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Electrolysis in solid particles disperse water systems directed toward environmental stress O processes

Research Project

Project/Area Number 19310053
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental technology/Environmental materials
Research InstitutionOkayama University

Principal Investigator

TANAKA Hideo  Okayama University, 大学院・自然科学研究科, 教授 (60032950)

Co-Investigator(Kenkyū-buntansha) KUROHOSHI Manabu  岡山大学, 大学院・自然科学研究科, 准教授 (30242316)
MITSUDO Koichi  岡山大学, 大学院・自然科学研究科, 助教 (40379714)
Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥16,510,000 (Direct Cost: ¥12,700,000、Indirect Cost: ¥3,810,000)
Fiscal Year 2009: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2008: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2007: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Keywords環境負荷低減技術 / 環境負荷O合成プロセス / 固体粒子分散-水系電解 / 水系電解 / シリカゲル / ポリマー粒子 / ナノエマルジョン / 電解酸化 / 固体粒子 / 分散系 / 活性炭 / アルコール / アリールハライド / 電解還元 / 有機電解合成 / 水系反応場 / 固体粒子分散-水系 / X-オキシル / アルコールの酸化 / アリールハライドの還元二量化 / 環境負荷0合成プロセス / 環境負荷0有機電解合成プロセス / 水系メディエーター / クローズド合成システム / 電解ワッカー反応 / ハロゲン化アリールの電解還元
Research Abstract

Electrosyntheses in disperse systems with aqueous solutions of mediator (I) as disperse media and substrates and mediator (II)-adsorbed and/or-immobilized solid particles (silica gel, polymer particles, and active carbon) as disperse phases have been intensively investigated, thereby, offering totally closed electrolysis systems without consumption of any chemicals.

Report

(4 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (57 results)

All 2010 2009 2008 2007 Other

All Journal Article (20 results) (of which Peer Reviewed: 20 results) Presentation (35 results) Remarks (2 results)

  • [Journal Article] Design of Redox-Mediatory Systems for Electro-Organic Synthesis2009

    • Author(s)
      H. Tanaka, M. Kuroboshi, K. Mitsudo
    • Journal Title

      Electrochemistry Vol.77

      Pages: 1002-1009

    • NAID

      10025445931

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] 電極での電子移動を駆動力とするクリーンな水中酸化法の開発と応用2009

    • Author(s)
      田中秀雄、黒星学
    • Journal Title

      科学と工業 Vol.83、No.5

      Pages: 206-214

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrooxidation of Alcohols in N-Oxyl-Immobilized Silica Gel/Water Disperse System: Approach to Totally Closed System2009

    • Author(s)
      M. Kuroboshi, K. Goto, H. Tanaka
    • Journal Title

      SYNTHESIS No.6

      Pages: 903-908

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Generation of Cationic Pd Catalysts and Application to Pd/TEMPO Double-Mediatory Electrooxidative Wacker-Type Reaction2009

    • Author(s)
      K. Mitsudo, T. Kaide, E. Nakamoto, K. Yoshida, H. Tanaka
    • Journal Title

      Journal of the American Chemical Society Vol.77

      Pages: 1002-1009

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Design of redox-mediatory systems for electro-organic synthesis2009

    • Author(s)
      Tanaka, Hideo
    • Journal Title

      Electrochemistry(Tokyo, Japan) 77

      Pages: 1002-1009

    • NAID

      10025445931

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pd/TEMPO-catalyzed electrooxidative synthesis of biaryls from arylboronic acids or arylboronic esters2009

    • Author(s)
      Mitsudo, Koichi
    • Journal Title

      Tetrahedron 65

      Pages: 8384-8388

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electroorganic synthesis in oil-in-water(O/W)nanoemulsion : TEMPO-mediated electrooxidation of amphiphilic alcohols in water2009

    • Author(s)
      Kuroboshi, Manabu
    • Journal Title

      Tetrahedron 65

      Pages: 7177-7185

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of aqueous media for electroorganic synthesis2009

