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Advanced Control of Catalytic Activity and Stereoselectivity in Catalytic Asymmetric Reactions

Research Project

Project/Area Number 19105002
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Research Field Synthetic chemistry
Research InstitutionKyoto University

Principal Investigator

HAYASHI Tamio  Kyoto University, 大学院・理学研究科, 教授 (00093295)

Research Collaborator SHIRAKAWA Eiji  京都大学, 大学院・理学研究科, 准教授 (70273472)
NISHIMURA Takahiro  京都大学, 大学院・理学研究科, 講師 (50335197)
SHINTANI Ryo  京都大学, 大学院・理学研究科, 助教 (50372561)
Project Period (FY) 2007 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥110,630,000 (Direct Cost: ¥85,100,000、Indirect Cost: ¥25,530,000)
Fiscal Year 2010: ¥24,830,000 (Direct Cost: ¥19,100,000、Indirect Cost: ¥5,730,000)
Fiscal Year 2009: ¥24,830,000 (Direct Cost: ¥19,100,000、Indirect Cost: ¥5,730,000)
Fiscal Year 2008: ¥24,830,000 (Direct Cost: ¥19,100,000、Indirect Cost: ¥5,730,000)
Fiscal Year 2007: ¥36,140,000 (Direct Cost: ¥27,800,000、Indirect Cost: ¥8,340,000)
Keywords触媒的不斉合成 / 遷移金属錯体触媒 / 不斉配位子 / キラルジエン配位子 / 触媒活性 / 不斉付加反応 / 不斉重合 / ロジウム触媒 / イリジウム触媒 / 銅触媒 / 反応機構
Research Abstract

One of the most important subjects in studying asymmetric catalysis is development of new chiral ligands which have both high catalytic activity and high enantioselectivity. We have successfully developed an entirely new type of chiral ligands which have olefins as coordinating functionalities to metal catalysts. Among them, chiral diene ligands showed great performance in terms of both catalytic activity and enantioselectivity in rhodium- and iridium-catalyzed asymmetric carbon-carbon bond forming reactions.

Report

(5 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (282 results)

All 2011 2010 2009 2008 2007 Other

All Journal Article (118 results) (of which Peer Reviewed: 118 results) Presentation (152 results) Book (8 results) Remarks (4 results)

  • [Journal Article] Rhodium-Catalyzed Asymmetric 1,4-Addition of Sodium Tetraarylborates to β,β-Disubstituted α,β-Unsaturated Esters2011

    • Author(s)
      Shintani, R.; Hayashi, T.
    • Journal Title

      Org.Lett.

      Volume: 13 Pages: 350-352

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Iron-Catalyzed Oxidative Coupling of Alkylamides with Arenes through Oxidation of Alkylamides Followed by Friedel-Crafts Alkylation2011

    • Author(s)
      Shirakawa, E.; Uchiyama, N.; Hayashi, T.
    • Journal Title

      J.Org.Chem.

      Volume: 76 Pages: 25-34

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Oxidative Alkynylation of Acrylate Esters with Propargylic Alcohols2011

    • Author(s)
      Nishimura, T.; Nagaosa, M.; Hayashi, T.
    • Journal Title

      Tetrahedron Lett.

      Volume: 52 Pages: 2185-2187

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Guiding the Nitrogen Nucleophile to the Middle : Palladium-Catalyzed Decarboxylative Cyclopropanation of 2-Alkylidenetrimethylene Carbonates with Isocyanates2011

    • Author(s)
      Shintani, R.; Moriya, K.; Hayashi, T.
    • Journal Title

      Chem.Commun.

      Volume: 47 Pages: 3057-3059

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Enantiomerically Pure P-Stereogenic Diphosphacrowns and Their Palladium Complexes2011

    • Author(s)
      Morisaki, Y.; Imoto, H.; Hirano, K.; Hayashi, T.; Chujo, Y.
    • Journal Title

      J.Org.Chem.

      Volume: 76 Pages: 1795-1803

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Copper-Catalyzed 1,4-Addition of Organoboronates to Alkylidenecyanoacetates : Mechanistic Insight and Application to Asymmetric Catalysis2011

    • Author(s)
      Takatsu, K.; Shintani, R.; Hayashi, T.
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 50

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mizoroki-Heck Type Reaction Mediated by Potassium tert-Butoxide2011

    • Author(s)
      Shirakawa, E.; Zhang, X.; Hayashi, T.
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 50

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Iron-catalyzed Pinacol Coupling of Aryl Ketones with a Phenyltitanium Reagent : A New Type of Catalytic Reaction2011

    • Author(s)
      Hayashi, T.; Sasaki, K.
    • Journal Title

      Chem.Lett.

      Volume: 40

    • NAID

      10028242767

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium/Chiral Diene-Catalyzed Asymmetric Cyclopolymerization of Achiral 1,8-Diynes2011

    • Author(s)
      Ichikawa, Y.; Nishimura, T.; Hayashi, T.
    • Journal Title

      Organometallics

      Volume: 30

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Asymmetric Arylation of N-Tosyl Ketimines.2010

    • Author(s)
      Shintani, R., Takeda, M., Tsuji, T., Hayashi, T.J.
    • Journal Title

      Am.Chem.Soc. 132

      Pages: 13168-13169

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Enantioselective 1, 6-Addition of Arylboronic Acids to Enynamides : Asymmetric Synthesis of Axially Chiral Allenylsilanes.2010

    • Author(s)
      Nishimura, T., Makino, H., Nagaosa, M., Hayashi, T.
    • Journal Title

      J.Am.Chem.Soc. 132

      Pages: 12865-12867

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Asymmetric Cyclopropanation of Alkenes with Dimethyl Diazomalonate Catalyzed by Chiral Diene.Rhodium Complexes.2010

    • Author(s)
      Nishimura, T., Maeda, Y., Hayashi, T.
    • Journal Title

      Angew.Chem.Int.Ed. 49

      Pages: 7324-7327

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Iridium/Chiral Diene-Catalyzed Asymmetric 1, 6-Addition of Arylboroxines to α,β,γ,δ-Unsaturated Carbonyl Compounds.2010

    • Author(s)
      Nishimura, T., Yasuhara, Y., Sawano, T., Hayashi, T.
    • Journal Title

      J.Am.Chem.Soc. 132

      Pages: 7872-7873

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Tetrafluorobenzobarrelenes as Effective Ligands for Rhodium-Catalyzed Asymmetric 1, 4-Addition of Arylboroxines to β, β-Disubstituted α, β-Unsaturated Ketones.2010

    • Author(s)
      Shintani, R., Takeda, M., Nishimura, T., Hayashi, T.
    • Journal Title

      Angew.Chem.Int.Ed. 49

      Pages: 3969-3971

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Asymmetric Synthesis of Spirocarbocyles : Arylboron Reagents as Surrogates of 1, 2-Dimetalloarenes.2010

    • Author(s)
      Shintani, R., Isobe, S., Takeda, M., Hayashi, T.
    • Journal Title

      Angew.Chem.Int.Ed. 49

      Pages: 3795-3798

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Tetrafluorobenzobarrelene Ligands for the Rhodium-Catalyzed Asymmetric Cycloisomerization of Oxygen-and Nitrogen-Bridged 1, 6-Enynes.2010

    • Author(s)
      Nishimura, T., Kawamoto, T., Nagaosa, M., Kumamoto, H., Hayashi, T.
    • Journal Title

      Angew.Chem.Int.Ed. 49

      Pages: 1638-1641

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to β-Phthaliminoacrylate Esters toward the Synthesis of β-Amino Acids.2010

    • Author(s)
      Nishimura, T., Wang, J., Nagaosa, M., Okamoto, K., Shintani, R., Kwong, F.-Y., Yu, W.-Y., Chan, A.S.C., Hayashi, T.
    • Journal Title

      J.Am.Chem.Soc. 132

      Pages: 464-465

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to β-Phthalimino-acrylate Esters toward the Synthesis of β-Amino Acids2010

    • Author(s)
      Nishimura, T.; Wang, J.; Nagaosa, M.; Okamoto, K.; Shintani, R.; Kwong, F.-Y.; Yu, W.-Y.; Chan, A.S.C.; Hayashi, T.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 464-465

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Tetrafluorobenzobarrelene Ligands for the Rhodium-Catalyzed Asymmetric Cycloisomerization of Oxygen- and Nitrogen-Bridged 1,6-Enynes2010

    • Author(s)
      Nishimura, T.; Kawamoto, T.; Nagaosa, M.; Kumamoto, H.; Hayashi, T.
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 49 Pages: 1638-1641

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Intramolecular Decarboxylative Allylic Arylation of α-Aryl-γ-Methylidene-δ-valerolactones2010

    • Author(s)
      Shintani, R.; Tsuji, T.; Park, S.; Hayashi, T.
    • Journal Title

      Chem.Commun.

      Volume: 46 Pages: 1697-1699

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Aryl- and Alkylation-Oligomerization of Alkynoates with Organoboron Reagents Giving Salicylates2010

    • Author(s)
      Yasuhara, Y.; Nishimura, T.; Hayashi, T.
    • Journal Title

      Chem.Commun.

      Volume: 46 Pages: 2130-2132

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Asymmetric Synthesis of Spirocarbocyles : Arylboron Reagents as Surrogates of 1,2-Dimetalloarenes2010

    • Author(s)
      Shintani, R.; Isobe, S.; Takeda, M.; Hayashi, T.
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 49 Pages: 3795-3798

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Tetrafluorobenzobarrelenes as Effective Ligands for Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboroxines to β,β-Disubstituted α,β-Unsaturated Ketones2010

    • Author(s)
      Shintani, R.; Takeda, M.; Nishimura, T.; Hayashi, T.
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 49 Pages: 3969-3971

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanistic Investigation of the Palladium-Catalyzed Decarboxylative Cyclization of γ-Methylidene-δ-valerolactones with Isocyanates : Kinetic Studies and Origin of the Site Selectivity in the Nucleophilic Attack at a (π-Allyl)palladium2010

    • Author(s)
      Shintani, R.; Tsuji, T.; Park, S.; Hayashi, T.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 7508-7513

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Iridium/Chiral Diene-Catalyzed Asymmetric 1,6-Addition of Arylboroxines to α,β,γ,δ-Unsaturated Carbonyl Compounds2010

    • Author(s)
      Nishimura, T.; Yasuhara, Y.; Sawano,T.; Hayashi, T.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 7872-7873

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organocatalytic Asymmetric Mannich-type Reaction of N-sulfonylimines with Isocyanoacetate Leading to Optically Active 2-Imidazoline-4-carboxylates2010

    • Author(s)
      Zhang, Z.-W.; Lu, G.; Chen, M.-M.; Lin, N.; Li, Y.-B.; Hayashi, T.; Chan, A.S.C.
    • Journal Title

      Tetrahedron Asymmetry

      Volume: 21 Pages: 1715-1721

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Enantioselective Alkynylative Cyclization of Allenyl Aldehydes with Terminal Alkynes2010

    • Author(s)
      Guo, X.-X.; Sawano, T.; Nishimura, T.; Hayashi, T.
    • Journal Title

      Tetrahedron Asymmetry

      Volume: 21 Pages: 1730-1736

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Redox Catalysis of Halide Ion for Formal Cross-Dehydrogenative Coupling : Bromide Ion-Catalyzed Direct Oxidative α-Acetoxylation of Ketones2010

    • Author(s)
      Nagano, T.; Jia, Z.; Li, X.; Yan, M.; Lu, G.; Chan, A.S.C.; Hayashi, T.
    • Journal Title

      Chem.Lett.

