| Budget Amount *help |
¥111,670,000 (Direct Cost: ¥85,900,000、Indirect Cost: ¥25,770,000)
Fiscal Year 2011: ¥13,650,000 (Direct Cost: ¥10,500,000、Indirect Cost: ¥3,150,000)
Fiscal Year 2010: ¥13,520,000 (Direct Cost: ¥10,400,000、Indirect Cost: ¥3,120,000)
Fiscal Year 2009: ¥13,520,000 (Direct Cost: ¥10,400,000、Indirect Cost: ¥3,120,000)
Fiscal Year 2008: ¥13,520,000 (Direct Cost: ¥10,400,000、Indirect Cost: ¥3,120,000)
Fiscal Year 2007: ¥57,460,000 (Direct Cost: ¥44,200,000、Indirect Cost: ¥13,260,000)
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| Research Abstract |
We have developed novel sophisticated synthetic strategies for the preparation of highly challenging classes of low-coordinate derivatives of the heavier main group elements (multiply-bonded compounds such as disilynes with silicon-silicon triple bonds, isolable Si-, Ge-, and Sn-centered cations, radicals, and anion-and cation-radicals, Si and Ge heterocycles and their uses as ligands for transition metals etc.). We also performed the detailed analysis of their structural and synthetic properties, and carried out the systematic study of the basic similarities and differences between these new species and their organic analogues.
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