Studies on Environment Conscious Catalytic Processes in Supercritical Fluid

• Project/Area Number: 19310060
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Environmental technology/Environmental materials
• Research Institution: Gifu University
• Principal Investigator: SUGI Yoshihiro Gifu University, 工学部, 教授 (90281047)
• Co-Investigator(Kenkyū-buntansha): KOMURA Kenichi 岐阜大学, 工学部, 准教授 (40377685)
• Project Period (FY): 2007 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥13,390,000 (Direct Cost: ¥10,300,000、Indirect Cost: ¥3,090,000); Fiscal Year 2008: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000); Fiscal Year 2007: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
• Keywords: グリーンケミストリー / ゼオライト / メソポーラス材料 / 超臨界媒体 / 炭酸ガス / ナノサイズベータゼオライト / 形状選択性

Research Abstract

環境調和型化学プロセスの鍵技術である超臨界流体、特に超臨界炭酸ガス(sc-CO_2)媒体中における固体酸触媒機能を検討した。Sc-CO_2を反応媒体にすることにより触媒活性劣化の原因となる重質有機化合物が効率的に除去され、触媒活性が長期間にわたり持続されることが実証できた。また、新規触媒機能を有する多孔質触媒の創成に関する研究を行い、メソポーラス細孔とゼオライト骨格を有する新規材料Al-MCM-48-SUB の創製に成功した。

Research Products

• [Journal Article] The Isomerization of 4,4'-Diisopropyl- biphenyl at External Acid Sites in the Isopropylation of Biphenyl over H-Mordenites (2009)
  • Author(s): Y. Sugi, I. Toyama, H. Tamada, S. Tawada, K. Komura, and Y. Kubota
  • Journal Title: J. Mol. Catal. A : Chemical 304 Pages: 22-27
  • Peer Reviewed
• [Journal Article] Highly stable Mesoporous Aluminosilicates with a Dual Pore System : Simultaneous Formation of Mesophase with Zeolitic Building Units (2009)
  • Author(s): S. C. Laha, A. Sakthivel, K. Komura, S. -J. Huang, P. -H. Wu, S. -B. Liu, Y. Sasaki, M. Kobayashi, Y. Sugi
  • Journal Title: Chem. Lett. 38(印刷中)
  • NAID: 10025122732
  • Peer Reviewed
• [Journal Article] The Isomerization of 4, 4'-Diisopropylbiphenyl at External Acid Sites in the Isopropylation of Biphenyl over H-Mordenites (2009)
  • Author(s): Y. Sugi, I. Toyama, H. Tamada, S. Tawada, K. Komura, Y. Kubota
  • Journal Title: J. Mol. Catal. A : Chemical 304 Pages: 22-27
  • Peer Reviewed
• [Journal Article] The β-Zeolite Synthesized by Dry-gel Conversion Method Without the Use of Sodium Hydroxide : Characterization and Catalytic Behaviors (2009)
  • Author(s): T. Shibata, S. Suzuki, H. Maekawa, K. Komura, Y. Kubota, Y. Sugi
  • Journal Title: J. Mol. Catal. A : Chemical 297 Pages: 80-85
  • Peer Reviewed
• [Journal Article] The β-Zeolite Synthesized by Dry-gel Conversion Method without the Use of Sodium Hydroxide : Characterization and Catalytic Behaviors (2009)
  • Author(s): A. Sakthivel, A. Iida, K. Komura, Y. Sugi
  • Journal Title: J. Nanosci. Nanotechnol. 9 Pages: 475-483
  • Peer Reviewed
• [Journal Article] Nano-sized β-Zeolites with Tunable Particle Sizes : Synthesis by DGC Method in the Presence of Surfactants, Characterization, and Catalytic Properties (2009)
  • Author(s): A. Sakthivel, A. Iida, K. Komura, Y. Sugi, K. V. R. Chary
  • Journal Title: Micorpor. Mesopor. Mater. 119 Pages: 322-330
  • Peer Reviewed
• [Journal Article] Na-Y Zeolite as a Highly Active Catalyst for the Hydroamination of α, β-Unsaturated Compounds with Aromatic Amines (2009)
  • Author(s): K. Komura, R. Hongo, J. Tsutsui, Y. Sugi
  • Journal Title: Catal. Lett. 128 Pages: 203-209
  • Peer Reviewed
• [Journal Article] Strong Acids as Catalysts for the Chloromethylation of m-Xylene. Environmentally Conscious Synthesis of 1, 3-bis(Chloromethyl)-4, 6-dimethylbenzene (2009)
  • Author(s): T. Kishida, N. Ieda, T. Yamauchi, K. Komura, Y. Sugi
  • Journal Title: Ind. Eng. Chem. Res. 48 Pages: 1831-1839
  • Peer Reviewed
• [Journal Article] Tungstophosphoric Acid Supported on MCM-48 : An Efficient Catalyst for the Esterification of Long Chain Fatty Acids and Alcohols in Supercritical Carbon Dioxide (2009)
  • Author(s): A. Sakthivel, K. Komura, Y. Sugi
  • Journal Title: Ind. Ens. Chem. Res. 47 Pages: 2538-2544
  • Peer Reviewed
• [Journal Article] The Alkylation of Naphthalene over One-dimensional Twelve-membered Ring Zeolites. The Influence of Zeolite structure and Alkylating Agents on the Selectivity for Dialkylnaphthalenes (2009)
  • Author(s): Y. Sugi, H. Maekawa, H. Naiki, K. Komura, Y. Kubota
  • Journal Title: Bull. Chem. Soc. Jpn. 81 Pages: 897-905
  • NAID: 10021077022
  • Peer Reviewed
• [Journal Article] A New Synthesis Route to Nano-sized β-Zeolite with Organic Silane Containing Surfactant (2008)
  • Author(s): C.Venkatesan, K. Aoyama, K. Komura, and Y. Sugi
  • Journal Title: Zeolites and Related Materials : Trends, Targets and Challenges (Stud. Surf. Sci. Catal. 174A) Elsevier Pages: 225-228
  • Peer Reviewed
• [Journal Article] Synthetic Investigation on MCM-68 Zeolite with MSE Topology and its Application for Shape-Selective Alkylation of Biphenyl, Micropor (2008)