      Volume: 39 Pages: 929-931

    • NAID

      10027184527

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Copper-Catalyzed Asymmetric Addition of Arylboronates to Isatins : A Catalytic Cycle Involving Alkoxocopper Intermediates2010

    • Author(s)
      Shintani, R.; Takatsu, K.; Hayashi, T.
    • Journal Title

      Chem.Commun.

      Volume: 46 Pages: 6822-6824

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Asymmetric Conjugate Alkynylation of Nitroalkenes2010

    • Author(s)
      Nishimura, T.; Sawano, T.; Tokuji, S.; Hayashi, T.
    • Journal Title

      Chem.Commun.

      Volume: 46 Pages: 6837-6839

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Asymmetric Cyclopropanation of Alkenes with Dimethyl Diazomalonate Catalyzed by Chiral Diene-Rhodium Complexes2010

    • Author(s)
      Nishimura, T.; Maeda, Y.; Hayashi, T.
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 49 Pages: 7324-7327

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Asymmetric Arylation of Azomethine Imines2010

    • Author(s)
      Shintani, R.; Soh, Y.-T.; Hayashi, T.
    • Journal Title

      Org.Lett.

      Volume: 12 Pages: 4106-4109

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Enantioselective 1,6-Addition of Arylboronic Acids to Enynamides : Asymmetric Synthesis of Axially Chiral Allenylsilanes2010

    • Author(s)
      Nishimura, T.; Makino, H.; Nagaosa, M.; Hayashi, T.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 12865-12867

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Asymmetric Arylation of N-Tosyl Ketimines2010

    • Author(s)
      Shintani, R.; Takeda, M.; Tsuji, T.; Hayashi, T.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 13168-13169

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Asymmetric Hydrosilylation of 1,3-Dienes2010

    • Author(s)
      Han, J.W.; Hayashi, T.
    • Journal Title

      Tetrahedron Asymmetry

      Volume: 21 Pages: 2193-2197

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Asymmetric Conjugate Addition of Arylboroxines to Borylalkenes : Asymmetric Synthesis of β-Arylalkylboranes2010

    • Author(s)
      Sasaki, K.; Hayashi, T.
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 49 Pages: 8145-8147

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] tert-Butoxide-Mediated Arylation of Benzene with Aryl Halides in the Presence of a Catalytic 1,10-Phenanthroline Derivative2010

    • Author(s)
      Shirakawa, E.; Itoh, K.; Higashino, T.; Hayashi, T.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 15537-15539

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to β-Phthaliminoacrylate Esters toward the Synthesis of β-Amino Acids2010

    • Author(s)
      Nishimura, T. ; Wang, J. ; Nagaosa, M. ; Okamoto, K. ; Shintani, R. ; Kwong, F.-Y. ; Yu, W.-Y. ; Chan, A.S.C. ; Hayashi, T.
    • Journal Title

      J.Am.Chem.Soc. 132

      Pages: 464-465

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Tetrafluorobenzobarrelene Ligands for the Rhodium-Catalyzed Asymmetric Cycloisomerization of Oxygen- and Nitrogen-Bridged 1, 6-Enynes2010

    • Author(s)
      Nishimura, T. ; Kawamoto, T. ; Nagaosa, M. ; Kumamoto, H. ; Hayashi, T.
    • Journal Title

      Angew.Chem.Int.Ed. 49

      Pages: 1638-1641

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Intramolecular Decarboxylative Allylic Arylation of α-Aryl-γ-methylidene-δ-valerolactones2010

    • Author(s)
      Shintani, R. ; Tsuji, T. ; Park, S. ; Hayashi, T.
    • Journal Title

      Chem.Commun. 46

      Pages: 1697-1699

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Aryl- and Alkylation-Oligomerization of Alkynoates with Organoboron Reagents Giving Salicylates2010

    • Author(s)
      Yasuhara, Y. ; Nishimura, T. ; Hayashi, T.
    • Journal Title

      Chem.Commun. 46

      Pages: 2130-2132

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Tetrafluorobenzobarrelenes as Effective Ligands for Rhodium-Catalyzed Asymmetric 1, 4-Addition of Arylboroxines to β, β-Disubstituted α, β-Unsaturated Ketones2010

    • Author(s)
      Shintani, R. ; Takeda, M. ; Nishimura, T. ; Hayashi, T.
    • Journal Title

      Angew.Chem.Int.Ed. 49(掲載決定)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Asymmetric Synthesis of Spirocarbocyles : Arylboron Reagents as Surrogates of 1, 2-Dimetalloarenes2010

    • Author(s)
      Shintani, R. ; Isobe, S. ; Takeda, M. ; Hayashi H.
    • Journal Title

      Angew.Chem.Int.Ed. 49(掲載決定)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Enantioselective Alkynylative Cyclization of Allenyl Aldehydes with Terminal Alkynes2010

    • Author(s)
      Guo, X.-X. ; Sawano, T. ; Nishimura, T. ; Hayashi, T.
    • Journal Title

      Tetrahedron Asymmetry 21(掲載決定)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Diene Ligands for Asymmetric Catalysis.2009

    • Author(s)
      Shintani, R., Hayashi, T.
    • Journal Title

      Aldrichimica Acta 42

      Pages: 31-38

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Sodium Tetraarylborates as Effective Nucleophiles in the Rhodium/Diene-Catalyzed 1, 4-Addition to β, β-Disubstituted α, β-Unsaturated Ketones : Catalytic Asymmetric Construction of Quaternary Carbon Stereocenters.2009

    • Author(s)
      Shintani, R., Tsutsumi, Y., Nagaosa, M., Nishimura, T., Hayashi, T.
    • Journal Title

      J.Am.Chem.Soc. 131

      Pages: 13588-13589

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Tuning the Chiral Environment of C_2-Symmetric Diene Ligands : Development of 3, 7-Disubstituted Bicyclo[3.3.1]nona-2, 6-dienes.2009

    • Author(s)
      Shintani, R., Ichikawa, Y., Takatsu, K., Chen, F.-X., Hayashi, T.
    • Journal Title

      J.Org.Chem. 74

      Pages: 869-873

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Tuning the Chiral Environment of C_2-Symmetric Diene Ligands : Development of 3, 7-Disubstituted Bicyclo [3.3.1] nona-2, 6-dienes2009

    • Author(s)
      Shintani, R. ; Ichikawa, Y. ; Takatsu, K. ; Chen, F.-X. ; Hayashi, T.
    • Journal Title

      J.Org.Chem. 74

      Pages: 869-873

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stereoselective Synthesis of Nipecotic Acid Derivatives via Palladium-Catalyzed Decarboxylative Cycloaddition of γ-Methylidene-δ-valerolactones with Imines2009

    • Author(s)
      Shintani, R. ; Murakami, M. ; Hayashi, T.
    • Journal Title

      Org.Lett. 11

      Pages: 457-459

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-catalyzed Decarboxylative [4+1] Cyclization of γ-Methylidene-δ-valerolactones with Isocyanides2009

    • Author(s)
      Park, S. ; Shintani, R. ; Hayashi, T.
    • Journal Title

      Chem.Lett. 38

      Pages: 204-205

    • NAID

      10025119661

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Iron-Catalyzed Carbolithiation of Alkynes Having No Heteroatoms2009

    • Author(s)
      Shirakawa, E. ; Ikeda, D. ; Ozawa, T. ; Watanabe, S. ; Hayashi, T.
    • Journal Title

      Chem.Commun.

      Pages: 1885-1887

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Asymmetric Hydroalkoxylation and Hydrosulfenylation of Diphenylphosphinylallenes2009

    • Author(s)
      Kawamoto, T. ; Hirabayashi, S. ; Guo, X.-X. ; Nishimura, T. ; Hayashi, T.
    • Journal Title

      Chem.Commun.

      Pages: 3528-3530

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electronic and Steric Tuning of Chiral Diene Ligands for Rhodium-Catalyzed Asymmetric Arylation of Imines2009

    • Author(s)
      Okamoto, K. ; Hayashi, T. ; Rawal, V.H.
    • Journal Title

      Chem.Commun.

      Pages: 4815-4817

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ruthenium-Catalyzed Transformation of Alkenyl Triflates to Alkenyl Halides2009

    • Author(s)
      Shirakawa, E. ; Imazaki, Y. ; Hayashi, T.
    • Journal Title

      Chem.Commun.

      Pages: 5088-5090

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Asymmetric Polymerization of Achiral Arylacetylenes Giving Helical Polyacetylenes in the Presence of a Rhodium Catalyst with C_2-Symmetric Tetrafluorobenzobarrelene Ligand2009

    • Author(s)
      Nishimura, T. ; Ichikawa, Y. ; Hayashi, T. ; Onishi, N. ; Shiotsuki, M. ; Masuda, T.
    • Journal Title

      Organometallics 28

      Pages: 4890-4893

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Asymmetric [5+2] Cycloaddition of Alkyne-Vinylcyclopropanes2009

    • Author(s)
      Shintani, R. ; Nakatsu, H. ; Takatsu, K. ; Hayashi, T.
    • Journal Title

      Chem.Eur.J. 15

      Pages: 8692-8694

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Asymmetric Conjugate Alkynylation of Enones with Alkynylsilanols2009

    • Author(s)
      Nishimura, T. ; Tokuji, S. ; Sawano, T. ; Hayashi, T.
    • Journal Title

      Org.Lett. 11

      Pages: 3222-3225

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Concise Synthesis of Chiral tfb Ligands and Their Application to Rhodium-Catalyzed Asymmetric Arylation of Aldehydes2009

    • Author(s)
      Nishimura, T. ; Kumamoto, H. ; Nagaosa, M. ; Hayashi, T.
    • Journal Title

      Chem.Commun.

