Budget Amount *help |
¥45,500,000 (Direct Cost: ¥35,000,000、Indirect Cost: ¥10,500,000)
Fiscal Year 2009: ¥15,340,000 (Direct Cost: ¥11,800,000、Indirect Cost: ¥3,540,000)
Fiscal Year 2008: ¥15,080,000 (Direct Cost: ¥11,600,000、Indirect Cost: ¥3,480,000)
Fiscal Year 2007: ¥15,080,000 (Direct Cost: ¥11,600,000、Indirect Cost: ¥3,480,000)
|
Research Abstract |
We have achieved strong 4nπ Mobius aromaticity by various methods for the conformational control of meso-aryl expanded porphyrins, such as metal coordination, temperature control, protonation, and intramoleculer fusion. We report the syntheses of a series of novel subporphyrins and related molecules by various chemical transformations of meso-aryl-subporphyrins. In addition, we have also developed a transition metal-catalyzed coupling reactions toward the construction of multi-porphyrin arrays.
|