  • Author(s): T. Shibata, S. Suzuki, H. Kawagoe, K. Komura, Y.Kubota, Y. Sugi, J. -H. Kim, and G. Seo
  • Journal Title: Mesopor. Mater 116 Pages: 216-226
  • Peer Reviewed
• [Journal Article] The Alkylation of Naphthalene over One-dimensional Fourteen-membered Ring Zeolites (2008)
  • Author(s): Y. Sugi, H. Maekawa, H. Naiki, K. Komura and Y.Kubota
  • Journal Title: The Influence of Zeolite Structure and Alkylating Agents on the Selectivity for Dialkylnaphthalenes, Bull. Chem. Soc. Jpn 81 Pages: 1166-1174
  • Peer Reviewed
• [Journal Article] New Synthesis Route to Uniform-sized β-Zeolite in the Presence of a Cationic Surfactant Containing Siloxane Moiety (2008)
  • Author(s): C. Venkatesan, K. Komura, and Y. Sugi
  • Journal Title: Chem. Lett. 37 Pages: 668-669
  • NAID: 10021081683
  • Peer Reviewed
• [Journal Article] Selective Isopropylation of Isobutylbenzene over H-Mordenite in Supercritical CO2 Medium : Remarkable Enhancement in Catalytic Activity and Selectivity for 4-Isobutylcumene (2008)
  • Author(s): S. C. Laha, K. Komura, and Y. Sugi
  • Journal Title: Catal. Lett. 123 Pages: 259-263
  • Peer Reviewed
• [Journal Article] The Alkylation of Naphthalene over One-dimensional Twelve-membered Ring Zeolites. The Influence of Zeolite Structure and Alkylating Agents on the Selectivity for Dialkylnaphthalenes, Bull (2008)
  • Author(s): Y. Sugi, H. Maekawa, H. Naiki, K. Komura, and Y. Kubota
  • Journal Title: Chem. Soc. Jpn 81 Pages: 897-905
  • Peer Reviewed
• [Journal Article] Fe(III)Containing Mesoporous Molecular Sieves with Framework Zeolite Secondary Builiding Units, J. Nanosci (2008)
  • Author(s): A. Sakthivel, K. Komura, and Y. Sugi
  • Journal Title: Nanotechnol 8 Pages: 400-404
  • Peer Reviewed
• [Journal Article] The Alkylation of Naphthalene over Three-dimensional Large Pore Zeolites (2008)
  • Author(s): Y. Sugi, H. Maekawa, Y. Hasegawa, H. Naiki, K. Komura, and Y. Kubota
  • Journal Title: The Influence of Zeolite Structure and Alkylating Agent on the Selectivity for Dialkylnaphthalenes, Catal. Today 132 Pages: 27-37
  • Peer Reviewed
• [Journal Article] The Shape-selective Ethylation of Biphenyl over H-Mordenite. Reactivity of the Intermediates on the Catalysis, J. Mol. Catal (2008)
  • Author(s): Y. Sugi, S. Watanabe, Y. Imada, K. Komura, and Y. Kubota
  • Journal Title: A : Chemical 285 Pages: 101-110
  • Peer Reviewed
• [Journal Article] MCM-48 Supported Tungstophosphoric Acid : An Efficient Catalyst for the Esterification of Long-Chain Fatty Acids and Alcohols in Supercritical Carbon Dioxide, Ind (2008)
  • Author(s): A. Sakthivel, K. Komura, and Y. Sugi
  • Journal Title: Eng. Chem. Res. 47 Pages: 2538-2544
  • Peer Reviewed
• [Journal Article] The Alkylation of Biphenyl over Three-Dimensional Large Pore Zeolites. The Influence of Zeolite Structure and Alkylating Agents on the Selectivity for 4,4'-Dialkylbiphenyl, Catal (2008)
  • Author(s): Y. Sugi, H. Maekawa, Y. Hasegawa, A. Ito, R. Asai, D. Yamamoto, K. Komura, Y. Kubota, J. -H. Kim, and G. Seo
  • Journal Title: Today 131 Pages: 413-422
  • Peer Reviewed
• [Journal Article] The Shape-Selective Isopropylation of Biphenyl over CIT-5 Zeolites with CFI Topology, J. Mol (2008)
  • Author(s): H. Maekawa, A. Iida, C. Naitoh, K. Nakagawa, K. Komura, Y. Kubota, Y. Sugi, D. -H. Choi, -H. Kim, and G. Seo
  • Journal Title: Catal. A : Chemical 274 Pages: 24-32
  • Peer Reviewed
• [Journal Article] The Isopropylation of Biphenyl over One-dimensional Zeolites with Corrugated Channels (2008)
  • Author(s): H. Maekawa, T. Shibata, A. Niimi, C. Asaoka, K. Yamasaki, H Naiki, K. Komura, Y. Kubota, Y. Sugi, J. -Y. Lee, J. -H. Kim, G. Seo
  • Journal Title: J. Mol. Catal. A : Chemical 279 Pages: 27-36
  • Peer Reviewed
• [Journal Article] The Alkylation of Biphenyl over Three-Dimensional Large Pore Zeolites. The Influence of Zeolite structure and Alkylating Agents on the Selectivity for 4, 4' -Dialkylbiphenyl (2008)
  • Author(s): Y. Sugi, H. Maekawa, Y. Hasegawa, A. Ito, R. Asai, D. Yamamoto, K. Komura, Y. Kubota, J. -H. Kim, G. Seo
  • Journal Title: Catal. Today 131 Pages: 413-422
  • Peer Reviewed
• [Journal Article] The Esterification of Glycerine with Laurie Acid Catalyzed by Multi-valent Metal Salts. Selective Formation of Mono-and Dilaurins (2008)
  • Author(s): R. Nakamura, K. Komura, Y. Sugi
  • Journal Title: Catal. Commun. 9 Pages: 511-515
  • Peer Reviewed
• [Journal Article] Fe (III) Containing Mesoporous Molecular Sieves with Framework Zeolite Secondary Building Units (2008)
  • Author(s): A. Sakthivel, K. Komura, Y. Sugi
  • Journal Title: J. Nanosci. Nanotechnol. 8 Pages: 400-404
  • Peer Reviewed