      Pages: 5713-5715

    • NAID

      120006653852

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stereoselective Synthesis of Spirooxindoles by Palladium-Catalyzed Decarboxylative Cyclization of γ-Methylidene-δ-valerolactones with Isatins2009

    • Author(s)
      Shintani, R. ; Hayashi, S. ; Murakami, M. ; Takeda, M. ; Hayashi, T.
    • Journal Title

      Org.Lett. 11

      Pages: 3754-3756

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Diene Ligands for Asymmetric Catalysis2009

    • Author(s)
      Shintani, R. ; Hayashi, T.
    • Journal Title

      Aldrichimica Acta 42

      Pages: 31-38

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sodium Tetraarylborates as Effective Nucleophiles in the Rhodium/Diene-Catalyzed 1, 4-Addition to β, β-Disubstituted α, β-Unsaturated Ketones : Catalytic Asymmetric Construction of Quaternary Carbon Stereocanters2009

    • Author(s)
      Shintani, R. ; Tsutsumi, Y. ; Nagaosa, M. ; Nishimura, T. ; Hayashi, T.
    • Journal Title

      J.Am.Chem.Soc. 131

      Pages: 13588-13589

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Asymmetric Synthesis of β-Alkynyl Aldehydes by Rhodium-Catalyzed Conjugate Alkynylation2009

    • Author(s)
      Nishimura, T. ; Sawano, T. ; Hayashi, T.
    • Journal Title

      Angew.Chem.Int.Ed. 48

      Pages: 8057-8059

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Decarboxylative [4+3] Cyclization of γ-Methylidene-δ-valerolactones with 1, 1-Dicyanocyclopropanes2009

    • Author(s)
      Shintani, R. ; Murakami, M. ; Tsuji, T. ; Tanno, H. ; Hayashi, T.
    • Journal Title

      Org.Lett. 11

      Pages: 5642-5645

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tuning the Chiral Environment of C_2-Symmetric Diene Ligands : Development of 3, 7-Disubstituted Bicyclo[3.3.1]nona-2, 6-dienes2009

    • Author(s)
      Shintani, R., Ichikawa, Y., Takatsu, K., Chen F. -X, Havashi, T.
    • Journal Title

      J. Org. Chem. 74

      Pages: 869-873

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stereoselective Synthesis of Nipecotic Acid Derivatives via Palladium-Catalyzed Decarboxylatlve Cycloaddition of γ -Methylidene-δ-valerolaotones with Imines2009

    • Author(s)
      Shintani, R., Murakami, M., Hayashi, T.
    • Journal Title

      Org. Lett. 11

      Pages: 457-459

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-catalyzed Decarboxylative [4+1]Cyclization of γ-Methylidene-δ-val-valerolactones with Isocyanides2009

    • Author(s)
      Park, S., Shintani, R., Hayashi, T.
    • Journal Title

      Chem. Lett. 38

      Pages: 204-205

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Iron-catalyzed carbolithiation of alkynes having no heteroatoms2009

    • Author(s)
      Shirakawa, E., Ikeda, D., Ozawa, T., Watanabe, S., Hayashi, T.
    • Journal Title

      Chem. Commun.

      Pages: 1885-1887

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes2009

    • Author(s)
      Kawamoto, T., Hirabayashi, S., Guo, X. -X., Nishimura, T., Hayashi, T.
    • Journal Title

      Chem. Coamun.

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Simple Chiral Diene Ligands Provide High Enantioselectivities in Transition-Metal-Catalyzed Conjugate Addition Reactions.2008

    • Author(s)
      Okamoto, K., Hayashi, T., Rawal, V.
    • Journal Title

      H.Org.Lett. 10

      Pages: 4387-4389

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Rearrangement of Aryl Bis(alkynyl) Carbinols to 3-Alkynyl-1-indanones2008

    • Author(s)
      Shintani, R., Takatsu, K., Katoh, T., Nishimura, T., Hayashi, T.
    • Journal Title

      Angew. Chem. Int. Ed. 47

      Pages: 1447-1449

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Platinum-Catalyzed Generation of Silylenes from Hydrodisilanes and Their Addition to α, β-Unsaturated Ketones2008

    • Author(s)
      Okamoto, K., Hayashi, T.
    • Journal Title

      Chem. Lett. 37

      Pages: 108-109

    • NAID

      10020148253

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Fe-Cu cooperative catalysis in isomerization of alkyl Grignard reagents2008

    • Author(s)
      Shirakawa, E., Ikeda, D., Yamaguchi, S., Hayashi, T.
    • Journal Title

      Chem. Commun.

      Pages: 1214-1216

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Steric Tuning of Silylacetylenes and Chiral Phosphine Ligands for Rhodium-Catalyzed Asymmetric Conjugate Alkynylation of Enones2008

    • Author(s)
      Nishimura, T., Guo, X. -X., Uchiyama, N., Katoh, T., Hayashi, T.
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 1576-1577

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Addition of Organo[2-(hydroxymethyl)-phenyl]diraethylsilanes to Arenesulfonylimines2008

    • Author(s)
      Nakao, Y., Takeda, M., Chen, J. -S., Hiyama, T., Ichikawa, Y., Shintani, R., Hayashi, T.
    • Journal Title

      Chem. Lett. 37

      Pages: 290-291

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium/Chiral Diene-Catalyzed Asymmetric 1, 4-Addition of Arylboronic Acids to Arylmethylene Cyanoacetates2008

    • Author(s)
      Sorgel, S., Tokunaga, N., Sasaki, K., Okamoto, K., Hayashi, T.
    • Journal Title

      Org. Lett. 10

      Pages: 589-592

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Kinetic Resolution of Tertiary Homoallyl Alcohols via Stereoselective Carbon-Carbon Bond Cleavage2008

    • Author(s)
      Shintani, R., Takatsu, K., Hayashi, T.
    • Journal Title

      Org. Lett. 10

      Pages: 1191-1193

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Asymmetric Addition of Terminal Alkynes to Diarylphosphinylallenes2008

    • Author(s)
      Nishimura, T., Guo, X. -X., Hayashi, T.
    • Journal Title

      Chem. Asian J. 3

      Pages: 1505-1510

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cobalt-catalyzed Coupling of Alkenyl Triflates with Aryl and Alkenyl Grignard Reagents2008

    • Author(s)
      Shirakawa, E., Imazaki, Y., Hayashi, T.
    • Journal Title

      Chem. Lett. 37

      Pages: 654-655

    • NAID

      10021081549

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ruthenium-catalyzed 1, 4-Addition of Organoboronic Acids to α, β-Unsaturated Ketones2008

    • Author(s)
      Shintani, R., Hayashi, T.
    • Journal Title

      Chem. Lett. 37

      Pages: 724-725

    • NAID

      10021082149

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] C_2-Symmetric Tetrafluorobenzobarrelenes as Highly Efficient Ligands for the Iridium-Catalyzed Asymmetric Annulation of 1, 3 Dienes with 2-Formylphenylboron Reagents2008

    • Author(s)
      Nishimura, T., Yasuhara, Y., Hayashi, T.
    • Journal Title

      Tetrahedron Asymmetry 19

      Pages: 1778-1783

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Platinum-catalyzed 1, 4-Addition of Arylboronic Acids to β-Substituted α, β-Unsaturated Ketones2008

    • Author(s)
      Hayashi, T., Sasaki, K.
    • Journal Title

      Chem. Lett. 37

      Pages: 842-843

    • NAID

      10024281403

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Tetrafluorobenzobarrelenes as Highly Efficient Ligands for the Rhodium-catalyzed Asymmetric 1, 4-Addition of Arylboronic Acids2008

    • Author(s)
      Nishimura, T., Nagaosa, M., Hayashi, T.
    • Journal Title

      Chem. Lett. 37

      Pages: 860-861

    • NAID

      10024281577

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Asymmetric Ring-Opening Alkynylation of Azabenzonorbornadi enes2008

    • Author(s)
      Nishimura, T., Tsurumaki, E., Kawamoto, T., Guo, X. -X., Hayashi, T.
    • Journal Title

      Org. Lett. 10

      Pages: 4057-4060

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Simple Chiral Diene Ligands Provide High Enantioselectivities in Transition-Metal-Catalyzed Conjugate Addition Reactions2008

    • Author(s)
      Okamoto, K., Hayashi, T., Rawal, V. H.
    • Journal Title

      Org. Lett. 10

      Pages: 4387-4389

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Asymmetric [4+2]Cycloaddition of γ-Methylidene-δ-valero-lactones with Isocyanates ; Conversion, of Racemic Lactones to Enantio-enriched Lactaras2008

    • Author(s)
      Shintani, R., Park, S., Shirozu, F., Murakami, M., Hayashi, T.
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 16174-16175

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Rearrangement of Aryl Bis (alkynyl) Carbinols to 3-Alkynyl-1-indanones2008

    • Author(s)
      Shintani, R.; Takatsu, K.; Katoh, T.; Nishimura, T.; Hayashi, T.
    • Journal Title

      Angew. Chem. Int. Ed. 47

      Pages: 1447-1449

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Platinum-Catalyzed Generation of Silylenes from Hydrodisilanes and Their Addition to α,β-Unsaturated Ketones2008

    • Author(s)
      Okamoto, K.; Hayashi, T.
    • Journal Title

      Chem. Lett. 37

      Pages: 108-109

    • NAID

      10020148253

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Fe-Cu cooperative catalysis in isomerization of alkyl Grignard reagents2008

    • Author(s)
      Shirakawa, E.; Ikeda, D.; Yamaguchi, S.; Hayashi, T.
    • Journal Title

      Chem. Common.

      Pages: 1214-1216

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Steric Tuning of Silylacetylenes and Chiral Phosphine Ligands for Rhodium-Catalyzed Asymmetric Conjugate Alkynylation of Enones2008

    • Author(s)
      Nishimura, T.; Guo, X.-X.; Uchiyama, N.; Katoh, T.; Hayashi, T.
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 1576-1577

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Addition of Organo [2-(hydroxymethyl)-phenyl] dimethylsilanes to Arenesulfonylimines2008

    • Author(s)
      Nakao, Y.; Takeda, M.; Chen, J.-S.; Hiyama, T.; Ichikawa, Y.; Shintani, R.; Hayashi, T.
    • Journal Title

      Chem. Lett. 37

      Pages: 290-291

    • NAID

      10021078372

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium/Chiral Diene-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to Arylmethylene Cyanoacetates2008

    • Author(s)
      Sorgel, S.; Tokunaga, N.; Sasaki, K.; Okamoto, K.; Hayashi, T.
    • Journal Title

      Org. Lett. 10

      Pages: 589-592

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Kinetic Resolution of Tertiary Homoallyl Alcohols via Stereoselective Carbon-Carbon Bond Cleavage2008

    • Author(s)
      Shintani, R.; Takatsu, K.; Hayashi, T.
    • Journal Title

      Org. Lett. 10

      Pages: 1191-1193

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Asymmetric Addition of Terminal Alkynes to Diarylphosphinylallenes2008

    • Author(s)
      Nishimura, T.; Guo, X.-X.; Hayashi, T.
    • Journal Title

      Chem. Asian J. 3(in press)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cobalt-catalyzed Coupling of Alkenyl Triflates with Aryl and Alkenyl Grignard Reagents2008

