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Fabrication of nano-to-submicron-sized exclusive pods and their spatial functionalization

Research Project

Project/Area Number 18KK0142
Research Category

Fund for the Promotion of Joint International Research (Fostering Joint International Research (B))

Allocation TypeMulti-year Fund
Review Section Medium-sized Section 28:Nano/micro science and related fields
Research InstitutionKumamoto University

Principal Investigator

Takafuji Makoto  熊本大学, 大学院先端科学研究部(工), 教授 (50332086)

Co-Investigator(Kenkyū-buntansha) 龍 直哉  熊本県産業技術センター(ものづくり室、材料・地域資源室、食品加工室), その他部局等, 研究主任 (90743641)
伊原 博隆  沖縄工業高等専門学校, その他部局等, 校長 (10151648)
Project Period (FY) 2018-10-09 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥17,940,000 (Direct Cost: ¥13,800,000、Indirect Cost: ¥4,140,000)
Fiscal Year 2021: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2020: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2019: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
Fiscal Year 2018: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywordsマイクロ粒子 / 閉鎖性空間 / ディンプル構造 / コアシェル粒子 / ナノ空間 / ナノ粒子 / ナノ・マイクロ粒子 / コアシェル微粒子
Outline of Final Research Achievements

In this study, we aim to create nano- and submicron-sized pod-like spaces at the microparticle surface with specific inner spaces. Polymer particles with the pod structure on their surface were prepared by removal of interfacial silica particles from the core-shell polymer microspheres with silica nanoparticles-embedded on the surface. The pod aperture and internal size can be variously controlled by the preparation conditions. Various substances ranging from dye molecules to nanoparticles could be stored in the internal space of the pod, suggesting that the interior of the space is highly diffusive and fluid, but also that it is closed nature.

Academic Significance and Societal Importance of the Research Achievements

環状分子や有機金属構造体(MOF)、ゼオライト、層状化合物(ナノシート)などメソからナノサイズの空間を利用した研究は数多く報告されているが、サブミクロンの空孔を有する構造体の研究例は少なく、拡散性・流動性が存在するサイズの隔離空間として学術的に興味深い研究対象である。ナノ・サブミクロンポッドは界面自己組織化したナノ粒子をテンプレートとしており、空間のサイズや深さ、開口部の直径の制御が可能であり、開口部よりも広がった内部空間を作製することもできる。ポリマーマイクロ粒子界面にポッド配置していることから、カラム充填剤や物質輸送キャリアなどへの展開も可能である。

Report

(6 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Research-status Report
  • 2020 Research-status Report
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (60 results)

All 2023 2022 2021 2020 2019 2018 Other

All Int'l Joint Research (4 results) Journal Article (6 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 5 results,  Open Access: 1 results) Presentation (44 results) (of which Int'l Joint Research: 23 results,  Invited: 5 results) Remarks (6 results)

  • [Int'l Joint Research] ボルドー大学/フランス国立科学研究センター(フランス)

    • Related Report
      2021 Research-status Report
  • [Int'l Joint Research] ボルドー大学/フランス国立科学研究センター(フランス)

    • Related Report
      2020 Research-status Report
  • [Int'l Joint Research] ボルドー大学/フランス国立科学研究センター(フランス)

    • Related Report
      2019 Research-status Report
  • [Int'l Joint Research] ボルドー大学/フランス国立科学研究センター(フランス)

    • Related Report
      2018 Research-status Report
  • [Journal Article] Preparation of Hybrid Microspheres with Homogeneously Dispersed Nanosilica Using In-situ Sol-Gel Reaction inside a Polystyrene Matrix2022

    • Author(s)
      Toyofuji Ayumi、Hano Nanami、Yamaguchi Yuya、Wakiya Takeshi、Ihara Hirotaka、Takafuji Makoto
    • Journal Title

      Chemistry Letters

      Volume: 51 Issue: 6 Pages: 639-642

    • DOI

      10.1246/cl.220121

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective reflection enhancement by controlling of surface-layering structure of inorganic nanoparticles on polymer microspheres2022

    • Author(s)
      Hano Nanami、Ryu Naoya、Nagaoka Shoji、Ihara Hirotaka、Takafuji Makoto
    • Journal Title