• [Journal Article] The Alkylation of Naphthalene over Three-dimensional Large Pore Zeolites. The Influence of Zeolite Structure and Alkylating Agent on the Selectivity for Dialkylnaphthalenes (2008)
  • Author(s): Y. Sugi, H. Maekawa, Y. Hasegawa, H. Naiki, K. Komura, Y. Kubota
  • Journal Title: Catal. Today 132 Pages: 27-37
  • Peer Reviewed
• [Journal Article] The Shape-selective Ethylation of Biphenyl over H-Mordenite. Reactivity of the Intermediates on the Catalysis (2008)
  • Author(s): Y. Sugi, S. Watanabe, Y. Imada, K. Komura, Y. Kubota
  • Journal Title: J. Mol. Catal. A : Chemical 285 Pages: 101-110
  • Peer Reviewed
• [Journal Article] Selective Isopropylation of Isobutylbenzene over H-Mordenite in Supercritical C0_2 Medium : Remarkable Enhancement in Catalytic Activity and Selectivity for 4-Isobutylcumene (2008)
  • Author(s): S. C. Laha, K. Komura, Y. Sugi
  • Journal Title: Catal. Lett. 123 Pages: 259-263
  • Peer Reviewed
• [Journal Article] Remarkable Improvement of Catalytic Performance in Dimethyl Ether to Olefin (DTO)Reaction over CeO_2 -modified Calcium-containing MFI Type Zeolite (2008)
  • Author(s): A. Iida, R. Nakamura, K. Komura, Y. Sugi
  • Journal Title: Chem. Lett. 37 Pages: 494-495
  • Peer Reviewed
• [Journal Article] New Synthesis Route to Nano-sized β-Zeolite in the Presence of a Cationic Surfactant Containing Siloxane Moiety (2008)
  • Author(s): C. Venkatesan, K. Komura, Y. Sugi
  • Journal Title: Chem. Lett. 37 Pages: 668-669
  • Peer Reviewed
• [Journal Article] The Alkylation of Naphthalene over One-dimensional Fourteen-membered Ring Zeolites. The Influence of Zeolite structure and Alkylating Agents on the Selectivity for Dialkylnaphthalenes (2008)
  • Author(s): Y. Sugi, H. Maekawa, H. Naiki, K. Komura, Y. Kubota
  • Journal Title: Bull. Chem. Soc. Jpn. 81 Pages: 1166-1174
  • NAID: 10022019566
  • Peer Reviewed
• [Journal Article] Synthetic Investigation on MCM-68 Zeolite with MSE Topology and its Application for Shape-Selective Alkylation of Biphenyl (2008)
  • Author(s): T. Shibata, S. Suzuki, H . Kawagoe, K. Komura, Y. Kubota, Y. Sgsi, J. -H. Kim, G. Seo
  • Journal Title: Micropor. Mesopor. Mater. 116 Pages: 216-226
  • Peer Reviewed
• [Journal Article] Multi-Valent Metal Salts as Versatile Catalyst for the Amidation of Long-chain Aliphatic Acid with Aliphatic Amine (2008)
  • Author(s): Y Terada, N. Ieda, K. Komura, Y. Sugi
  • Journal Title: Synthesis 2008 Pages: 2318-2320
  • Peer Reviewed
• [Journal Article] FeCl_3・6H_2O as a Versatile Catalyst for the Esterification of Steroid Alcohols with Fatty Acids (2008)
  • Author(s): K. Komura, A. Ozaki, N. Ieda, Y. Sugi
  • Journal Title: Synthesis 2008 Pages: 3407-3410
  • Peer Reviewed
• [Journal Article] Quinoline-Carboimine Derived Palladium Complexes Immobillized on Ordered Mesoporous Silica as Catalysts for Sonogashira Coupling Reactions (2008)
  • Author(s): H. Nakamura, K. Komura, Y. Sugi
  • Journal Title: J. Mol. Catal. A : Chemical 293 Pages: 72-78
  • Peer Reviewed
• [Journal Article] Product Selectivity and Catalytic Deactivation of MOR Zeolites with Different Acid Site Densities in Methanll-to-Olefin Reaction (2008)
  • Author(s): J. W. Park, S. J. Kim, M. E. Seo, S. Y. Kim, Y. Sugi, G. Seo
  • Journal Title: Appl. Catal. A : General 349 Pages: 76-85
  • Peer Reviewed
• [Journal Article] Multi-Valent Metal Salt Hydrates as Catalysts for the Esterification of Fatty Acids and Alcohols (2008)
  • Author(s): N. Ieda, K. Mant, R. Nakamur a, Y. Miya, K. Komura, Y. Sugi
  • Journal Title: Ind. Eng. Chem. Res. 47 Pages: 8631-8638
  • Peer Reviewed
• [Journal Article] Synthesis of Nano-sized β-Zeolites by Dry Gel Conversion (DGC) Method with the Use of Sodium Hydroxide (2008)
  • Author(s): A. Sakthivel, A. Iida, K. Komura, Y. Sugi
  • Journal Title: Nanoporous Materials Pages: 79-88
  • Peer Reviewed
• [Journal Article] Quinoline-Carboimine Palladium Complex Immobilized on MCM-41 as a Versatile Catalyst for Sonogashira Corss Coupling Reaction (2008)
  • Author(s): H. Nakamura, K. Komura, Y. Sugi
  • Journal Title: Nanoporous Materials Pages: 561-570
  • Peer Reviewed
• [Journal Article] A New Synthesis Route to Nano-sized β-Zeolite with Organic Silane Containing Surfactant (2008)
  • Author(s): C. Venkatesan, K. Aoyama, K. Komura, Y. Sugi
  • Journal Title: Stud. Surf. Sci. Catal. 174A Pages: 225-228
  • Peer Reviewed
• [Journal Article] The ethylation of biphenyl over H-mordenite: Reactivities of the intermediates in the catalysis (2008)
  • Author(s): Y. Sugi, S. Watanabe, Y. Imada, S. B. Waghmode, K. Komura, Y. Kubota, T. Hanaoka, T. Matsuzaki, K. Nakajima, K. Kunimori
  • Journal Title: J. Mol. Catal. A: Chemical 285 Pages: 101-110
  • Peer Reviewed