    • Author(s)
      Shirakawa, E.; Imazaki, Y.; Hayashi, T.
    • Journal Title

      Chem. Lett. 37(in press)

    • NAID

      10021081549

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Cationic Rhodium-Chiral Diene Complex as a High-Performance Catalyst for the Intramolecular Asymmetric [4+2] Cycloaddition of Alkyne-1, 3-Dienes.2007

    • Author(s)
      Shintani, R., Sannohe, Y., Tsuji, T., Hayashi, T.
    • Journal Title

      Angew.Chem.Int.Ed. 46

      Pages: 7277-7280

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Organo[2-(hydroxymethyl)phenyl]dimethylsilanes as Mild and Reproducible Agents for Rhodium-Catalyzed 1, 4-Addition Reactions.2007

    • Author(s)
      Nakao, Y., Chen, J.-S., Imanaka, H., Hiyama, T., Ichikawa, Y., Duan, W.-L., Shintani, R., Hayashi, T.
    • Journal Title

      J.Am.Chem.Soc. 129

      Pages: 9137-9143

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Phosphine.Olefin Ligands in the Rhodium-Catalyzed Asymmetric 1, 4-Addition Reactions.2007

    • Author(s)
      Duan, W.-L., Iwamura, H., Shintani, R., Hayashi, T.
    • Journal Title

      J.Am.Chem.Soc. 129

      Pages: 2130-2138

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Asymmetric Cyclodimerization of Oxa-and Azabicyclic Alkenes2007

    • Author(s)
      Nishimura, T.; Kawamoto, T.; Sasaki, K.; Tsurumaki, E.; Hayashi, T.
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 1492-1493

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Phosphine-Olefin Ligands in the Rhodium-Catalyzed Asymmetric 1,4-Addition Reactions2007

    • Author(s)
      Duan, W.-L.; Iwamura, H.; Shintani, R.; Hayashi, T.
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 2130-2138

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Iron-Catalyzed Arylmagnesiation of Aryl (alkyl) acetylenes in the Presence of an N-Heterocyclic Carbene Ligand2007

    • Author(s)
      Yamagami, T.; Shintani, R.: Shirakawa, E.; Hayashi, T.
    • Journal Title

      Org. Lett. 9

      Pages: 1405-1408

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Asymmetric 1,4-addition of organoboron reagents to quinone monoketals catalyzed by a chiral diene/rhodium complex: a new synthetic route to enantio-enriched 2-aryltetralones2007

    • Author(s)
      Tokunaga, N.; Hayashi, T.
    • Journal Title

      Adv. Synth. Catal. 349

      Pages: 513-516

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-catalyzed conjugate reduction of enones into α,β-dideuterioketones with hexamethyldisilane and deuterium oxide2007

    • Author(s)
      Otsuka, H.; Shirakawa, E.; Hayashi, T.
    • Journal Title

      Chem. Commun.

      Pages: 1819-1821

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Asymmetric Synthesis of 3,3-Disubstituted 1-Indanones2007

    • Author(s)
      Shintani, R.; Takatsu, K.; Hayashi, T.
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 3735-3737

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Aryl Transfer from tert-Arylmethanols to α,β-Unsaturated Carbonyl Compounds2007

    • Author(s)
      Nishimura, T.; Katoh, T.; Hayashi, T.
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 4937-4939

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Asymmetric Construction of Chiral C-N Axes through Rhodium-Catalyzed 1,4-Addition2007

    • Author(s)
      Duan, W.-L.; Imazaki, Y.; Shintani, R.; Hayashi, T.
    • Journal Title

      Tetrahedron 63

      Pages: 8529-8536

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Asymmetric [3+3] Cycloaddition of Trimethylenemethanes with Nitrones2007

    • Author(s)
      Shintani, R.; Park, S.; Duan, W.-L.; Hayashi, T.
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 5901-5903

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Iridium-Catalyzed [3+2] Annulation of 1,3-Dienes with ortho-Carbonylated Phenylboronic Acids. A Novel Catalytic Process Involving Regioselective 1,2-Addition2007

    • Author(s)
      Nishimura, T.; Yasuhara, Y.; Hayashi, T.
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 7506-7507

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organo [2-(hydroxymethyl) phenyl] dimethylsilanes as Mild and Reproducible Agents for Rhodium-Catalyzed 1,4-Addition Reactions2007

    • Author(s)
      Nakao, Y.; Chen, J.-S.; Imanaka, H.; Hiyama, T.; Ichikawa, Y.; Duan, W.-L.; Shintani, R.; Hayashi, T
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 9137-9143

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Cationic Rhodium-Chiral Diene Complex as a High-Performance Catalyst for the Intramolecular Asymmetric [4+2] Cycloaddition of Alkyne-1,3-Dienes2007

    • Author(s)
      Shintani, R.; Sannohe, Y.; Tsuji, T.; Hayashi, T.
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 7277-7280

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cobalt-catalyzed cross-coupling of alkynyl Grignard reagents with alkenyl triflates2007

    • Author(s)
      Shirakawa, E.; Sato, T.; Imazaki, Y.; Kimura, T.; Hayashi, T.
    • Journal Title

      Chem. Commun.

      Pages: 4513-4515

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] γ-Methylene-δ-valerolactones as a Coupling Partner for Cycloaddition: Palladium-Catalyzed [4+3] Cycloaddition with Nitrones2007

    • Author(s)
      Shintani, R.; Murakami, M.; Hayashi, T.
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 12356-12357

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Regioselective Hydroalkynylation of Internal Alkynes with Silylacetylenes: An Alkynylrhodium (I) Intermediate Generated from [Rh (OH) (binap)]_22007

    • Author(s)
      Nishimura, T.; Guo, X.-X.; Ohnishi, K.; Hayashi. T.
    • Journal Title

      Adv. Synth. Catal. 349

      Pages: 2669-2672

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Asymmetric Synthesis of Allylsilanes through Rhodium/Chiral Diene-Catalyzed 1,4-Addition of Alkenyl [2-(hydroxymethyl) phenyl] dimethylsilanes2007

    • Author(s)
      Shintani, R.; Ichikawa, Y.; Hayashi, T.; Chen, J.; Nakao, Y.; Hiyama, T.
    • Journal Title

      Org. Lett. 9

      Pages: 4643-4645

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Asymmetric Rearrangement of Alkynyl Alkenyl Carbinols: Synthetic Equivalent to Asymmetric Conjugate Alkynylation of Enones2007

    • Author(s)
      Nishimura, T.; Katoh, T.; Takatsu, K.; Shintani, R.; Hayashi, T.
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 14158-14159

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of arylzinc reagents and their use in the rhodium-catalyzed asymmetric 1,4-addition for the synthesis of 2-aryl-4-piperidones2007

    • Author(s)
      Shintani, R.; Hayashi, T.
    • Journal Title

      Nature Protocols 2

      Pages: 2903-2909

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Synthesis of Spiro [2.4] heptanes: Ligand-Dependent Position-Control in the Nucleophilic Attack to a π-Allylpalladium Intermediate2007

    • Author(s)
      Shintani, R.; Park, S.; Hayashi, T.
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 14866-14867

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Platinum-Catalyzed Addition of Dimethylsilylene to β-Methyl α,β-Unsaturated Ketones: γ-Silylation Forming 1-Oxa-2-silacyclohex-5-enes2007

    • Author(s)
      Okamoto, K.; Hayashi, T.
    • Journal Title

      Org. Lett. 9

      Pages: 5067-5069

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Unprecedented Formation of μ-Vinylidene Complexes from Phospharuthenocene and Acyl Chloride via Activation of the C=0 Double Bond2007

    • Author(s)
      Ogasawara, M.; Sakamoto, T.; Ito, A.; Ge, Y.; Nakajima, K.; Takahashi, T.; Hayashi, T.
    • Journal Title

      Organometallics 26

      Pages: 6698-6700

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] パラジウム触媒によるγ-メチリデン-δ-バレロラクトンとイソシアネートとの脱炭酸を伴う環化反応の機構に関する研究2011

    • Author(s)
      新谷亮
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春期年会(2011)講演予稿集
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] ロジウム触媒を用いたニトロアルケンの不斉共役アルキニル化反応2011

    • Author(s)
      澤野卓大
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春期年会(2011)講演予稿集
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] ロジウム触媒を用いたアリールボロキシンのβ-アルコキシアクリル酸エステルへの不斉1,4付加反応2011

    • Author(s)
      笠井惇如
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春期年会(2011)講演予稿集
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] ロジウム-キラルジエン触媒による末端アルキンの環状エノンへの不斉共役付加反応2011

    • Author(s)
      永長誠
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春期年会(2011)講演予稿集
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] 銅触媒による有機ボロン酸エステルのアルキリデンシアノ酢酸エステルへの不斉1,4-付加反応2011

    • Author(s)
      高津慶士
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春期年会(2011)講演予稿集
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] ロジウム触媒によるN-トシルケトイミンの不斉アリール化反応2011

    • Author(s)
      竹田桃太郎
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春期年会(2011)講演予稿集
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] パラジウム触媒を用いた脱炭酸を伴う2-アルキリデントリメチレンカーボネートとイソシアネートによるシクロプロパン化反応2011

    • Author(s)
      守屋孝平
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春期年会(2011)講演予稿集
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] 新規光学活性ホスフィン-オレフィン配位子の合成とロジウム触媒による不斉1,4-付加への利用2011

    • Author(s)
      成井倫太郎
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春期年会(2011)講演予稿集
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] 遷移金属を用いないGrignard反応剤とハロゲン化アリールのカップリング反応2011

    • Author(s)
      林裕美
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春期年会(2011)講演予稿集
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] ルテニウム触媒を用いるアリールトリフラートのハロゲン化物への変換反応2011

    • Author(s)
      今崎雄介
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春期年会(2011)講演予稿集
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] イリジウム/キラルジエン触媒を用いたアリールボロキシンのδ-アリール-α,β,γ,δ-不飽和カルボニル化合物への不斉1,6付加反応2011

    • Author(s)
      野一色彰
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春期年会(2011)講演予稿集
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] 鉄触媒によるアルキンのアリールリチウム化を用いたベンゾシロールの合成2011

    • Author(s)
      増井誠二
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春期年会(2011)講演予稿集
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] 鉄触媒を用いるアリールボロン酸と芳香族化合物の酸化的カップリング反応2011

    • Author(s)
      内山七瀬
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春期年会(2011)講演予稿集
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] 鉄触媒によるフェニルチタン試薬を用いたアリールケトンのピナコールカップリング反応2011

    • Author(s)
      佐々木恵吾
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春期年会(2011)講演予稿集
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] Rhodium-Catalyzed Asymmetric Construction of Tetrasubstituted Carbon Stereocenters2010