      Colloids and Surfaces A: Physicochemical and Engineering Aspects

      Volume: 637 Pages: 128188-128188

    • DOI

      10.1016/j.colsurfa.2021.128188

    • Related Report
      2021 Research-status Report
    • Peer Reviewed
  • [Journal Article] Hetero-network hydrogels crosslinked with silica nanoparticles for strategic control of thermal responsive property2021

    • Author(s)
      Rahman M. Maria、Alam Md. Ashraful、Ihara Hirotaka、Takafuji Makoto
    • Journal Title

      Soft Matter

      Volume: 17 Issue: 17 Pages: 4615-4622

    • DOI

      10.1039/d1sm00191d

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Efficient removal of methylene blue dye from an aqueous solution using silica nanoparticle crosslinked acrylamide hybrid hydrogels2021

    • Author(s)
      Maria Rahman M.、Al Foisal Jannat、Ihara Hirotaka、Takafuji Makoto
    • Journal Title

      New Journal of Chemistry

      Volume: 45 Issue: 43 Pages: 20107-20119

    • DOI

      10.1039/d1nj04383h

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Fabrication of Carbon-Like, π-Conjugated Organic Layer on a Nano-Porous Silica Surface2020

    • Author(s)
      Noguchi Hiroki、Sultana Marzia、Hano Nanami、Kuwahara Yutaka、Takafuji Makoto、Nagaoka Shoji、Qiu Hongdeng、Ihara Hirotaka
    • Journal Title

      Nanomaterials

      Volume: 10 Issue: 9 Pages: 1882-1882

    • DOI

      10.3390/nano10091882

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Monodisperse Surface-Charge-Controlled Black Nanoparticles for Near-Infrared Shielding2019

    • Author(s)
      Hano Nanami、Takafuji Makoto、Noguchi Hiroki、Ihara Hirotaka
    • Journal Title

      ACS Applied Nano Materials

      Volume: 2 Issue: 6 Pages: 3597-3605

    • DOI

      10.1021/acsanm.9b00555

    • Related Report
      2019 Research-status Report
  • [Presentation] Preparation of core-shell microspheres with surface-layering structure of inorganic nanoparticles and their selective reflectance property2023

    • Author(s)
      Nanami Hano, Naoya Ryu, S. Nagaoka, Hirotaka Ihara, Makoto Takafuji
    • Organizer
      12th International Colloids Conference
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Strategic control of thermo-responsive property of the hetero-network hydrogels crosslinked with nanosilica2023

    • Author(s)
      M. Maria Rahman, Md. Ashraful Alam, Nanami Hano, Hirotaka Ihara, Makoto Takafuji
    • Organizer
      12th International Colloids Conference
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] One-pot synthesis of ionic spherical polymer nanoparticles with naphthalene backbone2023

    • Author(s)
      Mai Fukunaga, Nanami Hano, Hirotaka Ihara, Makoto Takafuji
    • Organizer
      12th International Colloids Conference
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] One pot preparation of colloidal spheres composed of aromatic network polymer2022

    • Author(s)
      Makoto Takafuji, Nanami Hano, Udai Oishi, Kosuke Nakamae, Mai Fukunaga, Haruka Kimura, Hirotaka Ihara
    • Organizer
      11th International Colloids Conference
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of monodisperse spherical aromatic network polymer particles using various phenolic monomers2022

    • Author(s)
      Nanami Hano, Akari Yamamoto, Hirotaka Ihara, Makoto Takafuji
    • Organizer
      11th International Colloids Conference
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ナフタレンを主鎖骨格にもつポリマー球状粒子の構造制御および機能化2022

    • Author(s)
      杷野菜奈美、大石祐大、木村春香、岩本有生、福永真衣、小田玲子、伊原博隆、高藤 誠
    • Organizer
      第71回高分子討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 真球状カーボンナノ粒子の作製と構造評価2022

    • Author(s)
      高藤 誠、木村 春香、杷野 菜奈美、伊原 博隆
    • Organizer
      第71回高分子討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 無機ナノ粒子の分散・凝集を利用した機能性ポリマー複合材料の開発2022

    • Author(s)
      高藤 誠
    • Organizer
      高分子学会 無機高分子研究会
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] Introduction of ionic functional groups to spherical nanoparticles composed of aromatic network polymer2022

