Studies on Environment Conscious Catalytic Processes in Supercritical Fluid
Project/Area Number |
19310060
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Research Category |
Grant-in-Aid for Scientific Research (B)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Environmental technology/Environmental materials
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Research Institution | Gifu University |
Principal Investigator |
SUGI Yoshihiro Gifu University, 工学部, 教授 (90281047)
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Co-Investigator(Kenkyū-buntansha) |
KOMURA Kenichi 岐阜大学, 工学部, 准教授 (40377685)
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Project Period (FY) |
2007 – 2008
|
Project Status |
Completed (Fiscal Year 2008)
|
Budget Amount *help |
¥13,390,000 (Direct Cost: ¥10,300,000、Indirect Cost: ¥3,090,000)
Fiscal Year 2008: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2007: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
|
Keywords | グリーンケミストリー / ゼオライト / メソポーラス材料 / 超臨界媒体 / 炭酸ガス / ナノサイズベータゼオライト / 形状選択性 |
Research Abstract |
環境調和型化学プロセスの鍵技術である超臨界流体、特に超臨界炭酸ガス(sc-CO_2)媒体中における固体酸触媒機能を検討した。Sc-CO_2を反応媒体にすることにより触媒活性劣化の原因となる重質有機化合物が効率的に除去され、触媒活性が長期間にわたり持続されることが実証できた。また、新規触媒機能を有する多孔質触媒の創成に関する研究を行い、メソポーラス細孔とゼオライト骨格を有する新規材料Al-MCM-48-SUB の創製に成功した。
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Report
(3 results)
Research Products
(124 results)
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[Journal Article] The Alkylation of Biphenyl over Three-Dimensional Large Pore Zeolites. The Influence of Zeolite Structure and Alkylating Agents on the Selectivity for 4,4'-Dialkylbiphenyl, Catal2008
Author(s)
Y. Sugi, H. Maekawa, Y. Hasegawa, A. Ito, R. Asai, D. Yamamoto, K. Komura, Y. Kubota, J. -H. Kim, and G. Seo
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Journal Title
Related Report
Peer Reviewed
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[Journal Article] The Shape-Selective Isopropylation of Biphenyl over CIT-5 Zeolites with CFI Topology, J. Mol2008
Author(s)
H. Maekawa, A. Iida, C. Naitoh, K. Nakagawa, K. Komura, Y. Kubota, Y. Sugi, D. -H. Choi, -H. Kim, and G. Seo
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Journal Title
Catal. A : Chemical 274
Pages: 24-32
Related Report
Peer Reviewed
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[Journal Article] The Isopropylation of Biphenyl over One-dimensional Zeolites with Corrugated Channels2008
Author(s)
H. Maekawa, T. Shibata, A. Niimi, C. Asaoka, K. Yamasaki, H Naiki, K. Komura, Y. Kubota, Y. Sugi, J. -Y. Lee, J. -H. Kim, G. Seo
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Journal Title
J. Mol. Catal. A : Chemical 279
Pages: 27-36
Related Report
Peer Reviewed
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[Journal Article] The Alkylation of Biphenyl over Three-Dimensional Large Pore Zeolites. The Influence of Zeolite structure and Alkylating Agents on the Selectivity for 4, 4' -Dialkylbiphenyl2008
Author(s)
Y. Sugi, H. Maekawa, Y. Hasegawa, A. Ito, R. Asai, D. Yamamoto, K. Komura, Y. Kubota, J. -H. Kim, G. Seo
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Journal Title
Catal. Today 131
Pages: 413-422
Related Report
Peer Reviewed
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[Journal Article] The Alkylation of Biphenyl over One-Dimensional Twelve-Membered Ring Zeolites2007
Author(s)
Y. Sugi, H. Maekawa, A. Ito, C. Ozawa, T. Shibata, A. Niimi, C. Asaoka, K. Komura, Y. Kubota, J. -Y. Lee, J. -H. Kim, and G. Seo
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Journal Title
The Influence of Zeolite Structure and Alkylating Agents on the Selectivity for 4,4'-Dialkylbiphenyl, Bull. Chem. Soc. Jpn 80
Pages: 2232-2242
Related Report
Peer Reviewed
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[Journal Article] The Alkylation of Biphenyl over Fourteen-Membered Ring Zeolites. The Influence of Zeolite Structure and Alkylating Agent on the Selectivity for 4,4'-Dialkylbiphenyl, Bull2007
Author(s)
Y. Sugi, H. Maekawa, S. A. R. Mulla, A. Ito, C. Naitoh, K. Nakagawa, K. Komura, Y. Kubota, J.-H. Kim, and G. Seo
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Journal Title
Chem. Soc. Jpn 80
Pages: 1418-1428
Related Report
Peer Reviewed
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[Journal Article] The isopropylation of biphenyl over one-dimensional zeolites with corrugated channels2007
Author(s)
H. Maekawa, T. Shibata, A. Niimi, C. Asaoka, K. Yamasaki, H. Naiki, K. Komura, Y. Kubota, Y. Sugi, J.-Y. Lee, J.-H. Kim, G. Seo
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Journal Title
J. Mol. Catal. A: Chemical. 279
Pages: 27-36
Related Report
Peer Reviewed
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[Journal Article] The Alkylation of Biphenyl over Fourteen-Membered Ring Zeolites. The Influence of Zeolite Structure and Alkylating Agent on the Selectivity for 4,4'-Dialkylbiphenyl
Author(s)
Y. Sugi, H. Maekawa, S. A. R. Mulla, A. Ito, C. Naitoh, K. Nakagawa, K. Komura, Y. Kubota, J-H. Kim, G. Seo
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Journal Title
Bull. Chem. Soc. Jpn (印刷中)
NAID
Related Report
Peer Reviewed
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[Journal Article] The Alkylation of Biphenyl over One-Dimensional Twelve-Membered Ring Zeolites. The Influence of Zeolite Structure and Alkylating Agent on the Selectivity for 4,4'-Dialkylbiphenyl
Author(s)
Y. Sugi, H. Maekawa, A. Ito, C. Ozawa, T. Shibata, A. Niimi, C. Asaoka, K. Komura, Y. Kubota, J.-Y. Lee, J-H. Kim, G. Seo
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Journal Title
Bull. Chem. Soc. Jpn (印刷中)
NAID
Related Report
Peer Reviewed
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