    • Author(s)
      R.Shintani
    • Organizer
      Pacifichem 2010 ; Symposium # 199
    • Place of Presentation
      Honolulu, Hawaii, USA(招待講演)
    • Year and Date
      2010-12-20
    • Related Report
      2010 Annual Research Report
  • [Presentation] Ruthenium-Catalyzed Coupling of Alkenyl Triflates with Heteroatom Nucleophiles2010

    • Author(s)
      Y.Imazaki
    • Organizer
      Pacifichem 2010 ; Symposium #283
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2010-12-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Reactions of Grignard Reagents Catalyzed Cooperatively by Iron and Copper Complexes2010

    • Author(s)
      E.Shirakawa
    • Organizer
      Pacifichem 2010 ; Symposium #14
    • Place of Presentation
      Honolulu, Hawaii, USA(招待講演)
    • Year and Date
      2010-12-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Rhodium-Catalyzed Asymmetric Conjugated Alkynylation of α,β-Unsaturated Aldehydes2010

    • Author(s)
      T.Sawano
    • Organizer
      Pacifichem 2010 ; Symposium #282
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2010-12-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Rhodium/Chiral Diene-Catalyzed Asymmetric 1,4-Addition of Arylboroxines to β,β-Disubstituted α,β-Unsaturated Ketones2010

    • Author(s)
      M.Takeda
    • Organizer
      Pacifichem 2010 ; Symposium #282
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2010-12-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] t-Butoxide-Meditated Arylation of Benzene with Aryl Halides in the Presence of a Catalytic Amount of a 1,10-Phenanthroline Derivative2010

    • Author(s)
      K.Itoh
    • Organizer
      Pacifichem 2010 ; Symposium #132
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2010-12-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Rhodium-Catalyzed Asymmetric Alkynylations2010

    • Author(s)
      T.Nishimura
    • Organizer
      Pacifichem 2010 ; Symposium #85
    • Place of Presentation
      Honolulu, Hawaii, USA(招待講演)
    • Year and Date
      2010-12-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] Recent Advances in the Chiral Diene Ligands for Asymmetric Catalysis2010

    • Author(s)
      T.Hayashi
    • Organizer
      Pacifichem 2010 ; Symposium #282
    • Place of Presentation
      Honolulu, Hawaii, USA(招待講演)
    • Year and Date
      2010-12-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] Rhodium-Catalyzed Asymmetric Addition of Aarylboron Reagents to Alkenylboranes2010

    • Author(s)
      K.Sasaki
    • Organizer
      Pacifichem 2010 ; Symposium #282
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2010-12-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] キラルジエン配位子-最近の進歩2010

    • Author(s)
      林民生
    • Organizer
      平成22年度後期有機合成化学講習会「躍進する有機合成-天然物からライフサイエンス,材料まで-」
    • Place of Presentation
      日本薬学会,東京(招待講演)
    • Year and Date
      2010-11-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] キラルジエン配位子2010

    • Author(s)
      林民生
    • Organizer
      第30回有機合成若手セミナー「明日の有機合成を担う人のために」
    • Place of Presentation
      大阪府立大学,堺(招待講演)
    • Year and Date
      2010-11-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] 鉄触媒を用いるアルキルアミドとアレーンの酸化的カップリング反応2010

    • Author(s)
      内山七瀬
    • Organizer
      第57回有機金属化学討論会
    • Place of Presentation
      中央大学,八王子
    • Year and Date
      2010-09-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] ロジウム触媒による不斉四置換炭素のエナンチオ選択的な構築2010

    • Author(s)
      新谷亮
    • Organizer
      第57回有機金属化学討論会
    • Place of Presentation
      中央大学,八王子
    • Year and Date
      2010-09-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] ロジウム触媒を用いたニトロアルケンの不斉共役アルキニル化反応2010

    • Author(s)
      澤野卓大
    • Organizer
      第57回有機金属化学討論会
    • Place of Presentation
      中央大学,八王子
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] Chiral Diene Ligands for Asymmetric Catalysis2010

    • Author(s)
      T.Hayashi
    • Organizer
      Pre-symposium on Organometallic Chemistry for 24th International Conference on Organometallic Chemistry (ICOMC 24)
    • Place of Presentation
      Taipei, China(基調講演)
    • Year and Date
      2010-07-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Recent Advances in Rhodium-Catalyzed Asymmetric Addition Reactions2010

    • Author(s)
      林民生
    • Organizer
      The 1st North West Organic Chemistry Symposium
    • Place of Presentation
      Manchester, UK
    • Year and Date
      2010-07-06
    • Related Report
      2010 Final Research Report
  • [Presentation] Recent Advances in Rhodium-Catalyted Asymmetric Addition Reactions2010

    • Author(s)
      T.Hayashi
    • Organizer
      The 1st North West Organic Chemistry Symposium
    • Place of Presentation
      Manchester, UK(基調講演)
    • Year and Date
      2010-07-06
    • Related Report
      2010 Annual Research Report
  • [Presentation] Chiral Diene Ligands for Asymmetric Catalysis2010

    • Author(s)
      T.Hayashi
    • Organizer
      The 21st French-Japanese Symposium on Medicinal and Fine Chemistry (FJS-2010)
    • Place of Presentation
      Kyoto, Japan(招待講演)
    • Year and Date
      2010-05-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] パラジウム触媒によるγ-メチリデン-δ-バレロラクトンと1, 1-ジシアノシクロプロパンとの脱炭酸を伴う[4+3]環化付加反応2010

    • Author(s)
      辻孝宙
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学, 本部キャンパス
    • Year and Date
      2010-03-29
    • Related Report
      2009 Annual Research Report
  • [Presentation] テトラアリールホウ酸ナトリウムを用いたロジウム/ジエン触媒によるβ位二置換α, β-不飽和ケトンへの1, 4-付加反応2010

    • Author(s)
      堤洋介
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学, 本部キャンパス
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] ロジウム/キラルジエン触媒によるアリールボロキシンのβ位二置換α, β-不飽和ケトンへの不斉1, 4-付加反応2010

    • Author(s)
      竹田桃太郎
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学, 本部キャンパス
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] ロジウム/キラルジエン触媒によるスピロ型炭素環状化合物の不斉合成2010

    • Author(s)
      磯部真吾
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学, 本部キャンパス
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] ロジウム触媒によるアリールボロン酸の共役エンインへの不斉付加反応を用いた三置換アレンの不斉合成2010

    • Author(s)
      牧野拓紀
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学, 本部キャンパス
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] ロジウム/キラルジエン触媒を用いた1, 8-ジインの不斉重合反応によるらせんポリアセチレンの合成2010

    • Author(s)
      市川喜隆
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学, 本部キャンパス
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] テトラフルオロベンゾバレレン骨格を有する新規キラルジエン-ロジウム錯体を用いたスチレン類のジアゾ化合物による不斉シクロプロパン化反応2010

    • Author(s)
      前田祐子
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学, 本部キャンパス
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] ロジウム触媒を用いたアルケニルボロン酸誘導体に対する不斉付加反応2010

    • Author(s)
      佐々木恵吾
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学, 本部キャンパス
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] β-アミノ酸の合成を指向したロジウム触媒によるアリールボロン酸の不斉1, 4-付加反応2010

    • Author(s)
      永長誠
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学, 本部キャンパス
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] ロジウム触媒を用いたイサチンの不斉アルキニル化反応2010

    • Author(s)
      澤野卓大
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学, 本部キャンパス
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] イリジウム触媒を用いたアリールボロン酸のα, β, γ, δ-不飽和カルボニル化合物への不斉1, 6付加反応2010

    • Author(s)
      安原祐一
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学, 本部キャンパス
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] ルテニウム触媒を用いるアルケニルトリフラートとヘテロ元素求核剤のカップリング反応2010

    • Author(s)
      今崎雄介
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学, 本部キャンパス
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] t-ブトキシドと触媒量の1, 10-フェナントロリン誘導体を用いるハロゲン化アリールとベンゼン誘導体のカップリング反応2010

    • Author(s)
      伊藤賢一
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学, 本部キャンパス
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] カリウムt-ブトキシドを用いるヨウ化アリールとアルケンのカップリング反応2010

    • Author(s)
      張学景
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学, 本部キャンパス
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] 鉄-銅協同触媒を用いるアルケンのヒドロマグネシウム化反応2010

    • Author(s)
      増井誠二
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学, 本部キャンパス
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] 鉄触媒を用いるアルキンのアリールおよびアルケニルリチウム化反応2010

    • Author(s)
      成井倫太郎
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学, 本部キャンパス
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] 鉄触媒を用いるアルキルアミドと炭素求核剤の酸化的カップリング反応 : アルキルアミドの酸化とそれに続く炭素求核剤との炭素-炭素結合形成反応2010

    • Author(s)
      内山七瀬
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学, 本部キャンパス
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] 鉄触媒を用いるアルキルアミンの酸化的カップリング反応2010

    • Author(s)
      守屋孝平
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学, 本部キャンパス
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] 鉄触媒によるアリールボロン酸エステルのイサチンへの不斉付加反応2010

    • Author(s)
      高津慶士
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学, 本部キャンパス
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] Recent Advances in the Chiral Diene Ligands for Asymmetric Catalysis2009

    • Author(s)
      林民生
    • Organizer
      International Symposium on Catalysis and Fine Chemicals (C&FC 2009)
    • Place of Presentation
      Seoul, Korea
    • Year and Date
      2009-12-16
    • Related Report
      2010 Final Research Report
  • [Presentation] Recent Advances in the Chiral Diene Ligands for Asymmetric Catalysis2009

    • Author(s)
      T.Hayashi
    • Organizer
      Intermational Symposium on Catalysis and Fine Chemicals(C & FC 2009)
    • Place of Presentation
      Seoul, Korea
    • Year and Date
      2009-12-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] ここまで進歩したロジウム触媒不斉付加反応2009

    • Author(s)
      林民生
    • Organizer
      第58回有機合成化学協会関東支部シンポジウム
    • Place of Presentation
      長岡技術科学大学, 講義棟
    • Year and Date
      2009-11-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] Chiral Tetrafluorobenzobarrelene Ligands for Rhodium-Catalyzed Asymmetric Reactions2009

    • Author(s)
      T.Nishimura
    • Organizer
      The 11th International Kyoto Conference on New Aspects of Organic Chemistry(IKCOC 11)
    • Place of Presentation
      Kyoto, Rihga Royal Hotel Kyoto
    • Year and Date
      2009-11-13
    • Related Report
      2009 Annual Research Report
  • [Presentation] Rhodium-Catalyzed Asymmetric [5+2] Cycloaddition of Allkyne-Vinylcyclopropanes2009

    • Author(s)
      K.Takatsu
    • Organizer
      The 11th International Kyoto Conference on New Aspects of Organic Chemistry(IKCOC 11)
    • Place of Presentation
      Kyoto, Rihga Royal Hotel Kyoto
    • Year and Date
      2009-11-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] Stereoselective Synthesis of Spirooxindoles by Palladium-Catalyzed Decarboxylative Cyclization of γ-Methylidene-δ-valerolactones with Isatins2009