    • Author(s)
      Tanaka, Hideo
    • Journal Title

      Kagaku to Kogyo(Osaka, Japan) 83

      Pages: 206-214

    • NAID

      40016664666

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrooxidation of alcohols in N-oxyl-immobilized silica gel/water disperse system : approach to totally closed system2009

    • Author(s)
      Kuroboshi, Manabu
    • Journal Title

      Synthesis

      Pages: 903-908

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electroreductive Generation of Recyclable Organic Reductant from N, N-Dioctyl-4, 4'-bipyridinium and Pd-Catalyzed Reductive Coupling of Aryl2009

    • Author(s)
      Manabu KUROBOSHI
    • Journal Title

      Synlett

      Pages: 85-88

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrooxidation of Alcohols in N-Oxyl-Immobilized Silica Gel/Water Disperse System : Approach to Totally Closed System2009

    • Author(s)
      Manabu KUROBOSHI
    • Journal Title

      Synthesis (in press)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrooxidative Desulfurization/Chlorination. A Facile Synthesis of 4-Chloro-2-azetidinones, a Potent Intermediate for Carbapenems2008

    • Author(s)
      Manabu KUROBOSHI
    • Journal Title

      Heterocycles 76

      Pages: 1471-1484

    • NAID

      40016323243

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Recyclable Electron Transfer System : Electroreduction of Viologen in Ionic Liquids and Pd-catalyzed Reductive Coupling of Aryl Halides2008

    • Author(s)
      Manabu KUROBOSHI
    • Journal Title

      Electrochemistry 76

      Pages: 862-864

    • NAID

      130002150774

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pd/TEMPO Double-mediatory Electrooxidative Wacker-type Cyclizations2008

    • Author(s)
      Koichi Mitsudo
    • Journal Title

      Electrochemistry 76

      Pages: 859-861

    • NAID

      130002150773

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrooxidative homo-coupling of arylboronic acids catalyzed by electrogenerated cationic palladium catalysts2008

    • Author(s)
      Koichi Mitsudo
    • Journal Title

      Tetrahedron Letters 49

      Pages: 7287-7289

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anionic WS-TEMPO-mediatory electrooxidation of alcohols in water: halide-free oxidation directed towards a totally closed system2007

    • Author(s)
      K. Mitsudo, H. Kumagai, F. Takabatake, J. Kubota, H. Tanaka
    • Journal Title

      Tetrahedron Letter Vol.48

      Pages: 8994-8997

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electroorganic Synthesis in Oil-in-Water Nanoemulsion: TEMPO-Mediated Electrooxidation of Amphiphilic Alcohols in Water2007

    • Author(s)
      T. Yoshida, M. Kuroboshi, J. Oshitani, K. Goto, H. Tanaka
    • Journal Title

      SYNLETT No.17

      Pages: 2691-2694

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Generation of Cationic Pd Catalysts and Application to Pd/TEMPO Double-Mediatory Electrooxidative Wacker-Type Reactions2007

    • Author(s)
      K. Mitsudo, T.Kaide, E. Nakamoto, K. Yoshida, and H. Tanaka
    • Journal Title

      Journal of the American Chemical Society 129

      Pages: 2246-2247

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electroorganic Synthesis in Oil-in-Water Nanoemulsion: TEMPO-Mediated Electrooxidation of Amphiphilic Alcohols in Water2007

    • Author(s)
      T. Yoshida, M. Kuroboshi, J. Oshitani, K. Gotoh, and H. Tanaka
    • Journal Title

      SYNLETT

      Pages: 2691-2694

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anodic WS-TEMPO-mediatory electrooxidation of alcohols in water: halide-free oxidation directed towards a totally closed system2007

    • Author(s)
      K. Mitsudo, H. Kumagai, F. Takabatake, J. Kubota, H. Tanaka
    • Journal Title

      Tetrahedron Letters 48

      Pages: 8994-8997

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] Amphiphilic Viologen in Water: Electro-generation of Organic Reductants in Water and Application to Reductive Coupling of Ar-X2010

