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Concentrated solar heat conversion to solar hydrogen using speciallycation-excess ferrite

Research Project

Project/Area Number 19206106
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Energy engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

TAMAURA Yutaka  Tokyo Institute of Technology, 炭素循環エネルギー研究センター, 教授 (00108185)

Co-Investigator(Kenkyū-buntansha) ABE Masanori  東京工業大学, 大学院・理工学研究科, 教授 (70016624)
KITAMOTO Masataka  東京工業大学, 大学院・総合理工学研究科, 准教授 (10272676)
KANEKO Hiroshi  東京工業大学, 炭素循環エネルギー研究センター, 特任准教授 (90323774)
HASEGAWA Noriko  東京工業大学, 炭素循環エネルギー研究センター, 助教 (30361801)
Project Period (FY) 2007 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥50,050,000 (Direct Cost: ¥38,500,000、Indirect Cost: ¥11,550,000)
Fiscal Year 2008: ¥14,040,000 (Direct Cost: ¥10,800,000、Indirect Cost: ¥3,240,000)
Fiscal Year 2007: ¥36,010,000 (Direct Cost: ¥27,700,000、Indirect Cost: ¥8,310,000)
Keywordsエネルギー生成 / 変換 / カチオン特異過剰フェライト / 集光太陽熱 / 急速加熱 / Frenkel型格子欠陥 / 酸素放出反応 / ソーラー水素生産 / ロータリー式太陽反応炉 / 固体物理化学解析 / 集光ビーム / メスバウアー / Frencke1欠陥構造 / YSZ固溶体 / セリア系化合物 / ロータリー型太陽反応炉 / CSIRO計画
Research Abstract

集光太陽ビームをセラミックスに照射し1300-1600℃に急速加熱すると、特殊な反応中間体を経由し、空気酸素分圧下で酸素放出反応が進行することを世界で初めて明らかにし、この反応で生成したセラミックス還元体が水を分解(水素生成過程)することを見出した(特開2008-094636)。これを用いるソーラー水素生産の実用化に向け、ロータリー式太陽反応炉およびビームダウン式集光システムの開発を行った。

Report

(3 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • Research Products

    (45 results)

All 2008 2007 2006 Other

All Journal Article (20 results) (of which Peer Reviewed: 20 results) Presentation (16 results) Book (2 results) Remarks (4 results) Patent(Industrial Property Rights) (3 results) (of which Overseas: 1 results)

  • [Journal Article] Cerium ion redox system in CeO_2-xFe2O_3 solid solution at high temperatures (1273-1673K) in the two-step water splitting reaction for solar H_2 generation2008

    • Author(s)
      H. kaneko, 他3名, N. Hasegawa, Y. Tamaura
    • Journal Title

      J. Mater. Sci 43

      Pages: 3153-3161

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Two-step water splitting process with solid solution of YSZ and Ni-ferrite for solar hydrogen production2008

    • Author(s)
      H. Ishihara, H. Kaneko, N. Hasegawa, Y. Tamaura
    • Journal Title

      J. Solar Energy Eng 130

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Two-step water splitting process at 1273-1623K with YSZ-iron oxide solid solution via co-precipitation process and solid state reaction2008

    • Author(s)
      H. Ishihara, H. Kaneko, N. Hasegawa, Y. Tamaura
    • Journal Title

      Energy 33

      Pages: 1788-1793

    • Related Report
      2008 Annual Research Report 2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Cerium ion redox system in CeO_2-xFe_2O_3 solid solution at high temperatures(1273-1673K) in the two-step water splitting reaction for solar H_2 generation2008

    • Author(s)
      H. kaneko, N. Hasegawa, Y. Tamaura, et al.
    • Journal Title

      J. Mater. Sci. 43

      Pages: 3153-3161

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Two-step water splitting process with solid solution of YSZ and Ni-ferrite for solar hydrogen production2008

    • Author(s)
      H. Ishihara, H. Kaneko, N. Hasegawa, Y. Tamaura
    • Journal Title

      J. Solar Energy Eng. 130

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solar Hybrid Fuel Production with Co-production of Methanol and Metal Mg2008

    • Author(s)
      Y. Tamaura, H. Ishihara, K. Oouchi, H. Kaneko
    • Journal Title

      Proceedings of 14th International Symposium on Concentrating Solar Power and Chemical Energy Technologies (CD-ROM)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cerium ion redox system in CeO_2-xFe_2O_3 solid solution at high temperatures (1273-1673K)in the two-step water splitting reaction for solar H_2 generation2008