    • Author(s)
      Mai Fukunaga, Nanami Hano, Hirotaka Ihara, Makoto Takafuji
    • Organizer
      The Pacific Polymer Conference (PPC17)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Aromatic network polymer (ArNP) colloidal nanoparticles and their applications2022

    • Author(s)
      Makoto Takafuji, Nanami Hano, Udai Oishi, Mai Fukunaga, Haruka Kimura, Yuki Iwamoto, Hirotaka Ihara
    • Organizer
      The Pacific Polymer Conference (PPC17)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of colloidal polymer spherical nanoparticles having diverse aromatic backbone2022

    • Author(s)
      Nanami Hano, Akari Yamamoto, Mai Fukunaga, Hirotaka Ihara, Makoto Takafuji
    • Organizer
      The Pacific Polymer Conference (PPC17)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 界面機能化単分散球状芳香族ポリマー粒子の作製2022

    • Author(s)
      福永 真衣、杷野 菜奈美、伊原 博隆、高藤 誠
    • Organizer
      第21回高分子ミクロスフェア討論会
    • Related Report
      2021 Research-status Report
  • [Presentation] 単分散球状多孔質カーボン粒子の作製と粒径制御2022

    • Author(s)
      木村 春香、杷野 菜奈美、伊原 博隆、高藤 誠
    • Organizer
      第21回高分子ミクロスフェア討論会
    • Related Report
      2021 Research-status Report
  • [Presentation] マイクロ粒子界面のディンプル空間を利用した選択的物質捕捉2021

    • Author(s)
      杷野 菜奈美、金輪 静夏、龍 直哉、Reiko Oda、伊原 博隆、高藤 誠
    • Organizer
      第70回高分子学会年次大会
    • Related Report
      2021 Research-status Report
  • [Presentation] 多様な界面機能を導入した新規π共役ポリマー球状粒子の創製2021

    • Author(s)
      福永 真衣、杷野 菜奈美、伊原 博隆、高藤 誠
    • Organizer
      第70回高分子学会年次大会
    • Related Report
      2021 Research-status Report
  • [Presentation] Facile control of thermal and mechanical properties of hetero-network hydrogels2021

    • Author(s)
      Mst. Maria Rahman, Hirotaka Ihara, Makoto Takafuji
    • Organizer
      48th World Polymer Congress ( IUPAC-MACRO2020)
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] 膨潤性有機・無機ハイブリッドポリマー球状粒子の作製2021

    • Author(s)
      豊藤 歩美、杷野 菜奈美、伊原 博隆、高藤 誠
    • Organizer
      第58回化学関連支部合同九州大会
    • Related Report
      2021 Research-status Report
  • [Presentation] 機能性アミンの導入による黒色ポリマー粒子の界面電荷制御2021

    • Author(s)
      福永 真衣、杷野 菜奈美、伊原 博隆、高藤 誠
    • Organizer
      第58回化学関連支部合同九州大会
    • Related Report
      2021 Research-status Report
  • [Presentation] 芳香族ネットワークポリマー粒子のカーボン化と高彩度・高耐熱性構造色への応用2021

    • Author(s)
      高藤 誠、中前 昂祐、杷野 菜奈美、伊原 博隆
    • Organizer
      第70回高分子討論会
    • Related Report
      2021 Research-status Report
  • [Presentation] フェノール性多環芳香族を主鎖骨格とする芳香族ネットワークポリマー粒子の光学特性制御2021

    • Author(s)
      杷野 菜奈美、山本 朱莉、高藤 誠、伊原 博隆
    • Organizer
      第70回高分子討論会
    • Related Report
      2021 Research-status Report
  • [Presentation] Silica nanoparticles crosslinked acrylamide hybrid hydrogels for efficient removal of dye2021

    • Author(s)
      Mst. Maria Rahman, Hirotaka Ihara, Makoto Takafuji
    • Organizer
      The 16th International Student Conference on Advanced Science and Technology (ICAST 2021)
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] Enhancement of colorfulness of colloidal silica photonic crystals by doping of monodisperse black polymer spheres2021