    • Author(s)
      T. Yamamoto, M. Kuroboshi, H. Tanaka
    • Organizer
      217th ECS Meeting
    • Place of Presentation
      Vancouver, Canada
    • Year and Date
      2010-04-26
    • Related Report
      2009 Final Research Report
  • [Presentation] 金属担持-活性炭電極を用いるハロゲン化アリールの電解還元2010

    • Author(s)
      國井雄太
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学理工学部(大阪府)
    • Related Report
      2009 Annual Research Report
  • [Presentation] Ni-Catalyzed Electroreductive Dehalogenation of Aryl Halides on an Activated Carbon Adsorbing Layer2009

    • Author(s)
      M. Kuroboshi, N. Hara, H. Tanaka
    • Organizer
      216th ECS Meeting
    • Place of Presentation
      Vienna, Austria
    • Related Report
      2009 Final Research Report
  • [Presentation] Pd/TEMPO複合メディエータ系を用いたアリールボロン酸及びアリールボロン酸エステルの電解ホモカップリング反応2009

    • Author(s)
      家現大輔、白神卓也、光藤耕一、田中秀雄
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学、船橋
    • Related Report
      2009 Final Research Report
  • [Presentation] ビオロゲン誘導体の水中での電解還元による有機還元剤の調製と反応2009

    • Author(s)
      黒星学、山本貴嗣、青木孝之、田中秀雄
    • Organizer
      電気化学会第76回大会
    • Place of Presentation
      京都大学
    • Related Report
      2009 Final Research Report
  • [Presentation] Ni-Catalyzed Electroreductive Dehalogenation of Aryl Halides on an Activated Carbon Adsorbing Layer Using a Stacked-Type Cell2009

    • Author(s)
      M.Kuroboshi
    • Organizer
      216th ECS Meeting
    • Place of Presentation
      Vienna, Austria
    • Related Report
      2009 Annual Research Report
  • [Presentation] ビオロゲンの電解還元による有機還元剤の発生と反応。アリール/アリールカップリングヘの展開2009

    • Author(s)
      竹谷 健太郎
    • Organizer
      日本化学会第89春季年会(1F4-51)
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Related Report
      2008 Annual Research Report
  • [Presentation] 電解塩素化を活用する4-クロロー2-アゼチジノンの合成2009

    • Author(s)
      立山 翔一
    • Organizer
      日本化学会第89春季年会(3G4-11)
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Related Report
      2008 Annual Research Report
  • [Presentation] 活性炭に吸着した芳香族ハロゲン化物の電解還元脱ハロゲン化2009

    • Author(s)
      原 直彰
    • Organizer
      日本化学会第89春季年会(1F4-46)
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Related Report
      2008 Annual Research Report
  • [Presentation] 電解還元系におけるフルオレン誘導体を用いる一電子還元分子内環化反応2009

    • Author(s)
      中川 裕美子
    • Organizer
      日本化学会第89春季年会(1F4-34)
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Related Report
      2008 Annual Research Report
  • [Presentation] Pd/TEMPO複合メディーエータ系を用いたアリールボロン酸及びアリールボロン酸エステルの電解ホモカップリング反応2009

    • Author(s)
      家現 大輔
    • Organizer
      日本化学会第89春季年会(2F4-15)
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Related Report
      2008 Annual Research Report
  • [Presentation] ビオロゲン誘導体の水中での電解還元による有機還元剤の調製と反応2009

    • Author(s)
      山本 貴嗣
    • Organizer
      電気化学会第76回大会
    • Place of Presentation
      京都大学吉田キャンパス
    • Related Report
      2008 Annual Research Report
  • [Presentation] 4-置換ピリジニウム塩の電気化学的挙動と有機還元剤への応用2009

    • Author(s)
      鈴木 亮祐
    • Organizer
      電気化学会第76回大会
    • Place of Presentation
      京都大学吉田キャンパス
    • Related Report
      2008 Annual Research Report
  • [Presentation] 4-チオアゼチジノン誘導体の電解酸化-脱硫塩素化反応2009

    • Author(s)
      米田 昌弘
    • Organizer
      電気化学会第76回大会
    • Place of Presentation
      京都大学吉田キャンパス
    • Related Report
      2008 Annual Research Report
  • [Presentation] Pd/TEMPO複合メディエータ系を用いたアリールボロン酸及びアリールボロン酸エステルの電解ホモカツブリング反応2009