    • Author(s)
      M.Takeda
    • Organizer
      The 11th International Kyoto Conference on New Aspects of Organic Chemistry(IKCOC 11)
    • Place of Presentation
      Kyoto, Rihga Royal Hotel Kyoto
    • Year and Date
      2009-11-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] Palladium-Catalyzed Decarboxylative Intramolecular Cyclization of α-Aryl-γ-methylidene-δ-valerolactones2009

    • Author(s)
      T.Tsuji
    • Organizer
      The 11th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC 11)
    • Place of Presentation
      Kyoto, Rihga Royal Hotel Kyoto
    • Year and Date
      2009-11-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] Iron-Catalyzed Pinacol Coupling of Ketones with a Phenyltitanium Reagent2009

    • Author(s)
      K.Sasaki
    • Organizer
      The 11th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC 11)
    • Place of Presentation
      Kyoto, Rihga Royal Hotel Kyoto
    • Year and Date
      2009-11-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] Iron(III)-Catalyzed Oxidative Coupling of Alkylamides with Arenes through Oxidation Followed by Electrophilic Aromatic Substitution2009

    • Author(s)
      N.Uchiyama
    • Organizer
      The 11th International Kyoto Conference on New Aspects of Organic Chemistry(IKCOC 11)
    • Place of Presentation
      Kyoto, Rihga Royal Hotel Kyoto
    • Year and Date
      2009-11-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] Rhodium-Catalyzed Asymmetric Conjugate Alkynylation of Enals2009

    • Author(s)
      T.Sawano
    • Organizer
      The 11th International Kyoto Conference on New Aspects of Organic Chemistry(IKCOC 11)
    • Place of Presentation
      Kyoto, Rihga Royal Hotel Kyoto
    • Year and Date
      2009-11-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] Ruthenium-Catalyzed Transformation of Alkenyl Triflates to Halides2009

    • Author(s)
      Y.Imazaki
    • Organizer
      The 11th International Kyoto Conference on New Aspects of Organic Chemistry(IKCOC 11)
    • Place of Presentation
      Kyoto, Rihga Royal Hotel Kyoto
    • Year and Date
      2009-11-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] Fe-Cu Cooperative Catalysis in the Reactions of Alkyl Grignard Reagents2009

    • Author(s)
      S.Masui
    • Organizer
      The 11th International Kyoto Conference on New Aspects of Organic Chemistry(IKCOC 11)
    • Place of Presentation
      Kyoto, Rihga Royal Hotel Kyoto
    • Year and Date
      2009-11-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] Coupling of Aryl Halides with Arenes in the Presence of a Catalytic Amount of a 1, 10-Phenanthroline Derivative2009

    • Author(s)
      K.Itoh
    • Organizer
      The 11th International Kyoto Conference on New Aspects of Organic Chemistry(IKCOC 11)
    • Place of Presentation
      Kyoto, Rihga Royal Hotel Kyoto
    • Year and Date
      2009-11-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] Recent Advances in Rhodium-Catalyted Asymmetric Addition Reactions2009

    • Author(s)
      T.Hayashi
    • Organizer
      Gratama Workshop 2009 Molecular Technology of the Future
    • Place of Presentation
      Delft, The Netherlands
    • Year and Date
      2009-09-15
    • Related Report
      2009 Annual Research Report
  • [Presentation] アルキニルエステル類とアルキルボロン酸を原料とするロジウム触媒を用いた五連続カルボロデーションを経るフェノール類の合成反応、2009

    • Author(s)
      安原祐一
    • Organizer
      第56回有機金属化学討論会
    • Place of Presentation
      同志社大学, 今出川キャンパス
    • Year and Date
      2009-09-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] 鉄-銅協同触媒によるGrignard反応剤の連続した反応2009

    • Author(s)
      白川英二
    • Organizer
      第56回有機金属化学討論会
    • Place of Presentation
      同志社大学, 今出川キャンパス
    • Year and Date
      2009-09-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] γ-メチリデン-δ-バレロラクトン : パラジウム触媒による環化付加反応における新規反応剤2009

    • Author(s)
      新谷亮
    • Organizer
      第56回有機金属化学討論会
    • Place of Presentation
      同志社大学, 今出川キャンパス
    • Year and Date
      2009-09-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] Recent Advances in the Chiral Diene Ligands for Asymmetric Catalysis2009

    • Author(s)
      林民生
    • Organizer
      16th European Symposium on Organic Chemistry (ESOC 2009)
    • Place of Presentation
      Prague, Czech Republic
    • Year and Date
      2009-07-16
    • Related Report
      2010 Final Research Report
  • [Presentation] Recent Advances in the Chiral Diene Ligands for Asymmetric Catalysis2009

    • Author(s)
      T.Hayashi
    • Organizer
      16th European Symposium on Organic Chemistry(ESOC 2009)
    • Place of Presentation
      Prague, Czech Republic
    • Year and Date
      2009-07-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] Recent Advances in Rhodium-Catalyzed Asymmetric Addition Reactions2009

    • Author(s)
      林民生
    • Organizer
      41st National Organic Chemistry Symposium 2009
    • Place of Presentation
      Boulder, Colorado, USA
    • Year and Date
      2009-06-09
    • Related Report
      2010 Final Research Report
  • [Presentation] Recent Advances in Rhodium-Catalyted Asymmetric Addition Reactions2009

    • Author(s)
      T.Hayashi
    • Organizer
      41st National Organic Chemistry Symposium 2009
    • Place of Presentation
      Boulder, Colorado, USA
    • Year and Date
      2009-06-09
    • Related Report
      2009 Annual Research Report
  • [Presentation] パラジウム触媒によるa-アリーα-アリールーy-メチリデン-δ-バレロラクトンの脱炭酸を伴う環化反応2009

    • Author(s)
      辻孝宙
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学, 船橋
    • Year and Date
      2009-03-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] パラジウム触媒によるy-メチリデン-8-バレロラクトンとイサチン類の脱炭酸を伴う[4+2]環化付加反応2009

    • Author(s)
      林慎也
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学, 船橋
    • Year and Date
      2009-03-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] パラジウム触媒によるy-メチリデン-δ-バレロラクトンとイソシアニドの脱炭酸を伴う[4+1]環化付加反応2009

    • Author(s)
      朴昭映
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学, 船橋
    • Year and Date
      2009-03-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] パラジウム触媒によるオレフィンの酸化的アルキニル化反応2009

    • Author(s)
      永長誠
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学, 船橋
    • Year and Date
      2009-03-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] パラジウム触媒によるγ-メチリデン-δ-バレロラクトンとイミンとの環化付加反応を利用したニペコチン酸誘導体の立体選択的合成2009

    • Author(s)
      村上正鷹
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学, 船橋
    • Year and Date
      2009-03-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] 鉄触媒を用いるアルキルアミドと芳香族化合物の酸化的カップリング反応2009

    • Author(s)
      内山七瀬
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学, 船橋
    • Year and Date
      2009-03-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] 鉄肖羽協同触媒を用いる第一級アルキルGrignard反応剤の調製とアルキンに対する付加反応2009

    • Author(s)
      池田大次
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学, 船橋
    • Year and Date
      2009-03-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] 鉄触媒を用いるハロゲン化アリールと芳香族化合物のカップリング反応2009

    • Author(s)
      東野智洋
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学, 船橋
    • Year and Date
      2009-03-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] ロジウム/キラルジェン触媒を用いたアキラルモノマーの不斉重合反応によるらせんポリアセチレンの合成2009

    • Author(s)
      市川善隆
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学, 船橋
    • Year and Date
      2009-03-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] π受容性キラルジェン/ロジウム触媒を用いる1, 6-エンインンインの不斉環化異性化反応2009

    • Author(s)
      川本教博
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学, 船橋
    • Year and Date
      2009-03-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] ロジウム触媒を用いたアルキン-ビニルシクロプロパンの分子内不斉[5+2]環化付加反応2009

    • Author(s)
      中津大貴
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学, 船橋
    • Year and Date
      2009-03-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] フェニル基のパラ位にのみ置換基をもつリン不斉C2対称dppe型配位子を用いる不斉共役付加反応2009

    • Author(s)
      成井倫太郎
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学, 船橋
    • Year and Date
      2009-03-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] テトラフルオロベンソバレレン骨格を有する新規光学活性ジェン-イリジウム錯体を用いた1, 3-ジェン類の2-ホルミルフェニルボロン試薬との不斉付加環化反応2009

    • Author(s)
      安原祐一
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学, 船橋
    • Year and Date
      2009-03-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] ルテニウム触媒を用いるアルケニルトリフラートのハロゲン化物への変換反応2009

    • Author(s)
      今崎雄介
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学, 船橋
    • Year and Date
      2009-03-27
    • Related Report
      2008 Annual Research Report
  • [Presentation] キラルなテトラフルオロベンソバレレン配位子の合成及びそのロジウム錯体触媒による有機ホウ素試薬の不斉付加反応2009

    • Author(s)
      熊本, はな
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学, 船橋
    • Year and Date
      2009-03-27
    • Related Report
      2008 Annual Research Report
  • [Presentation] ロジウム触媒を用いたa, β一不飽和アルデヒドに対するトリイソプロピルシリルアセチレンの不斉1, 4-付加反応2009

    • Author(s)
      澤野卓大
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学, 船橋
    • Year and Date
      2009-03-27
    • Related Report
      2008 Annual Research Report
  • [Presentation] キラルジェン配位子の新規合成法の開発とロジウム触媒による不斉付加反応への適用2009

    • Author(s)
      岡本和紘
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学, 船橋
    • Year and Date
      2009-03-27
    • Related Report
      2008 Annual Research Report
  • [Presentation] ロジウム触媒による立体選択的炭素一炭素結合開裂反応を利用した第三級ホモアリルアルコールの速度論的光学分割2009

    • Author(s)
      高津慶士
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学, 船橋
    • Year and Date
      2009-03-27
    • Related Report
      2008 Annual Research Report
  • [Presentation] 白金触媒によるβ-置換α, β-, β-不飽和ケトンに対するアリールボロン酸の1, 4-付加反応2009

    • Author(s)
      佐々木恵吾
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学, 船橋
    • Year and Date
      2009-03-27
    • Related Report
      2008 Annual Research Report
  • [Presentation] Palladium-Catalyzed Asymmetric Decarboxylative Coupling of γ-Methylidene-δ-valer-valerolactones with Isocyanates2008

    • Author(s)
      Soyoung Park
    • Organizer
      Japan-Korea Joint Symposium on Functional Materials toward Future Catalysts : Chemistry Showcase
    • Place of Presentation
      Daejeon, Korea
    • Year and Date
      2008-11-03
    • Related Report
      2008 Annual Research Report
  • [Presentation] 鉄-銅協同触媒を用いるアルキルGrignard反応剤の反応2008