    • Author(s)
      Makoto Takafuji, Kosuke Nakamae, Nanami Hano, Hirotaka Ihara
    • Organizer
      The International Chemical Congress of Pacific Basin Societies (Pacifichem 2021)
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] Preparation of amphiphilic monodisperse carbon-like black particles having selective reflectivity for near infrared light2021

    • Author(s)
      Nanami Hano, Han Yuan Ng, Hirotaka Ihara, Makoto Takafuji
    • Organizer
      The International Chemical Congress of Pacific Basin Societies (Pacifichem 2021)
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] Preparation of swellable silica-hybridized polystyrene microspheres2021

    • Author(s)
      Ayumi Toyofuji, Nanami Hano, Yuya Yamaguchi, Takeshi Wakiya, Hirotaka Ihara, Makoto Takafuji
    • Organizer
      The International Chemical Congress of Pacific Basin Societies (Pacifichem 2021)
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] Facile preparation of amino acid-incorporated pi-conjugated polymer particles2021

    • Author(s)
      Mai Fukunaga, Nanami Hano, Hirotaka Ihara, Makoto Takafuji
    • Organizer
      The International Chemical Congress of Pacific Basin Societies (Pacifichem 2021)
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] 単分散球状π共役ポリマー粒子の開発と多彩な光機能2020

    • Author(s)
      高藤 誠
    • Organizer
      2020年日本化学会九州支部秋期研究発表会
    • Related Report
      2020 Research-status Report
    • Invited
  • [Presentation] ジヒドロキシ多環芳香族を用いるオール有機ポリマー微粒子の色彩制御2020

    • Author(s)
      山本 朱莉、桑原 穣、永岡 昭二、高藤 誠、伊原 博隆
    • Organizer
      第69回高分子学会年次大会
    • Related Report
      2020 Research-status Report
  • [Presentation] ビナフトールの直接重合による蛍光色素材の合成2020

    • Author(s)
      岡村 直哉、桑原 穣、高藤 誠、伊原 博隆
    • Organizer
      第69回高分子学会年次大会
    • Related Report
      2020 Research-status Report
  • [Presentation] 界面ディンプルポリマー微粒子の物質捕捉機能の評価2020

    • Author(s)
      杷野 菜奈美、金輪 静夏、竹田 賀美、Oda Reiko、高藤 誠、伊原 博隆
    • Organizer
      第69回高分子学会年次大会
    • Related Report
      2020 Research-status Report
  • [Presentation] 機能性ナノゲル固定化多孔質シリカを利用した高選択的HPLC分離剤の開発2020

    • Author(s)
      河本 直樹、Yongxing Hu、Hongdeng Qiu、高藤 誠、伊原 博隆
    • Organizer
      第69回高分子学会年次大会
    • Related Report
      2020 Research-status Report
  • [Presentation] シリカ複合化ポリスチレン微粒子の作製と膨潤挙動2020

    • Author(s)
      豊藤 歩美、杷野 菜奈美、山口 裕也、脇屋 武司、高藤 誠、伊原 博隆
    • Organizer
      第69回高分子学会年次大会
    • Related Report
      2020 Research-status Report
  • [Presentation] Facile preparation of hetero-network hydrogels with tunable thermo-responsive property2020

    • Author(s)
      Mst. Maria Rahman, Md. Ashraful Alam, Makoto Takafuji, Hirotaka Ihara
    • Organizer
      第69回高分子討論会
    • Related Report
      2020 Research-status Report
  • [Presentation] 単分散球状ブラックポリマー粒子によるフォトニック結晶の構造色制御2020

    • Author(s)
      中前 昂祐、杷野 菜奈美、伊原 博隆、高藤 誠
    • Organizer
      2020年日本化学会九州支部秋期研究発表会
    • Related Report
      2020 Research-status Report
  • [Presentation] Fabrication of hetero-network hydrogels cross-linked with silica nanoparticles for strategic control of thermal responsive property2020

    • Author(s)
      Mst. Maria Rahman, Hirotaka Ihara, Makoto Takafuji
    • Organizer
      The 15th International Student Conference on Advanced Science and Technology (ICAST 2020)
    • Related Report
      2020 Research-status Report
    • Int'l Joint Research
  • [Presentation] Functionalization of inner space of dimples on the surface of polymer microspheres2020