• [Journal Article] MCM-48 supported tungstophosphoric acid: An efficient catalyst for the esterrfication of long-chain fatty acids and alcohols in supercritical carbon dioxide (2008)
  • Author(s): A. Sakthivel, K. Komura, Y. Sugi
  • Journal Title: Ind. Eng. Chem. Res 47 Pages: 2538-2544
  • Peer Reviewed
• [Journal Article] The Esterification of Glycerine with Lauric Acid Catalyzed by Multi-valent Metal Salts.Selective Formation of Mono-and Dilaurins (2008)
  • Author(s): R. Nakamura, K. Komura, Y. Sugi
  • Journal Title: Catal. Chem. 9 Pages: 511-515
  • Peer Reviewed
• [Journal Article] Fe(III)Containing MCM-48 Type Mesoporous Molecular Sieves with Frame work Zeolite Secondary Building Units (2008)
  • Author(s): A. Sakthivel, K. Komura, Y. Sugi
  • Journal Title: J. Nanosci. Nanotechn. 8 Pages: 400-404
  • Peer Reviewed
• [Journal Article] Na-Y Zeolite as a Versatile Heterogeneous Catalyst for the Hydroamination of Methyl Acrylate with Amines (2008)
  • Author(s): K. Komura, J. Tsutsui, R. Hongo, Y. Sugi
  • Journal Title: Stud. Surf. Sci. Catal. 170B Pages: 1111-1119
  • Peer Reviewed
• [Journal Article] Shape-Selective Alkylation of Biphenyl over Metalloaluminophosphates with AFI Topology (2007)
  • Author(s): H. Maekawa, S. K. Saha, S. A. R. Mulla, S. B. Waghmode, K. Komura, Y. Kubota, and Y. Sugi
  • Journal Title: J. Mol. Catal. A : Chemical 263 Pages: 238-246
  • Peer Reviewed
• [Journal Article] Hydrothermal Synthesis of Metallosilicate SSZ-24 from Metallosilicate Beta as Precursors, Micropor (2007)
  • Author(s): Y. Kubota, H. Maekawa, S. Miyata, T. Tatsumi, and Y. Sugi
  • Journal Title: Mesopor. Mater 101 Pages: 115-126
  • Peer Reviewed
• [Journal Article] The Alkylation of Biphenyl over One-Dimensional Twelve-Membered Ring Zeolites (2007)
  • Author(s): Y. Sugi, H. Maekawa, A. Ito, C. Ozawa, T. Shibata, A. Niimi, C. Asaoka, K. Komura, Y. Kubota, J. -Y. Lee, J. -H. Kim, and G. Seo
  • Journal Title: The Influence of Zeolite Structure and Alkylating Agents on the Selectivity for 4,4'-Dialkylbiphenyl, Bull. Chem. Soc. Jpn 80 Pages: 2232-2242
  • Peer Reviewed
• [Journal Article] The Alkylation of Biphenyl over Fourteen-Membered Ring Zeolites. The Influence of Zeolite Structure and Alkylating Agent on the Selectivity for 4,4'-Dialkylbiphenyl, Bull (2007)
  • Author(s): Y. Sugi, H. Maekawa, S. A. R. Mulla, A. Ito, C. Naitoh, K. Nakagawa, K. Komura, Y. Kubota, J.-H. Kim, and G. Seo
  • Journal Title: Chem. Soc. Jpn 80 Pages: 1418-1428
  • Peer Reviewed
• [Journal Article] Novel Route to Synthesize Nano-sized β-Zeolite with High Surface Area (2007)
  • Author(s): A. Sakthivel, K. Komura, and Y. Sugi
  • Journal Title: Chem. Lett. 36 Pages: 894-895
  • Peer Reviewed
• [Journal Article] Esterification of Glycerine by Lauric Acid over Aluminium and Zirconium containing Mesoporous Molecular Sieves under Supercritical Carbon Dioxide Medium (2007)
  • Author(s): A. Sakthivel, R. Nakamura, K. Komura, and Y. Sugi
  • Journal Title: J. Superfluids Chem. 42 Pages: 219-225
  • Peer Reviewed
• [Journal Article] Shape-Selective Alkylation of Biphenyl over H-[Al]-SSZ-24 Zeolites with AFI Topology, H. Maekawa, Bull (2007)
  • Author(s): A. Ito, H. Kawagoe, K. Komura, Y. Kubota, and Y. Sugi
  • Journal Title: Chem. Soc. Jpn. 80 Pages: 215-223
  • Peer Reviewed
• [Journal Article] Hydrothermal Synthesis of Metallosilicate SSZ-24 from Metallosilicate Beta as Precursors (2007)
  • Author(s): Y. Kubota, H. Maekawa, S. Miyata, T. Tatsumi, Y. Sugi
  • Journal Title: Micropor. Mesopor. Mater. 101 Pages: 115-126
  • Peer Reviewed
• [Journal Article] Esterification of glycerol by lauric acid over aluminum and zirconium containing mesoporous molecular sieves uder supercritical carbon dioxide medium (2007)
  • Author(s): A. Sakthivel, R. Nakamura, K. Komura, Y. Sugi
  • Journal Title: J. Super Fluid. Chem. 42 Pages: 219-225
  • Peer Reviewed
• [Journal Article] A Novel Layered Silicate Having the Intercalated Potassium Cation: Synthesis, Characterizations, and Modification by Acid Treatment (2007)
  • Author(s): K. Komura, T. Ikeda, A. Kawai, F. Mizukami, Y. Sugi
  • Journal Title: Chem. Lett. 36 Pages: 1248-1249
  • NAID: 10019961750
  • Peer Reviewed
• [Journal Article] Novel Route to Synthesize Nano-sized 〓-Zeolite with High Surface Area (2007)
  • Author(s): A. Sakthivel, K. Komura, Y. Sugi
  • Journal Title: Chem. Lett. 36 Pages: 894-845
  • Peer Reviewed
• [Journal Article] The isopropylation of biphenyl over one-dimensional zeolites with corrugated channels (2007)
  • Author(s): H. Maekawa, T. Shibata, A. Niimi, C. Asaoka, K. Yamasaki, H. Naiki, K. Komura, Y. Kubota, Y. Sugi, J.-Y. Lee, J.-H. Kim, G. Seo
  • Journal Title: J. Mol. Catal. A: Chemical. 279 Pages: 27-36
  • Peer Reviewed