    • Author(s)
      H. kaneko, H. Ishihara, S. Taku, Y. Naganuma, N. Hasegawa, Y. Tamaura
    • Journal Title

      J. Mater. Sci. 43

      Pages: 3153-3161

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of Rotary-type Solar Reactor for Solar H_2 Production with Two-step Water Splitting Reaction2008

    • Author(s)
      H. Kaneko, H. Fukuzumi, H. Ishihara, S. Taku, Y. Naganuma, N. Hasegawa, Y. Tamaura
    • Journal Title

      Proceedings of 14th International Symposium on Concentrating Solar Power and Chemical Energy Technologies (CD-ROM)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Fe doping on photoluminescence of yttria-stabilized zirconia2007

    • Author(s)
      H. Nakajima, 他4名, H. Kaneko, Y. Tamaura
    • Journal Title

      J. Alloys Compd 411

      Pages: 255-258

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Rotary-type Solar Reactor for Solar Hydrogen Production with Two-step Water Splitting Process2007

    • Author(s)
      H. Kaneko, 他6名, Y. Tamaura
    • Journal Title

      Energy & Fuels 21

      Pages: 2287-2293

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ce-Zr 系酸化物を用いた二段階水分解反応によるソーラー水素生産( Two-step water splitting Reaction with Ce-Zr Oxide system for solar hydrogen production)2007

    • Author(s)
      S. Taku, H. Kaneko, Y. Tamaura
    • Journal Title

      Eco-Engineering 19(4)

      Pages: 255-262

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Fe doping on crystalline and optical properties of yttria-stabilized zirconia2007

    • Author(s)
      H. Nakajima, K. Itoh, H. Kaneko, Y. Tamaura
    • Journal Title

      J. Phys. Chem. Solids 68

      Pages: 1946-1950

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Fe doping on photoluminescence of yttria-stabilized zirconia2007

    • Author(s)
      H. Nakajima, H. Ishihara, Q. Shen, T. Toyoda, K. Itoh, H. Kaneko, Y. Tamaura
    • Journal Title

      J. Alloys Compd. 41

      Pages: 255-258

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ce-Zr系酸化物を用いた二段階水分解反応によるソーラー水素生産2007

    • Author(s)
      S. Taku, H. Kaneko, Y. Tamaura
    • Journal Title

      Eco-Engineering 19(4)

      Pages: 255-262

    • NAID

      10019786866

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Fe doping on crystalline and properties of yttria-stabilized zirconia2007

    • Author(s)
      H. Nakajima, K. Itoh, H. Kaneko, Y. Tamaura
    • Journal Title

      J. Phys. Chem. Solids 68

      Pages: 1946-1950

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of reactivity of NiFe2O4 in two-step water splitting reaction using binary phase system of CeO_2-NiFe_2O_4

    • Author(s)
      Y. Naganuma, H. Kaneko, N. Hasegawa, Y. Tamaura
    • Journal Title

      rans. Mater. Res. Soc. Japan (in press)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reactive ceramics of CeO_2-ZrO_2 for H_2-generation by two-step water splitting reaction using concentrated solar thermal energy

    • Author(s)
      S. Taku, H. Kaneko, N. Hasegawa, Y. Tamaura
    • Journal Title

      Trans. Mater. Res. Soc. Japan (in press)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electric conductivity and reactivity of the CeO_2-ZrO_2 solid solution at high temperature for O2-releasing step

    • Author(s)
      C. Lee , 他5名, H. Kaneko, N. Hasegawa, Y. Tamaura
    • Journal Title

      Trans. Mater. Res. Soc. Japan (in press)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reactivity and XAFS study on (1-x)CeO_2-xNiO (x = 0.025-0.3) system in the two-step water-splitting reaction for solar H_2 production

    • Author(s)
      H. Kaneko, Y. Tamaura
    • Journal Title

      J. Phys. Chem. Solids (in press)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Two-step water splitting process with solid solution of YSZ and Ni-ferrite for solar hydrogen production

    • Author(s)
      H. Ishihara, H. Kaneko, N. Hasegawa, Y. Tamaura
    • Journal Title

      J. Solar Energy Eng. (In press)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] Simultaneous Production of H_2 and O_2 with Rotary-type Solar Reactor (Tokyo Tech Model) for Solar Hybrid Fuel2008