    • Author(s)
      Namami Hano, Shizuka Kanawa, Yoshimi Takeda, Naoya Ryu, Reiko Oda, Hirotaka Ihara, Makoto Takafuji
    • Organizer
      10th International Colloids Conference
    • Related Report
      2020 Research-status Report
    • Int'l Joint Research
  • [Presentation] 選択的近赤外光反射特性を有する単分散黒色ナノ粒子の作製2019

    • Author(s)
      杷野菜奈美、野口広貴、高藤誠、伊原博隆
    • Organizer
      第68回高分子学会年次大会
    • Related Report
      2019 Research-status Report
  • [Presentation] Surface-functionalized hybrid polymer microspheres with unique morphological feature2019

    • Author(s)
      Makoto Takafuji
    • Organizer
      The 2nd Materials Research Society of Thailand International Conference
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 単分散ブラック球状粒子を利用した構造色の色調制御2019

    • Author(s)
      中前昂祐、杷野菜奈美、伊原博隆、高藤誠
    • Organizer
      第56回化学関連支部合同九州大会・外国人研究者交流国際シンポジウム
    • Related Report
      2019 Research-status Report
  • [Presentation] Monodisperse black polymer spherical particles for selective reflection materials2019

    • Author(s)
      Makoto Takafuji, Nanami Hano, Kosuke Nakamae, Yutaka Kuwahara, Hirotaka Ihara
    • Organizer
      International Symposium for Advanced Materials Research
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Microwave-assisted Preparation of Monodisperse Black Polymer Nanoparticles and Their Selective Reflection Property of Near Infrared2019

    • Author(s)
      Makoto Takafuji, Nan ami Hano, Hiroki Noguchi, Yutaka Kuwahara, Hirotaka Ihara
    • Organizer
      The 16th Pacific Polymer Conference
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Enhancement of selective reflection of silica colloidal crystals by doping mono-disperse black polymer particles for vivid structural colors2019

    • Author(s)
      Kosuke Nakamae, Nanami Hano, Makoto Takafuji, Hirotaka Ihara
    • Organizer
      The 16th Pacific Polymer Conference
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Development of Surface-Functinalized Hybrid Microspheres2018

    • Author(s)
      Makoto Takafuji
    • Organizer
      セルロース学会西部支部セミナー(国立成功大學(NCKU), 台湾)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Morphological control of wrinkled-structure of silica nanoparticle-crosslinked shell on the polymer microsphere2018

    • Author(s)
      Nanami Hano
    • Organizer
      12th SPSJ International Polymer Conference (IPC2018)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Preparation of hybrid microspheres with interpenetrating polymer-silica network2018

    • Author(s)
      Yuya Yamaguchi
    • Organizer
      12th SPSJ International Polymer Conference (IPC2018)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Remarks] 研究代表者(高藤 誠)のウェブページ

    • URL

      http://www.chem.kumamoto-u.ac.jp/~wildcats/takafuji/index-j.html

    • Related Report
      2022 Annual Research Report
  • [Remarks] 研究グループ(Supramolecular Chemistry Group)のウェブページ

    • URL

      http://www.chem.kumamoto-u.ac.jp/~suprachemistry/

    • Related Report
      2022 Annual Research Report
  • [Remarks] 研究者のウェブページ

    • URL

      http://www.chem.kumamoto-u.ac.jp/~wildcats/takafuji/index-j.html

    • Related Report
      2021 Research-status Report 2020 Research-status Report 2018 Research-status Report
  • [Remarks] 研究者の所属する研究グループのウェブページ

    • URL

      http://www.chem.kumamoto-u.ac.jp/~suprachemistry/

    • Related Report
      2021 Research-status Report 2020 Research-status Report
  • [Remarks] 研究者(高藤誠)のウェブページ

    • URL

      http://www.chem.kumamoto-u.ac.jp/~wildcats/takafuji/index-j.html

    • Related Report
      2019 Research-status Report
  • [Remarks] 研究者の所属する研究グループのウェブページ

    • URL

      http://www.chem.kumamoto-u.ac.jp/~ihara/lab3/index-j.html

    • Related Report
      2019 Research-status Report 2018 Research-status Report

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Published: 2018-10-12   Modified: 2024-01-30  

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