Budget Amount *help |
¥47,710,000 (Direct Cost: ¥36,700,000、Indirect Cost: ¥11,010,000)
Fiscal Year 2009: ¥15,600,000 (Direct Cost: ¥12,000,000、Indirect Cost: ¥3,600,000)
Fiscal Year 2008: ¥16,640,000 (Direct Cost: ¥12,800,000、Indirect Cost: ¥3,840,000)
Fiscal Year 2007: ¥15,470,000 (Direct Cost: ¥11,900,000、Indirect Cost: ¥3,570,000)
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Research Abstract |
In this research, we developed novel and specific chemical reactions, employing self-assembled hollow complexes as molecular-sized flasks : (1) Self-assembled M_<24>L_<48> giant spherical complex, (2) Endohedral functionalization of spherical complexes towards unique, unprecedented confined space, (3) Cavity-directed chemical reactions within self-assembled cages, and (4) Direct observation of unstable and reactive intermediates in coordination networks.
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