    • Author(s)
      Y. Tamaura, H. Kaneko, 他3名, N. Hasegawa
    • Organizer
      Proceedings of ES2008, 2nd International Conference on Energy Sustainability
    • Place of Presentation
      Jackonsville, Florida
    • Related Report
      2008 Final Research Report
  • [Presentation] Simultaneous Production of H_2 and O_2 with Rotary-type Solar Reactor (Tokyo Tech Model)for Solar Hybrid Fuel2008

    • Author(s)
      Y. Tamaura, H. Kaneko, N. Hasegawa, et al.
    • Organizer
      2nd International Conference on Energy Sustainability
    • Place of Presentation
      Jackonsville, Florida
    • Related Report
      2008 Annual Research Report
  • [Presentation] 東工大式ビームダウン集光太陽熱発電のアブダビプロジェクト2008

    • Author(s)
      玉浦裕, 金子宏, 石原英之, 湯浅実
    • Organizer
      第24回エネルギーシステム・経済・環境コンファレンス
    • Place of Presentation
      虎ノ門パストラル,東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] 酸素ガスを用いたMgO-Coalシステムによるソーラーハイブリッド燃料生産2008

    • Author(s)
      石原英之, 大内圭, 金子宏, 岡本崇史, 玉浦裕
    • Organizer
      第24回エネルギーシステム・経済・環境コンファレンス
    • Place of Presentation
      虎ノ門パストラル,東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] 格子欠陥反応中間体を利用するニッケルフェライト二段階水分解反応2008

    • Author(s)
      金子宏, 長沼祐樹, 石原英之, 福角浩昭, 多久俊平, 大内圭, 長谷川紀子, 玉浦裕
    • Organizer
      第24回エネルギーシステム・経済・環境コンファレンス
    • Place of Presentation
      虎ノ門パストラル,東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] The Reactive Ceramics for Solar H_2 Production by Rotary Type Solar Reactor with Two Step Water Splitting2007

    • Author(s)
      Y. Tamaura, H. Kaneko, H. Ishihara, S. Taku, Y. Naganuma, H. Fukuzumi
    • Organizer
      16th International Symposium on the Reactivity of Solids
    • Place of Presentation
      University of Minnesota, Minneapolis
    • Related Report
      2007 Annual Research Report
  • [Presentation] CeO_2-NiO固溶体を用いた二段階水分解ソーラー水素生成反応2007

    • Author(s)
      金子宏, 石原英之, 多久俊平, 長沼祐樹, 福角浩昭, 大内圭, 長谷川紀子, 玉浦裕
    • Organizer
      第27回水素エネルギー協会大会
    • Place of Presentation
      タワーホール船堀,東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] 二号機ロータリー式太陽反応炉(東工大提案)を用いたソーラー酸素・水素同時生産2007

    • Author(s)
      福角浩昭, 金子宏, 石原英之, 多久俊平, 長沼祐樹, 大内圭, 玉浦裕
    • Organizer
      第27回水素エネルギー協会大会
    • Place of Presentation
      タワーホール船堀,東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] Solar Hybrid Fuel Production Using MgO-Coal System with Oxygen Gas2007

    • Author(s)
      H. Ishihara, K. Ouchi, H. Kaneko, T. Okamoto, Y. Tamaura
    • Organizer
      International Symposium on Innovative Materials for Processes in Energy Systems
    • Place of Presentation
      Kyoto Research Park, Kyoto
    • Related Report
      2007 Annual Research Report
  • [Presentation] Ce-Zr系酸化物を用いた二段階水分解ソーラー水素生産2007

    • Author(s)
      多久俊平, 石原英之, 福角浩昭, 金子宏, 長谷川紀子, 玉浦裕
    • Organizer
      2007生態工学会年次大会
    • Place of Presentation
      岐阜大学,岐阜
    • Related Report
      2007 Annual Research Report
  • [Presentation] ロータリー式太陽反応炉(東工大提案)の二号機開発2007

    • Author(s)
      石原英之, 福角浩昭, 長沼祐樹, 多久俊平, 長谷川紀子, 金子宏, 玉浦裕
    • Organizer
      2007生態工学会年次大会
    • Place of Presentation
      岐阜大学,岐阜
    • Related Report
      2007 Annual Research Report
  • [Presentation] ニッケルフェライト系二段階水分解反応のロータリー式太陽反応炉への適用2007

    • Author(s)
      金子宏, 長沼祐樹, 石原英之, 多久俊平, 長谷川紀子, 玉浦裕
    • Organizer
      2007生態工学会年次大会
    • Place of Presentation
      岐阜大学,岐阜
    • Related Report
      2007 Annual Research Report
  • [Presentation] 東工大式ビームダウン集光太陽熱発電のアブダビプロジェクト2007

