Semiconductive properties of hetrocyclic thiazyl radicals and related materials
| Project/Area Number |
19205018
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Functional materials chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
AWAGA Kunio Nagoya University, 物質科学国際研究センター, 教授 (10202772)
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| Co-Investigator(Kenkyū-buntansha) |
ITO Hiroshi 名古屋大学, 大学院・工学研究科, 准教授 (10260374)
MATSUSHITA Michio 名古屋大学, 大学院・工学研究科, 准教授 (80295477)
YOSHIKAWA Hirofumi 名古屋大学, 大学院・工学研究科, 助授 (60397453)
藤田 渉 首都大学東京, 大学院・理工学研究科, 准教授 (50292719)
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| Project Period (FY) |
2007 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥49,140,000 (Direct Cost: ¥37,800,000、Indirect Cost: ¥11,340,000)
Fiscal Year 2009: ¥11,310,000 (Direct Cost: ¥8,700,000、Indirect Cost: ¥2,610,000)
Fiscal Year 2008: ¥20,280,000 (Direct Cost: ¥15,600,000、Indirect Cost: ¥4,680,000)
Fiscal Year 2007: ¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
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| Keywords | 有機ラジカル / 有機半導体 / 過渡光電流 / 光学セル / 有機エレクトロニクス / フタロシアンニン / 電気的磁気的性質 / 電気化学的酸化還元 / 薄膜 / エレクトロクロミズム / XRDパターン / XPS測定 / 環状チアジルラジカル / 半導体性 |
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| Research Abstract |
There is a growing interest in organic electronics. In the present project, we have elucidated the thin film fabrication techniques on various electrode materials for the heterocyclic thiazyl radicals and related materials, aiming at their applications in organic devices. We discovered various new phenomena such as electrochemical doing for organic robust thin films, non-linear transport due to partial melting of charge ordered states and EPR signal oscillation, organic photoconductivity based on the interactive radical dimer model, etc.
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Report
(4 results)
Research Products
(39 results)
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[Journal Article] Electronic structure of disjoint diradical 4, 4'-bis(1, 2, 3, 5-dithiadiazolyl) thin films2009
Author(s)
Kanai, Kaname; Yoshida, Hiroyuki; Noda, Yukiko; Iwasaki, Akito; Suizu, Rie; Tsutumi, Jun'ya; Imabayashi, Hiroki; Ouchi, Yukio; Sato, Naoki; Seki, Kazuhiko; Awaga, Kunio
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Journal Title
Physical Chemistry Chemical Physics 11(48)
Pages: 11432-11436
Related Report
Peer Reviewed
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[Journal Article] nteractive Radical Dimers in Photoconductive Organic Thin Films, Angewandte Chemie2009
Author(s)
Iwasaki, Akito; Hu, Laigui; Suizu, Rie; Nomura, Kenji; Yoshikawa, Hirofumi; Awaga, Kunio; Noda, Yukiko; Kanai, Kaname; Ouchi, Yukio; Seki, Kazuhiko; Ito, Hiroshi
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Journal Title
International Edition 48(22)
Pages: 4022-4024
Related Report
Peer Reviewed
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