• [Journal Article] Shape-Selective Isopropylation of Biphenyl over CIT-5 Zeolites with CFI Topology (2007)
  • Author(s): H. Maekawa, C. Naitoh, K. Nakagawa, A. Iida, K. Komura, Y. Kubota, Y. Sugi J.-H. Kim, G. Seo
  • Journal Title: J. Mol. Catal. A: Chemical 274 Pages: 24-32
  • Peer Reviewed
• [Journal Article] Multi-valent metal salts as versatile catalyst for the amidation of long-chain aliphaticacid with aliphatic amine
  • Author(s): Y. Terada, N. Ieda, K. Komura, Y. Sugi
  • Journal Title: Synthesis (印刷中)
  • Peer Reviewed
• [Journal Article] New Synthesis Route to Uniform-sized 〓-Zeolite in the Presence of a Cationic Surfactant Containing Siloxane Moiety
  • Author(s): C. Venkatesan, K. Komura, Y. Sugi
  • Journal Title: Chem. Lett. (印刷中)
  • Peer Reviewed
• [Journal Article] Synthetic Investigation on MCM-68 Zeolite with MSE Tbpology and its Application for Shape-Selective Alkylation of Biphenyl
  • Author(s): T. Shibata, S. Suzuki, H. Kawagoe, K. Komura, Y. Kubota, Y. Sugi, J.-H. Kim, G. Seo
  • Journal Title: Micropor. Mesopor. Mater. (印刷中)
  • Peer Reviewed
• [Journal Article] The Alkylation of Naphthalene over One-dimensional Twelve-membered Ring Zeolites. The Influence of Zeolite Structure and Alkylating Agent on the Selectivity for Dialkylnanthalenes
  • Author(s): Y. Sugi, H. Maekawa, H. Naiki, K. Komura, Y. Kubota
  • Journal Title: Bu11. Chem. Soc. Jpn (印刷中)
  • Peer Reviewed
• [Journal Article] The Alkylation of Naphthalene over One-dimensional Fourteen-membered Ring Zeolites. The Influence of Zeolite Structure and Alkylating Agent on the Selectivity for Dialkylnanthalenes
  • Author(s): Y. Sugi, H. Maekawa, H. Naiki, K. Komura, Y. Kubota
  • Journal Title: Bu11. Chem. Soc. Jpn (印刷中)
  • Peer Reviewed
• [Journal Article] The 〓-Zeolite synthesized by dry-gel conversion method without the use of sodium hydroxide: Characterization and catalytic behaviors
  • Author(s): A. Sakthivel, A. Iida, K. Komura, Y. Sugi
  • Journal Title: J. Nanosci. Nanotechno. (印刷中)
  • Peer Reviewed
• [Journal Article] The alkylation of naphthalene over three-dimensional large pore zeolites: The influenceof zeolite structure and alkylating agent on the selectivity for dialkylnaphthalenes
  • Author(s): Y. Sugi, H. Maekawa, Y. Hasegawa, H. Naiki, K. Komura, Y, Kubota J.-H. Kim, G. Seo
  • Journal Title: Catal. Today (印刷中)
  • Peer Reviewed
• [Journal Article] Remarkable Improvement of Catalytic Performance in Dimethylether to Olefin(DTO)Reaction over CeO_2-modified Calcium-containing MFI Type Zeolite
  • Author(s): A. Iida, R. Nakamura, K. Komura, Y. Sugi
  • Journal Title: Chem. Lett. (印刷中)
  • Peer Reviewed
• [Journal Article] Selective isopropylation of isobutylbenzene over H-mordenite in supercritical CO_2 medium: Remarkable enhancement in catalytic activity and selectivity for 4-isobutylcumene
  • Author(s): S. C. Laha, K. Komura, Y. Sugi
  • Journal Title: Catal. Lett. (印刷中)
  • Peer Reviewed
• [Journal Article] The Alkylation of Biphenyl over Fourteen-Membered Ring Zeolites. The Influence of Zeolite Structure and Alkylating Agent on the Selectivity for 4,4'-Dialkylbiphenyl
  • Author(s): Y. Sugi, H. Maekawa, S. A. R. Mulla, A. Ito, C. Naitoh, K. Nakagawa, K. Komura, Y. Kubota, J-H. Kim, G. Seo
  • Journal Title: Bull. Chem. Soc. Jpn (印刷中)
  • NAID: 10019528008
  • Peer Reviewed
• [Journal Article] The Alkylation of Biphenyl over One-Dimensional Twelve-Membered Ring Zeolites. The Influence of Zeolite Structure and Alkylating Agent on the Selectivity for 4,4'-Dialkylbiphenyl
  • Author(s): Y. Sugi, H. Maekawa, A. Ito, C. Ozawa, T. Shibata, A. Niimi, C. Asaoka, K. Komura, Y. Kubota, J.-Y. Lee, J-H. Kim, G. Seo
  • Journal Title: Bull. Chem. Soc. Jpn (印刷中)
  • NAID: 10019795649
  • Peer Reviewed
• [Presentation] Heterogeneous Aza-Henry reaction of aldimine with nitromethane catalyzed by zeolite catalysts for the synthesis of beta-nitroamine compounds, National Catalysis Symposium (2009)
  • Author(s): K. Komura, Y. Taninaka, and Y. Sugi
  • Organizer: Catalysis Society of India, Pune
  • Place of Presentation: India
  • Year and Date: 2009-01-18
• [Presentation] Heterogeneous Aza-Henry reaction of aldimine with nitromethane catalyzed by zeolite catalysts for the synthesis of beta-nitroamine compounds. (2009)
  • Author(s): K. Komura, Y. Taninaka, Y. Sugi
  • Organizer: National Catalysis Symposium, Catalysis Society of India
  • Place of Presentation: Pune, India
  • Year and Date: 2009-01-18
• [Presentation] 結晶性層状ケイ酸塩(K-LDS)の合成と特長、機能化に向けて (2008)
  • Author(s): 小村賢一, 上中麻奈未, 池田卓史, 杉義弘
  • Organizer: 第24 回ゼオライト研究発表会
  • Place of Presentation: 東京
  • Year and Date: 2008-11-27
• [Presentation] 結晶性層状ケイ酸塩(K-LDS)の合成と特長、機能化に向けて (2008)
  • Author(s): 小村賢一, 上中麻奈未, 池田卓史, 杉義弘
  • Organizer: ゼオライト研究発表会
