Creation of Specific Reactions within Self-Assembled Cages
| Project/Area Number |
19205012
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | The University of Tokyo |
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Principal Investigator |
FUJITA Makoto The University of Tokyo, 大学院・工学系研究科, 教授 (90209065)
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| Project Period (FY) |
2007 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥47,710,000 (Direct Cost: ¥36,700,000、Indirect Cost: ¥11,010,000)
Fiscal Year 2009: ¥15,600,000 (Direct Cost: ¥12,000,000、Indirect Cost: ¥3,600,000)
Fiscal Year 2008: ¥16,640,000 (Direct Cost: ¥12,800,000、Indirect Cost: ¥3,840,000)
Fiscal Year 2007: ¥15,470,000 (Direct Cost: ¥11,900,000、Indirect Cost: ¥3,570,000)
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| Keywords | 自己組織化 / ナノ空間 / 反応制御 / パラジウム / 光反応 |
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| Research Abstract |
In this research, we developed novel and specific chemical reactions, employing self-assembled hollow complexes as molecular-sized flasks : (1) Self-assembled M_<24>L_<48> giant spherical complex, (2) Endohedral functionalization of spherical complexes towards unique, unprecedented confined space, (3) Cavity-directed chemical reactions within self-assembled cages, and (4) Direct observation of unstable and reactive intermediates in coordination networks.
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Report
(4 results)
Research Products
(94 results)