    • Author(s)
      白川英二
    • Organizer
      第55回有機金属化学討論会
    • Place of Presentation
      大阪府立大学, 堺
    • Year and Date
      2008-09-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] ロジウム触媒を用いたシリルアセチレンによるエノンの不斉共役アルキニル化反応2008

    • Author(s)
      西村貴洋
    • Organizer
      第55回有機金属化学討論会
    • Place of Presentation
      大阪府立大学, 堺
    • Year and Date
      2008-09-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] パラジウム触媒を用いたy-メチリデン-トバレロラクトンと電子不足オレフィンの環化付加反応によるスピロ[2.4]ヘプタン類の合成2008

    • Author(s)
      朴昭映
    • Organizer
      第55回有機金属化学討論会
    • Place of Presentation
      大阪府立大学, 堺
    • Year and Date
      2008-09-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] Recent Advances in the Chirl Diene Ligands for Asymmetric Catalysis2008

    • Author(s)
      T. Hayashi
    • Organizer
      The 3rd International Forum on Homogeneous Catalysis and The First China-Spain Bilateral Symposium on Catalysis
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2008-09-24
    • Related Report
      2008 Annual Research Report
  • [Presentation] Recent Advances in the Rhodium-Catalyzed Asymmetric Carbon-Carbon Bond Formation2008

    • Author(s)
      林民生
    • Organizer
      57th Natural Products Gordon Research Conference
    • Place of Presentation
      Tilton, New Hampshire, USA
    • Year and Date
      2008-07-21
    • Related Report
      2010 Final Research Report
  • [Presentation] Recent Advances in the Rhodium-Catalyzed Asymmetric Carbon-Carbon Bond Formation2008

    • Author(s)
      T. Hayashi
    • Organizer
      57th Natural Products Gordon Research Conference
    • Place of Presentation
      Tilton, USA
    • Year and Date
      2008-07-21
    • Related Report
      2008 Annual Research Report
  • [Presentation] Synthesis of Spiro[2, 4]heptanes through Palladium-Catalyzed Cycloaddition of γ-Methylidene-δ-v-valerolactones with Electron-Deficient Olefins2008

    • Author(s)
      Soyoung Park
    • Organizer
      17th International Conference on Organic Synthesis (ICOS-17)
    • Place of Presentation
      Daejeon, Korea
    • Year and Date
      2008-06-25
    • Related Report
      2008 Annual Research Report
  • [Presentation] Recent Advances in the Chirl Diene Ligands for Asymmetric Catalysis2008

    • Author(s)
      T. Hayashi
    • Organizer
      5th Asian-European Symposium on Metal Mediated Efficient Organic Synthesis
    • Place of Presentation
      Obernai, France
    • Year and Date
      2008-05-26
    • Related Report
      2008 Annual Research Report
  • [Presentation] Recent Advances in the Rhodium-Catalyzed Asymmetric Carbon-Carbon Bond Formation2008

    • Author(s)
      林民生
    • Organizer
      Bristol Synthesis Meeting 2008
    • Place of Presentation
      Bristol, UK
    • Year and Date
      2008-04-15
    • Related Report
      2010 Final Research Report
  • [Presentation] Recent Advances in the Rhodium-Catalyzed-Asymmetric Carbon-Carbon Bond Formation2008

    • Author(s)
      T. Hayashi
    • Organizer
      Bristol Synthesis Meeting 2008
    • Place of Presentation
      Bristol, UK
    • Year and Date
      2008-04-15
    • Related Report
      2008 Annual Research Report
  • [Presentation] 新規ビシクロ[3.3.1]ノナ-2,6-ジエン配位子の開発とそれを用いたロジウム触媒による不斉1,4-付加反応2008

    • Author(s)
      市川 善隆
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学,東京
    • Year and Date
      2008-03-30
    • Related Report
      2007 Annual Research Report
  • [Presentation] 鉄触媒を用いるアルキンのカルボリチウム化反応2008

    • Author(s)
      小澤 翼
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学,東京
    • Year and Date
      2008-03-30
    • Related Report
      2007 Annual Research Report
  • [Presentation] 鉄-銅協同触媒を用いるアルキルGrignard反応剤のアルキンに対する付加反応2008

    • Author(s)
      池田 大次
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学,東京
    • Year and Date
      2008-03-30
    • Related Report
      2007 Annual Research Report
  • [Presentation] コバルト触媒を用いるGrignard反応剤とアルケニルトリフラートのクロス・カップリング反応2008

    • Author(s)
      今崎 雄介
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学,東京
    • Year and Date
      2008-03-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] ロジウム触媒を用いるアルキニルアルケニルカルビノール類の不斉転位反応2008

    • Author(s)
      西村 貴洋
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学,東京
    • Year and Date
      2008-03-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] ロジウム触媒を用いたアルキニルシラノールによる電子不足オレフィンの不斉アルキニル化反応2008

    • Author(s)
      徳地 澄人
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学,東京
    • Year and Date
      2008-03-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] イリジウム触媒を用いた1,3-ジエン類の2-ホルミルフェニルボロン酸との高選択的[3+2]付加環化反応2008

    • Author(s)
      安原 祐一
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学,東京
    • Year and Date
      2008-03-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] 新しい不斉環境-キラルジエン配位子2008

    • Author(s)
      林民生
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学,東京
    • Year and Date
      2008-03-28
    • Related Report
      2010 Final Research Report 2007 Annual Research Report
  • [Presentation] ロジウム触媒を用いたアリールビス(アルキニル)カルビノールの3-アルキニル-1-インダノンへの転位反応2008

    • Author(s)
      高津 慶士
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学,東京
    • Year and Date
      2008-03-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] ロジウム触媒を用いるホスフィニルアレンへのヘテロ原子求核剤の不斉付加反応2008

    • Author(s)
      川本 教博
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学,東京
    • Year and Date
      2008-03-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] テトラフルオロベンゾバレレン骨格を有するキラルジエン-ロジウム錯体触媒による有機ホウ素試薬の不斉付加反応2008

    • Author(s)
      永長 誠
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学,東京
    • Year and Date
      2008-03-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] ロジウム/キラルジエン触媒によるアリールメチレンシアノ酢酸エステルに対するアリールボロン酸の不斉1,4-付加反応2008

    • Author(s)
      佐々木 恵吾
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学,東京
    • Year and Date
      2008-03-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] パラジウム触媒によるγ-メチリデン-δ-バレロラクトンとニトロンの[4+3]環化付加反応2008

    • Author(s)
      村上 正鷹
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学,東京
    • Year and Date
      2008-03-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] パラジウム触媒を用いたγ-メチリデン-δ-バレロラクトンと電子不足オレフィンの環化付加反応によるスピロ[2.4]ヘプタン類の合成2008

    • Author(s)
      朴 昭映
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学,東京
    • Year and Date
      2008-03-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] パラジウム触媒によるγ-メチリデン-δ-バレロラクトンとイソシアネートの不斉[4+2]環化付加反応2008

    • Author(s)
      白水 文貴
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学,東京
    • Year and Date
      2008-03-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] 白金触媒によるβ位にメチル基を有するα,β-不飽和ケトンへのシリレンの付加反応.1-オキサ-2-シラシクロヘキサー5-エン類の生成2008

    • Author(s)
      岡本 和紘
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学,東京
    • Year and Date
      2008-03-26
    • Related Report
      2007 Annual Research Report
  • [Presentation] キラルジエン:触媒的不斉合成のための新しい配位子2008

    • Author(s)
      林 民生
    • Organizer
      有機合成化学協会2007年度高砂香料国際賞「野依賞」受賞記念講演会
    • Place of Presentation
      KKR HOTEL TOKYO,東京
    • Year and Date
      2008-02-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] Chiral Diene Ligands for Transition Metal-Catalyzed Asymmetric Reactions2008

    • Author(s)
      T. Hayashi
    • Organizer
      1st Japan-Singapore Bilateral Symposium on Catalysis
    • Place of Presentation
      Singapore,Singapore
    • Year and Date
      2008-01-07
    • Related Report
      2007 Annual Research Report
  • [Presentation] ロジウム触媒存在下第三級アルコールをアリール化剤として用いるα,β-不飽和カルボニル化合物のヒドロアリール化反応2007

    • Author(s)
      加藤 泰祐
    • Organizer
      第27回有機合成若手セミナー「明日の有機合成を担う人のために」
    • Place of Presentation
      京都大学,京都
    • Year and Date
      2007-11-15
    • Related Report
      2007 Annual Research Report
  • [Presentation] ロジウム触媒を用いるアレニルホスフィンオキシド類の不斉アルキニル化反応2007

    • Author(s)
      郭 勲祥
    • Organizer
      第27回有機合成若手セミナー「明日の有機合成を担う人のために」
    • Place of Presentation
      京都大学,京都
    • Year and Date
      2007-11-15
    • Related Report
      2007 Annual Research Report
  • [Presentation] Palladium-Catalyzed Asymmetric [3+3] Cycloaddition of Trimethylenemethanes with Nitrones2007

    • Author(s)
      Soyoung Park
    • Organizer
      2007 Workshop on Organometallic Chemistry
    • Place of Presentation
      Wako, Japan
    • Year and Date
      2007-11-08
    • Related Report
      2007 Annual Research Report
  • [Presentation] イリジウム触媒による1,3-ジエンへのアリールボロン酸の高選択的付加反応2007

    • Author(s)
      西村 貴洋
    • Organizer
      第54回有機金属化学討論会
    • Place of Presentation
      広島大学,広島
    • Year and Date
      2007-10-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] 白金触媒によるβ位にメチル基を有するα,β-不飽和ケトンへのシリレンの付加反応2007

    • Author(s)
      岡本 和紘
    • Organizer
      第54回有機金属化学討論会
    • Place of Presentation
      広島大学,広島
    • Year and Date
      2007-10-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] 鉄/銅協同触媒を用いるアルキルGringnard反応剤の異性化2007

    • Author(s)
      池田 大次
    • Organizer
      第54回有機金属化学討論会
    • Place of Presentation
      広島大学,広島
    • Year and Date
      2007-10-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] ロジウム触媒を用いたアセチレンおよびアレンへの末端アセチレンの付加による共役エンインの合成2007

    • Author(s)
      林 民生
    • Organizer
      2007学術創成研究評価のためのシンポジウム
    • Place of Presentation
      学士会館,東京
    • Year and Date
      2007-10-10
    • Related Report
      2007 Annual Research Report
  • [Presentation] Highly Selective Iridium-Catalyzed Addition of Arylboronic Acids to 1,3-Dienes2007

    • Author(s)
      T. Nishimura
    • Organizer
      4th Japanese-Sino Symposium on Organic Chemistry for Young Scientists
    • Place of Presentation
      Narita, Japan
    • Year and Date
      2007-09-23
    • Related Report
      2007 Annual Research Report
  • [Presentation] ロジウム触媒を用いるオキサーおよびアザビシクロアルケンの不斉「3+2」環化付加反応2007