  • Place of Presentation: 東京
  • Year and Date: 2008-11-27
• [Presentation] ゼオライトの形状選択性-ビフェニルのアルキル化を例として (2008)
  • Author(s): 杉義弘
  • Organizer: 第24 回ゼオライト研究発表会
  • Place of Presentation: 東京
  • Year and Date: 2008-11-26
• [Presentation] ゼオライトの形状選択性-ビフェニルのアルキル化を例として (2008)
  • Author(s): 杉義弘
  • Organizer: ゼオライト研究発表会
  • Place of Presentation: 東京
  • Year and Date: 2008-11-26
• [Presentation] A New Synthesis Route to Nano-sized β-Zeolite with Organic Silane Containing Surfactant (2008)
  • Author(s): C. Venkatesan, K. Aoyama, K. Komura, and Y. Sugi
  • Organizer: 4th International FEZA Conference (FEZA2008)
  • Place of Presentation: Paris, France
  • Year and Date: 2008-08-30
• [Presentation] Shape-selective isopropylation of isobutylbenzene in supercritical CO_2 over H-mordenite (2008)
  • Author(s): S. C. Laha, K. Komura, and Y. Sugi
  • Organizer: 14th International Congress on Catalysis
  • Place of Presentation: Seoul, Korea
  • Year and Date: 2008-07-17
• [Presentation] Shape-selective isopropylation of isobutylbenzene in supercritical C0_2 over H-mordenite (2008)
  • Author(s): S. Laha, K. Komura, Y. Sugi
  • Organizer: 14th International Congress on Catalysis
  • Place of Presentation: Seoul, Korea
  • Year and Date: 2008-07-17
• [Presentation] hydrothermally treated aluminosilicate gels : Viable precursors for mesoporous and microporous aluminosilicates, International Symposium on Creation and Control of Advanced Selective Catalysis (2008)
  • Author(s): C. Venkatesan, K. Komura, Y. Sugi, Y. Sasaki, M. Kobayashi, and Template free
  • Organizer: A Pre-Symposium of 14th International Congress on Catalysis (Pre-ICC14, Kyoto2008)
  • Place of Presentation: 京都
  • Year and Date: 2008-07-10
• [Presentation] Template free, hydrothermally treated aluminosilicate gels : Viable precursors for mesoporous and microporous aluminosilicates (2008)
  • Author(s): C. Venkatesan, K. Komura, Y. Sugi, Y. Sasaki, M. Kobayashi
  • Organizer: International Symposium on Creation and Control of Advanced Selective Catalysis, A Pre-Symposium of 14th International Congress on Catalysis (Pre-ICC14, Kvoto2008)
  • Place of Presentation: 京都
  • Year and Date: 2008-07-10
• [Presentation] Multi-valent metal salt hydrates as catalysts for the esterification of fatty acids and alcohols, International Symposium on Creation and Control of Advanced Selective Catalysis (2008)
  • Author(s): N. Ieda, K. Mantri, Y. Miyata, K. Komura, and Y. Sugi
  • Organizer: A Pre-Symposium of 14th International Congress on Catalysis (Pre-ICC14, Kyoto2008)
  • Place of Presentation: 京都
  • Year and Date: 2008-07-09
• [Presentation] Multi-valent metal salt hydrates as catalysts for the esterification of fatty acids and alcohols (2008)
  • Author(s): N. Ieda, K. Mantri, Y. Miyata, K., Y. Sugi
  • Organizer: International Symposium on Creation and Control of Advanced Selective Catalysis, A Pre-Symposium of 14th International Congress on Catalysis (Pre-ICC14, Kyoto2008)
  • Place of Presentation: 京都
  • Year and Date: 2008-07-09
• [Presentation] Quinoline-Carboimine Palladium Complex Immobilized on MCM-41 as a Versatile Catalyst for Sonogashira Cross Coupling Reaction,Nanoporous Materials (2008)
  • Author(s): H. Nakamura, K. Komura, and Y. Sugi
  • Organizer: the 5th International Symposium
  • Place of Presentation: Vancouver, Canada
  • Year and Date: 2008-05-26
• [Presentation] Quinoline-Carboimine Palladium Complex Immobilized on MCM-41 as a Versatile Catalyst for Sonogashira Corss Coupling Reaction (2008)
  • Author(s): H. Nakamura, K. Komura, Y. Sugi
  • Organizer: Nanoporous Materials, the 5th International Symposium
  • Place of Presentation: Vancouver, Canada
  • Year and Date: 2008-05-26
• [Presentation] Synthesis of Nano-sized β-Zeolites by Dry Gel Conversion (DGC) Method with the Use of Sodium Hydroxide, Nanoporous Materials (2008)
  • Author(s): A. Sakthivel, A. Iida, K. Komura, and Y. Sugi
  • Organizer: the 5th International Symposium
  • Place of Presentation: Vancouver, Canada
  • Year and Date: 2008-05-25
• [Presentation] Synthesis of Nano-sized β-Zeolites by Dry Gel Conversion (DGC) Method with the Use of Sodium Hydroxide (2008)
  • Author(s): A. Sakthivel, A. Iida, K. Komura, Y. Sugi
  • Organizer: Nanoporous Materials, the 5th International Symposium
  • Place of Presentation: Vancouver, Canada
  • Year and Date: 2008-05-25
• [Presentation] The alkylation of biphenyl over zeolites. The influences of zeolite structure and alkylating agent on the shape-selective catalysis, International Symposium on Zeolite Catalysis for Green Chemistry in Synthesis of Chemicals and Fuels, (2008)
  • Author(s): Y. Sugi
  • Organizer: 235th ACS National Meeting
  • Place of Presentation: New Orleans, U.S.A.