    • Author(s)
      玉浦裕, 宇多村元昭, 金子宏, 石原英之, 長谷川紀子
    • Organizer
      平成19年度日本太陽エネルギー学会・日本風力エネルギー協会合同研究発表会
    • Place of Presentation
      札幌コンベンションセンター,札幌
    • Related Report
      2007 Annual Research Report
  • [Presentation] ロータリー式太陽反応炉二号機(東工大提案)を用いた二段階水分解による水素生産2007

    • Author(s)
      石原英之, 福角浩昭, 長沼祐樹, 多久俊平, 金子宏, 玉浦裕
    • Organizer
      平成19年度日本太陽エネルギー学会・日本風力エネルギー協会合同研究発表会
    • Place of Presentation
      札幌コンベンションセンター,札幌
    • Related Report
      2007 Annual Research Report
  • [Presentation] CeO_2-ZrO_2系反応性セラミックスを用いた二段階水分解反応によるソーラー水素生産2007

    • Author(s)
      多久俊平, 長沼祐樹, 大内圭, 金子宏, 玉浦裕
    • Organizer
      平成19年度日本太陽エネルギー学会・日本風力エネルギー協会合同研究発表会
    • Place of Presentation
      札幌コンベンションセンター,札幌
    • Related Report
      2007 Annual Research Report
  • [Presentation] ニッケルフェライトの格子欠陥型反応中間体を用いた二段階水分解反応2007

    • Author(s)
      長沼祐樹, 金子宏, 石原英之, 多久俊平, 福角浩昭, 大内圭, 玉浦裕
    • Organizer
      平成19年度日本太陽エネルギー学会・日本風力エネルギー協会合同研究発表会
    • Place of Presentation
      札幌コンベンションセンター,札幌
    • Related Report
      2007 Annual Research Report
  • [Book] 太陽エネルギー有効利用最前線(664頁), ISBN978-4-86043-154-92008

    • Author(s)
      玉浦裕, 他(全62名)
    • Publisher
      株式会社エヌ・ティー・エス
    • Related Report
      2008 Annual Research Report
  • [Book] 太陽エネルギー有効利用最前線(664頁), 総論太陽エネルギー利用の可能性と技術課題, 第2編ソーラー水素生産, 第3編太陽熱発電技術, 第5編太陽エネルギー利用の動向と普及のための取り組2006

    • Author(s)
      玉浦裕, 他61名
    • Total Pages
      664
    • Publisher
      株式会社エヌ・ティー・エス,
    • Related Report
      2008 Final Research Report
  • [Remarks] 玉浦裕, 焦点探訪 UAEで太陽熱発電実証プラント 鏡で反射、場所の制約なし, 平成20 年9 月25 日, 日経産業新聞

    • Related Report
      2008 Final Research Report
  • [Remarks] 玉浦裕, 太陽熱発電UAE に設置 平成20年1 月18 日(夕), 朝日新聞

    • Related Report
      2008 Final Research Report
  • [Remarks] 玉浦裕, 地球異変「石油後」探る中東環境意識し投資の半面エネルギー消費は激増, 平成20年11月25日, 朝日新聞

    • Related Report
      2008 Final Research Report
  • [Remarks]

    • URL

      http://www.chemistry.titech.ac.jp/~tamaura/tamaura/content.html

    • Related Report
      2008 Annual Research Report
  • [Patent(Industrial Property Rights)] 反応性セラミックスおよびその製造方法、ならびに水素製造方法および水素製造装置2008

    • Inventor(s)
      多久俊平, 玉浦裕
    • Industrial Property Number
      2008-114899
    • Filing Date
      2008-07-01
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Patent(Industrial Property Rights)] 水素製造方法、水素製造装置および金属酸化物2008

    • Inventor(s)
      玉浦裕, 金子宏
    • Patent Publication Number
      2008-094636
    • Acquisition Date
      2008-04-24
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Patent(Industrial Property Rights)] 合成ガス・マグネシウムコプロダクションプロセスMagnesium Metal Production by Carbothermic Process Using Oxygen Gas2007

    • Inventor(s)
      玉浦裕, 岡本崇史, 金子宏, 石原英之
    • Industrial Property Rights Holder
      東京工業大学
    • Filing Date
      2007-09-18
    • Related Report
      2007 Annual Research Report
    • Overseas

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Published: 2007-04-01   Modified: 2016-04-21  

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