    • Author(s)
      白神 卓也
    • Organizer
      電気化学会第76回大会
    • Place of Presentation
      京都大学吉田キャンパス
    • Related Report
      2008 Annual Research Report
  • [Presentation] 不均一系Pd触媒を用いた電解Wacker型酸化反応2009

    • Author(s)
      福永 悟史
    • Organizer
      電気化学会第76回大会
    • Place of Presentation
      京都大学吉田キャンパス
    • Related Report
      2008 Annual Research Report
  • [Presentation] 活性炭吸着相を反応場とする電解還元脱ハロゲン化 (2MO4)2008

    • Author(s)
      ・田中秀雄・原 直彰・出井宏明・黒星 学
    • Organizer
      電気化学会代75回大会(2008)
    • Place of Presentation
      山梨大学
    • Year and Date
      2008-03-31
    • Related Report
      2007 Annual Research Report
  • [Presentation] O/W ナノエマルション系における両親媒性アルコールの電解酸化(4J4-05)2008

    • Author(s)
      吉田 友則・黒星 学・田中 秀雄
    • Organizer
      日本化学会第88春季年会(2008)
    • Place of Presentation
      立教大学
    • Year and Date
      2008-03-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] Pd/TEMPO複合メディエータ系を用いる電解Wacker型環化反応(4J4-43)2008

    • Author(s)
      石井 徹・光藤 耕一・田中 秀雄
    • Organizer
      日本化学会第88春季年会(2008)
    • Place of Presentation
      立教大学
    • Year and Date
      2008-03-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] 活性炭吸着相を反応場とする芳香族ハロゲン化物の電解還元脱ハロゲン化-積層型セルの開発(4J4-40)2008

    • Author(s)
      出井 宏明・原 直彰・黒星 学・田中 秀雄
    • Organizer
      日本化学会第88春季年会(2008)
    • Place of Presentation
      立教大学
    • Year and Date
      2008-03-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] 還元型ビオロゲンを電子プールとする芳香族ハロゲン化物の水中二量化反応(3J4-41)2008

    • Author(s)
      ・青木 隆之・山本 貴嗣・黒星 学・田中 秀雄
    • Organizer
      日本化学会第88春季年会(2008)
    • Place of Presentation
      立教大学
    • Year and Date
      2008-03-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] Pd/Viologen-Promoted Reductive Coupling of Aryl Halides in Aqueous Solution2008

    • Author(s)
      Manabu KUROBOSHI
    • Organizer
      213th ECS Meeting (535)
    • Place of Presentation
      Phoenix, AZ, USA
    • Related Report
      2008 Annual Research Report
  • [Presentation] Electroreductive Dehalogenation/Dimerization of Aryl Halides on an Activated Carbon Adsorbing Layer Using a Stacked-Type Cell2008

    • Author(s)
      Manabu KUROBOSHI
    • Organizer
      213th ECS Meeting (562)
    • Place of Presentation
      Phoenix, AZ, USA
    • Related Report
      2008 Annual Research Report
  • [Presentation] Pd/TEMPO Double-Mediatory Electrooxidative Wacker-Type Cyclization2008

    • Author(s)
      Hideo Tanaka
    • Organizer
      213th ECS Meeting (511)
    • Place of Presentation
      Phoenix, AZ, USA
    • Related Report
      2008 Annual Research Report
  • [Presentation] 水中で機能する有機還元剤の調製と芳香族ハロゲン化物の還元的カップリング反応2008

    • Author(s)
      山本貴嗣
    • Organizer
      第3 2回有機電子移動化学討論会一エレクトロオーガニックケミストリー討論会 (P12)
    • Place of Presentation
      近畿大学本部キャンパス
    • Related Report
      2008 Annual Research Report
  • [Presentation] 電解活性化されたPd触媒を用いた分子間および分子内Wacker型反応2008