  • Year and Date: 2008-04-07
• [Presentation] The alkylation of biphenyl over zeolites. The influences of zeolite structure and alkylating agent on the shape-selective catalysis (2008)
  • Author(s): Y. Sugi
  • Organizer: International Symposium on Zeolite Catalysis for Green Chemistry in Synthesis of chemicals and Fuels, 235th ACS National Meeting
  • Place of Presentation: New Orleans, U.S.A.
  • Year and Date: 2008-04-07
• [Presentation] 低級オレフィン合成におけるゼオライト触媒の希土類金属修飾効果 (2007)
  • Author(s): 飯田光, 中村亮, 小村賢一, 杉義弘
  • Organizer: 第38 回中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 三重大学
  • Year and Date: 2007-11-12
• [Presentation] 三次元大孔径ゼオライトによるナフタレンのイソプロピル化反応 (2007)
  • Author(s): 内木博章, 前川弘吉, 小村賢一, 杉義弘
  • Organizer: 第38 回中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 三重大学
  • Year and Date: 2007-11-12
• [Presentation] メソポーラス固定化パラジウム錯体を触媒とする薗頭反応 (2007)
  • Author(s): 中村英樹, 小村賢一, 杉義弘
  • Organizer: 第38 回中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 三重大学
  • Year and Date: 2007-11-12
• [Presentation] ベータゼオライトを触媒としたイソブタンのアルキル化反応 (2007)
  • Author(s): 青山清忠, 羽賀悠治, 小村賢一, 杉義弘
  • Organizer: 第38回中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 三重大学
  • Year and Date: 2007-11-12
• [Presentation] 多価金属塩触媒による長鎖脂肪酸と長鎖アミンのアミド化反応 (2007)
  • Author(s): 寺田佑嗣, 小村賢一, 杉義弘
  • Organizer: 第38 回中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 三重大学
  • Year and Date: 2007-11-12
• [Presentation] 塩化鉄水和物を触媒とした長鎖脂肪酸と長鎖アルコールのエステル化反応 (2007)
  • Author(s): 家田昇, 小村賢一, 杉義弘
  • Organizer: 第38 回中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 三重大学
  • Year and Date: 2007-11-12
• [Presentation] 塩化鉄水和物を触媒とした長鎖脂肪酸と長鎖アルコールのエステル化反応 (2007)
  • Author(s): 家田昇, 小村賢一, 杉義弘
  • Organizer: 第38回中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 三重大学
  • Year and Date: 2007-11-12
• [Presentation] 多価金属塩触媒による長鎖脂肪酸と長鎖アミンのアミド化反応 (2007)
  • Author(s): 寺田佑嗣, 小村賢一, 杉義弘
  • Organizer: 第38回中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 三重大学
  • Year and Date: 2007-11-12
• [Presentation] メソポーラス固定化パラジウム錯体を触媒とする薗頭反応 (2007)
  • Author(s): 中村英樹, 小村賢一, 杉義弘
  • Organizer: 第38回中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 三重大学
  • Year and Date: 2007-11-12
• [Presentation] 三次元大孔径ゼオライトによるナフタレンのイソプロピル化反応 (2007)
  • Author(s): 内木博章, 前川弘吉, 小村賢一, 杉義弘
  • Organizer: 第38回中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 三重大学
  • Year and Date: 2007-11-12
• [Presentation] 低級オレフィン合成におけるゼオライト触媒の希土類金属修飾効果 (2007)
  • Author(s): 飯田光, 中村亮, 小村賢一, 杉義弘
  • Organizer: 第38回中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 三重大学
  • Year and Date: 2007-11-12
• [Presentation] Shape-Selective Isopropylation of Biphenyl over MCM-68 Zeolite (2007)
  • Author(s): T. Shibata, S. Suzuki, K. Komura, Y. Kubota, and Y. Sugi
  • Organizer: 8^<th> European Catalysis Conference (Europacat 8)
  • Place of Presentation: Turku, Finland
  • Year and Date: 2007-08-28
• [Presentation] Shape-Selective Isopropylation of Biphenyl over MCM-68 Zeolite (2007)
  • Author(s): T. Shibata, S. Suzuki, K. Komura, Y. Kubota, Y. Sugi
  • Organizer: Europacat 8
  • Place of Presentation: Turku
  • Year and Date: 2007-08-28
• [Presentation] Na-Y Zeolite as a Versatile Heterogeneous Catalyst for the Hydroamination of Methyl Acrylate with Amines (2007)
  • Author(s): K. Komura, J. Tsutsui, R. Hongo, and Y. Sugi
  • Organizer: 15th International Zeolite Conference
  • Place of Presentation: Bejing, China
  • Year and Date: 2007-08-13
• [Presentation] Esterification of Long Chain Fatty Acids under supercritical CO2 Medium using AlZrMMSH Materials (2007)
  • Author(s): A. Sakthivel, K. Komura, and Y. Sugi
  • Organizer: 15th International Zeolite Conference
  • Place of Presentation: China
  • Year and Date: 2007-08-12
• [Presentation] Na-Y Zeolite as a Versatile Heterogeneous Catalyst for the Hydroamination of Methyl Acrylate with Amines (2007)
  • Author(s): K. Komura, J. Tsutsui, R. Hongo, Y. Sugi
  • Organizer: 15th Internationa Zeolite Conference
  • Place of Presentation: Bejing
  • Year and Date: 2007-08-12
