体の合成と性質 (2019)
  • Author(s): 張雲雅、高橋仁徳、中村貴義、野呂真一郎
  • Organizer: 化学系学協会北海道支部2019年冬季研究発表会
• [Presentation] Perfluoro基で修飾された多孔性Zr錯体の合成と特性評価 (2019)
  • Author(s): 伊藤彰則、大関隆志、野呂真一郎
  • Organizer: 化学系学協会北海道支部2019年冬季研究発表会
• [Presentation] Dibenzo[24]crown-8/1-ethyl-3-methylimidazolium超分子カチオンを導入した[Ni(dmit)2]アニオンラジカル炎の融解挙動と電気物性 (2019)
  • Author(s): 高橋仁徳、白川祐基、星野哲久、野呂真一郎、芥川智行、中村貴義
  • Organizer: 日本化学会第99春季年会(2019)
• [Presentation] ビピリジンとジチオレン配位子誘導体からなる分極性非対称白金錯体のエレクトロクロミック特性 (2019)
  • Author(s): 堀葵、久保和也、キム ユナ、森田朝子、友田千尋、角屋智史、野呂真一郎、玉置伸之、中村貴義、山田順一
  • Organizer: 日本化学会第99春季年会(2019)
• [Presentation] 糖残基を有する双頭型両親媒性分子の合成とその集合能評価 (2019)
  • Author(s): 石ヶ森あずみ、和泉雅之、高橋仁徳、野呂真一郎、中村貴義、越智里香
  • Organizer: 日本化学会第99春季年会(2019)
• [Presentation] A series of copper coordination polymers constructed by bis(imidazole) ligands and bulky fluorinated anions: synthesis, structures, and physical properties (2018)
  • Author(s): Xin Zheng, Kiyonori Takahashi, Takayoshi Nakamura, Shin-ichiro Noro
  • Organizer: 錯体化学会第68回討論会
  • Int'l Joint Research
• [Presentation] Crystal Structure, Gas Sorption and Dielectric Properties of One-Dimensional Copper(II) Coordination Polymer with 2- Thiophenecarboxylate Ligand (2018)
  • Author(s): Kiyonori Takahashi, Norihisa Hoshino, Shin-ichiro Noro, Tomoyuki Akutagawa, and Takayoshi Nakamura
  • Organizer: 43th International Conference on Coordination Chemistry
  • Int'l Joint Research
• [Presentation] 混合原子価ポリオキソメタレートが示す分子構造相転移における結晶溶媒の影響 (2018)
  • Author(s): 藤林将、高橋仁徳、野呂真一郎、中村貴義、綱島亮
  • Organizer: 2018年日本化学会中国四国支部大会
• [Presentation] 糖脂質型両親媒性分子ライブラリの合成とその自己集合能の評価 (2018)
  • Author(s): 石ヶ森あずみ、和泉雅之、野呂真一郎、中村貴義、越智里香
  • Organizer: 2018年日本化学会中国四国支部大会