    • Author(s)
      川本 教弘
    • Organizer
      第24回有機合成化学セミナー
    • Place of Presentation
      淡路夢舞台国際会議場,淡路
    • Year and Date
      2007-09-12
    • Related Report
      2007 Annual Research Report
  • [Presentation] 白金触媒によりジシランから発生させたシリレンのエノンに対する付加反応2007

    • Author(s)
      岡本 和紘
    • Organizer
      第24回有機合成化学セミナー
    • Place of Presentation
      淡路夢舞台国際会議場,淡路
    • Year and Date
      2007-09-12
    • Related Report
      2007 Annual Research Report
  • [Presentation] Addition of Terminal Alkynes to Internal Alkynes Catalyzed by Hydroxorhodium Complexes2007

    • Author(s)
      T. Nishimura
    • Organizer
      14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2007-08-05
    • Related Report
      2007 Annual Research Report
  • [Presentation] C_2-Symmetrical Dppe-Type P-Chiral Ligands Having Substituents Merely at Para-Positions2007

    • Author(s)
      Y. Kawata
    • Organizer
      14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2007-08-04
    • Related Report
      2007 Annual Research Report
  • [Presentation] Isomerization of Alkyl Grignard Reagents Catalyzed Cooperatively by Iron and Copper Complexes2007

    • Author(s)
      D. Ikeda
    • Organizer
      14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2007-08-04
    • Related Report
      2007 Annual Research Report
  • [Presentation] Rhodium-Catalyzed Asymmetric Synthesis of 3,3-Disubstituted 1-Indanones2007

    • Author(s)
      K. Takatsu
    • Organizer
      14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2007-08-04
    • Related Report
      2007 Annual Research Report
  • [Presentation] Platinum-Catalyzed Generation of Silylenes and Their Addition to Enones2007

    • Author(s)
      K. Okamoto
    • Organizer
      14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2007-08-04
    • Related Report
      2007 Annual Research Report
  • [Presentation] Rhodium-Catalyzed 1,4-Addition to α, β-Unsaturated Carbonyl Compounds with tert-Alcohols2007

    • Author(s)
      T. Katoh
    • Organizer
      14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2007-08-04
    • Related Report
      2007 Annual Research Report
  • [Presentation] Iridium-Catalyzed [3+2] Annulation of 1,3-Dienes with ortho-Carbonylated Phenylboronic Acids2007

    • Author(s)
      Y. Yasuhara
    • Organizer
      14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2007-08-03
    • Related Report
      2007 Annual Research Report
  • [Presentation] Rhodium-Catalyzed Asymmetric [3+2] Cycloaddition of Oxa- and Azabicyclic Alkenes2007

    • Author(s)
      T. Kawamoto
    • Organizer
      14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2007-08-03
    • Related Report
      2007 Annual Research Report
  • [Presentation] Arylmagnesiation of Alkynes Catalyzed Cooperatively by Iron and Copper Complexes2007

    • Author(s)
      E. Shirakawa
    • Organizer
      14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2007-08-03
    • Related Report
      2007 Annual Research Report
  • [Presentation] γ-Methylidene-δ-valerolactones as a Coupling Partner for Cycloaddition: Palladium-Catalyzed [4+3] Cycloaddition with Nitrones2007

    • Author(s)
      R. Shintani
    • Organizer
      14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2007-08-02
    • Related Report
      2007 Annual Research Report
  • [Presentation] Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to Alkyliden Cynoacetates: Asymmetric Synthesis of (R)-Tolterodine2007

    • Author(s)
      Sebastian Sorgel
    • Organizer
      14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2007-08-02
    • Related Report
      2007 Annual Research Report
  • [Presentation] Rhodium-Catalyzed Asymmetric Alkynylation of Allenic Phosphine Oxides with Terminal Alkynes2007

    • Author(s)
      Xun-xiang Guo
    • Organizer
      14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2007-08-02
    • Related Report
      2007 Annual Research Report
  • [Presentation] Palladium-Catalyzed Asymmetric [3+3] Cycloaddition of Trimethylenemethanes with Nitrones2007

    • Author(s)
      Soyoung Park
    • Organizer
      14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2007-08-02
    • Related Report
      2007 Annual Research Report
  • [Presentation] Catalytic Asymmetric Synthesis of Allylsilanes through 1,4-Addition of Alkenylsilicon Reagents to β-Silly α, β-Unsaturated Carbonyl Compounds under Rhodium/Chiral Diene catalysis2007

    • Author(s)
      Y. Ichikawa
    • Organizer
      14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2007-08-02
    • Related Report
      2007 Annual Research Report
  • [Presentation] 不飽和炭化水素のヒドロメタル化2007

    • Author(s)
      白川 英二
    • Organizer
      第34回有機金属化学セミナー
    • Place of Presentation
      キャンパスプラザ京都,京都
    • Year and Date
      2007-06-15
    • Related Report
      2007 Annual Research Report
  • [Presentation] 触媒的不斉合成のための新しい不斉環境Chiral Diene Ligands2007

    • Author(s)
      林 民生
    • Organizer
      平成19年度有機合成化学協会関西支部主催セミナー"化学千一夜"
    • Place of Presentation
      かんぽの宿大和平群,奈良
    • Year and Date
      2007-06-08
    • Related Report
      2007 Annual Research Report
  • [Presentation] Rhodium-Catalyzed Hydroarylation of α, β-Unsaturated Carbonyl Compounds with tert-Alcohols2007

    • Author(s)
      T. Katoh
    • Organizer
      International Conference on Asymmetric Organocatalysis
    • Place of Presentation
      Ohtsu, Japan
    • Year and Date
      2007-05-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] Rhodium-Catalyzed Asymmetric Cyclodimerization of Oxa- and Azabicyclic Alkenes2007

    • Author(s)
      T. Kawamoto
    • Organizer
      International Conference on Asymmetric Organocatalysis
    • Place of Presentation
      Ohtsu, Japan
    • Year and Date
      2007-05-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] Highly Selective 1,6-Addition of Arylboronic Acids to α, β, γ, δ-Unsaturated Carbonyl Compounds Catalyzed by an Iridium Complex2007

    • Author(s)
      Y. Yasuhara
    • Organizer
      International Conference on Asymmetric Organocatalysis
    • Place of Presentation
      Ohtsu, Japan
    • Year and Date
      2007-05-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] Chiral Diene Ligands for Catalytic Asymmetric Reactions2007

    • Author(s)
      林民生
    • Organizer
      The 24th Herbert C.Brown Lectures in Organic Chemistry
    • Place of Presentation
      Purdue Univ., Indiana, USA
    • Year and Date
      2007-04-21
    • Related Report
      2010 Final Research Report
  • [Presentation] Chiral Diene Ligands for Catalytic Asymmetric Reactions2007

    • Author(s)
      T. Hayashi
    • Organizer
      The 24th H.C. Brown Lectures in Organic Chemistry
    • Place of Presentation
      West Lafayette, USA
    • Year and Date
      2007-04-21
    • Related Report
      2007 Annual Research Report
  • [Presentation] Chiral Diene Ligands for Catalytic Asymmetric Reactions2007

    • Author(s)
      T. Hayashi
    • Organizer
      Conference Boehringer Ingelheim Lecture 2006-2007
    • Place of Presentation
      Montreal, Canada
    • Year and Date
      2007-04-18
    • Related Report
      2007 Annual Research Report
  • [Book] Science of Synthesis, Stereoselective Synthesis 1-Stereoselective Reactions of Carbon-Carbon Double Bonds (Asymmetric Hydrosilylation of Carbon-Carbon Double Bonds.)(de Vries, J.G., Ed.) Vol.2010/72011

    • Author(s)
      Han, J.W., Hayashi, T.
    • Publisher
      Thieme
    • Related Report
      2010 Final Research Report
  • [Book] Science of Synthesis, Stereoselective Synthesis 1 - Stereoselective Reactions of Carbon-Carbon Double Bonds ; de Vries, J.G.; Ed.2011

    • Author(s)
      Han, J.W.; Hayashi, T., 他32名
    • Total Pages
      1034
    • Publisher
      Thieme : Stuttgart
    • Related Report
      2010 Annual Research Report
  • [Book] Catalytic Asymmetric Conjugate Reractions (Rhodium-and Palladium-Catalyzed Asymmetric Conjugate Additions.)(Cordova, A., Ed.) Chap.12010

    • Author(s)
      Berthon, G., Hayashi, T.
    • Publisher
      Wiley-VCH
    • Related Report
      2010 Final Research Report
  • [Book] Catalytic Asymmetric Synthesis, 3rd Ed. (Asymmetric Hydrosilylation of Carbon-Carbon Double Bonds and Related Reactions.)(Ojima, I., Ed.) Chap.92010

    • Author(s)
      Han, J.W., Hayashi, T.
    • Publisher
      Wiley
    • Related Report
      2010 Final Research Report
  • [Book] Catalytic Asymmetric Conjugate Reactions ; Cordova, A.; Ed.2010

    • Author(s)
      Berthon, G.; Hayashi, T., 他15名
    • Total Pages
      447
    • Publisher
      Wiley-VCH : Weinheim
    • Related Report
      2010 Annual Research Report
  • [Book] Catalytic Asymmetric Synthesis, 3rd ed ; Ojima, I., Ed.2010

    • Author(s)
      Han, J.W. ; Hayashi, T., 他46名
    • Total Pages
      998
    • Publisher
      Wiley : Hoboken, NJ
    • Related Report
      2009 Annual Research Report
  • [Book] New Frontiers in Asymmetric Catalysis (Ligand Design for C-C Bond Formation.)(Mikami, K., Lautens, M., Eds.)2007

    • Author(s)
      Shintani, R., Hayashi, T.
    • Publisher
      Wiley-VCH
    • Related Report
      2010 Final Research Report
  • [Book] Comprehensive Organometallic Chemistry III (C-E Bond Formation through Asymmetric Hydrosilylation of Alkenes.)(Crabtree, R.H., Mingos, D.M.P., Eds.) Vol.102007

    • Author(s)
      Hayashi, T., Yamasaki, K.
    • Publisher
      Elsevier
    • Related Report
      2010 Final Research Report
  • [Remarks] ホームページ等

    • URL

      http://kuchem.kyoto-u.ac.jp/orgchem/Scientific_Research_S.htm

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://kuchem.kyoto-u.ac.jp/orgchem/Scientific_Research_S.htm

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://kuchem.kyoto-u.ac.jp/orgchem/Hayashi_Lab/Research.html

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://kuchem.kyoto-u.ac.jp/organization/lab/yuki.html

    • Related Report
      2008 Annual Research Report

URL: 

Published: 2007-04-01   Modified: 2016-04-21  

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