• [Presentation] Esterification of Long Chain Fatty Acids under supercritical CO_2 Medium using A1ZrMMSH Materials (2007)
  • Author(s): A. Sakthivel, K. Komura, Y. Sugi
  • Organizer: 15th Internationa Zeolite Conference
  • Place of Presentation: Bejing
  • Year and Date: 2007-08-12
• [Presentation] The Alkylation of Naphthalene over Zeolites- Zeolite Structure and Bulkiness of Alkylating Agent on the Shape-selective Catalysis (2007)
  • Author(s): Y. Sugi, Y. Kubota, K. Komura, J.-H.Kim, and G. Seo
  • Organizer: 11th Japan-Korea Symposium on Catalysis
  • Place of Presentation: Seoul, Korea
  • Year and Date: 2007-05-11
• [Presentation] The Alkylation of Naphthalene over Zeolites-Zeolite Structure and Bulkiness of Alkylating Agent on the Shape-selective Catalysis (2007)
  • Author(s): Y. Sugi, Y. Kubota, K. Komura, J.-H. Kim, G. Seo
  • Organizer: 11th Japan-Korea Symposium on Catalysis
  • Place of Presentation: Seoul
  • Year and Date: 2007-05-11
• [Book] 第5章 天然ガス利用技術. 5.シーワン化学原料としての天然ガス (2008)
  • Author(s): 杉義弘, 浜田秀昭
  • Publisher: 天然ガス資源とその応用技術、鈴木修市、岡田治編
• [Book] ゼオライト, 環境対応型セラミックスの技術と応用 (2008)
  • Author(s): 小村賢一, 杉義弘
  • Total Pages: 400
  • Publisher: シーエムシー
• [Book] 天然ガス資源とその応用技術 (2008)
  • Author(s): 杉義弘, 浜田秀昭
  • Total Pages: 350
  • Publisher: シーエムシー
• [Book] 第2章環境対応型ハイブリッド材料 (2007)
  • Author(s): 小村賢一, 杉義弘
  • Publisher: ゼオライト、環境対応型セラミックスの技術と応用, 野上正行編, 第2編シーエムシー出版
• [Patent(Industrial Property Rights)] 新規メソポーラスアルミノシリケートの製造法 (2008)
  • Inventor(s): 杉義弘, C.Ventakesan, 小村賢一
  • Industrial Property Rights Holder: 触媒化成、杉義弘
  • Industrial Property Number: 2008-335392
  • Filing Date: 2008-12-27
• [Patent(Industrial Property Rights)] カルボン酸ステロイドエステルの製造方法 (2008)
  • Inventor(s): 杉義弘, 小村賢一, 尾崎彰禎, 岸田徹, 家田昇
  • Industrial Property Rights Holder: 日生化学工業所
  • Industrial Property Number: 2008-212072
  • Filing Date: 2008-08-20
• [Patent(Industrial Property Rights)] カルボン酸エステルの製造方法およびエステル化触媒 (2008)
  • Inventor(s): 杉義弘, 小村賢一, K. Mantri
  • Industrial Property Rights Holder: 岐阜大学
  • Filing Date: 2008-03-14
• [Patent(Industrial Property Rights)] カルボン酸ステロイドエステルの製造方法 (2008)
  • Inventor(s): 杉義弘小村賢一尾崎彰禎岸田徹家田昇
  • Industrial Property Rights Holder: 日生化学工業所
  • Industrial Property Number: 2008-212072
  • Filing Date: 2008-08-20
• [Patent(Industrial Property Rights)] 新規メソポーラスアルミノシリゲートの製造法 (2008)
  • Inventor(s): 杉義弘, C. Ventakesa小村賢一
  • Industrial Property Rights Holder: 触媒化成, 杉義弘
  • Industrial Property Number: 2008-335392
  • Acquisition Date: 2008-12-27
• [Patent(Industrial Property Rights)] 新規なメソポーラスアルミノシリケートおよびその合成方法 (2007)
  • Inventor(s): 杉義弘, 小村賢一, S. C. Laha, C. Venkatesan, 小柳嗣雄
  • Industrial Property Rights Holder: 触媒化成, 杉義弘
  • Industrial Property Number: 2007-319912
  • Filing Date: 2007-12-11
• [Patent(Industrial Property Rights)] アミド化触媒、それを用いたカルボン酸アミドの製造方法及びそれを用いたペプチドの製造方法 (2007)
  • Inventor(s): 杉義弘, 小村賢一, 寺田佑嗣
  • Industrial Property Rights Holder: 岐阜大学
  • Industrial Property Number: 2007-291541
  • Filing Date: 2007-11-09
• [Patent(Industrial Property Rights)] 芳香族カルボン酸エステルの製造方法 (2007)
  • Inventor(s): 杉義弘, 窪田好浩, 三輪實, C. Ramesh
  • Industrial Property Rights Holder: 化学技術振興機構
  • Filing Date: 2007-08-31
• [Patent(Industrial Property Rights)] ポリアリレートの製造方法 (2007)
  • Inventor(s): 杉義弘, 窪田好浩, 三輪實, C. Ramesh
  • Industrial Property Rights Holder: 化学技術振興機構
  • Filing Date: 2007-07-27
• [Patent(Industrial Property Rights)] 芳香族カルボン酸エステルの製造方法 (2007)
  • Inventor(s): 杉義弘, 窪田好浩, 三輪實, C. Ramesh
  • Industrial Property Rights Holder: 化学技術振興機構
  • Filing Date: 2007-06-29
• [Patent(Industrial Property Rights)] アミド化触媒、それを用いたカルボン酸アミドの製造方法及びそれを用いたペプチドの製造方法 (2007)
  • Inventor(s): 杉 義弘, 小村賢一, 寺田裕嗣
  • Industrial Property Rights Holder: 岐阜大学長
  • Industrial Property Number: 2007-291541
  • Filing Date: 2007-11-09
• [Patent(Industrial Property Rights)] 新規なゼオライト骨格を有するメソポーラスアルミノシリケートおよびその製造方法 (2007)
  • Inventor(s): 杉 義弘, 小村賢一, S. C. Laha., C. Venkatesan, 小柳嗣雄
  • Industrial Property Rights Holder: 触媒化成杉 義弘
  • Industrial Property Number: 2007-319912
  • Filing Date: 2007-12-21