    • Author(s)
      光藤耕一
    • Organizer
      第3 2回有機電子移動化学討論会-エレクトロオーガニックケミストリー討論会 (08)
    • Place of Presentation
      近畿大学本部キャンパス
    • Related Report
      2008 Annual Research Report
  • [Presentation] Pd/TEMPO複合メディエータ系を用いたアリールボロン酸のホモカツプリング反応2008

    • Author(s)
      白神卓也
    • Organizer
      第3 2回有機電子移動化学討論会一エレクトロオーガニックケミストリー討論会 (08)
    • Place of Presentation
      近畿大学本部キャンパス
    • Related Report
      2008 Annual Research Report
  • [Presentation] Electrochemical Generation of Cationic Pd Catalysts and Application to Electrooxidative Wacker-tvpe Reactions2008

    • Author(s)
      Hideo Tanaka
    • Organizer
      The 23rd International Conference on Organometallic Chemistry(IC12)
    • Place of Presentation
      University of Rennes1, Rennes, France
    • Related Report
      2008 Annual Research Report
  • [Presentation] 電解活性パラジウム触媒を用いたアリールボロン酸の電解二量化反応2008

    • Author(s)
      白神卓也
    • Organizer
      第55回有機金属化学討論会(P2A-21)
    • Place of Presentation
      大阪府立大学中百舌鳥キャンパス
    • Related Report
      2008 Annual Research Report
  • [Presentation] Recyclable Electron Transfer System : Viologen/Pd-Promoted Reductive Coupling of Arvl Halides in Ionic Liquid2008

    • Author(s)
      Manabu KUROBOSHI
    • Organizer
      214th ECS Meeting (1512)
    • Place of Presentation
      Honolulu, HI, USA
    • Related Report
      2008 Annual Research Report
  • [Presentation] Electrooxidative Homo-coupling of Arylboronic Acids Catalyzed byelectrogenerated Cat ionic Palladium Catalysts2008

    • Author(s)
      Hideo Tanaka
    • Organizer
      214th ECS Meeting (1520)
    • Place of Presentation
      Honolulu, HI, USA
    • Related Report
      2008 Annual Research Report
  • [Presentation] Electrooxidative homo-coupling of arylboronic acids catalyzed byelectrogenerated cationic palladium catalysts2008

    • Author(s)
      Koichi Mitsudo
    • Organizer
      The 9th International Symposium on Organic Reactions
    • Place of Presentation
      Chiayi, Taiwan
    • Related Report
      2008 Annual Research Report
  • [Presentation] Electrochemical Generation of Cationic Pd Catalysts and Application to Pd/TEMPO Double-Mediatory Electrooxidative Wacker-type Reactions2008

    • Author(s)
      Hideo Tanaka
    • Organizer
      The 9th International Symposium on Organic Reactions
    • Place of Presentation
      Chiayi, Taiwan
    • Related Report
      2008 Annual Research Report
  • [Presentation] Electrochemical Generation of Cationic Pd Catalysts and Application to Pd/T2007

    • Author(s)
      K. Mitsudo, H. Tanaka, T. Kaide
    • Organizer
      211th ECS Meeting, Chicago, Illinois, USA
    • Place of Presentation
      Chicago, Illinois,USA
    • Year and Date
      2007-05-17
    • Related Report
      2007 Annual Research Report
  • [Presentation] TEMPO-Mediated Electrooxidation of Amphiphilic Alcohols in Nano-particle Disperse Water Systems2007

    • Author(s)
      T. Yoshida, M. Kuroboshi, and H. Tanaka
    • Organizer
      211th ECS Meeting, Chicago, Illinois, USA
    • Place of Presentation
      Chicago, Illinois,USA
    • Year and Date
      2007-05-17
    • Related Report
      2007 Annual Research Report
  • [Remarks]

    • URL

      http://achem.okayama-u.ac.jp/eoc/index.html

    • Related Report
      2009 Final Research Report
  • [Remarks]

    • URL

      http://achem.okayama-u.ac.jp/eoc/index.html

    • Related Report
      2007 Annual Research Report

URL: 

Published: 2007-04-01   Modified: 2016-04-21  

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