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Studies on Confined Nanospace and Water by Microscopic Infrared Spectroscopy

Research Project

Project/Area Number 19340088
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Condensed matter physics II
Research InstitutionTohoku University

Principal Investigator

MATSUI Hiroshi  Tohoku University, 大学院・理学研究科, 准教授 (30275292)

Co-Investigator(Kenkyū-buntansha) 石川 桃子  東北大学, 大学院・理学研究科, 教育研究支援者 (40374912)
Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Fiscal Year 2009: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2008: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2007: ¥12,220,000 (Direct Cost: ¥9,400,000、Indirect Cost: ¥2,820,000)
Keywords水 / 閉ざされた水 / ナノ空間 / 水和 / プロトン伝導 / DNA / ゼオライト / 水ナノチューブ / 赤外分光 / ダイナミックス
Research Abstract

Employing the microscopic infrared spectroscopy as functions of temperature, relative humidity and pressure, we clarified the structural properties and the coordination of confined water in the dry DNA, the interlayer spaces and the nanochannel frameworks. Furthermore the quasi one-dimensional high-proton conduction was successfully detected in water nanotube. The present results have interdisciplinary importance for the communities studying water and proton conductions.

Report

(4 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (36 results)

All 2010 2009 2008 2007 Other

All Journal Article (12 results) (of which Peer Reviewed: 12 results) Presentation (20 results) Remarks (4 results)

  • [Journal Article] Stron correlations in highly electron-doped complex Zn(II)-DNA2010

    • Author(s)
      A. Omeruzu, B. Anzelak, I. Tuel, J. Strancar, A. Potocnik, D. Arcon, I. Arcon, D. Mihailovic, H. Matsui
    • Journal Title

      Phys.Rev.Lett. 104(掲載決定)

      Pages: 4-4

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hydration states and metallic intercalation effects in dry DNA2010

    • Author(s)
      H. Matsui, M. Nagatori, H. Sakamoto, K. Mizoguchi, N. Toyota
    • Journal Title

      J.Physc.Chem.Solids 71巻

      Pages: 440-443

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hydration states and metallic intercalation effects in dry DNA2010

    • Author(s)
      H.Matsui
    • Journal Title

      Journal of Physics and Chemistry of Solids 71

      Pages: 440-443

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Two-Dimensionally Confined Water in between MnO_2 Layers of Na-Birnessite2009

    • Author(s)
      H. Matsui, J. Ju, T. Odaira, N. Toyota
    • Journal Title

      J.Phys.Soc.Jpn. 78巻

    • NAID

      10025962934

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Infrared Spectroscopic Studies on Incorporating the Effect of Metallic Ions into a M-DNA Double Helix2009

    • Author(s)
      H. Matsui, N. Toyota, M. Nagatori, H. Sakamoto, K. Mizoguchi
    • Journal Title

      Phys.Rev.B 79巻

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Two-dimensionally confined water in between MnO_2 layers of Na-birnessite2009

    • Author(s)
      H.Matsui
    • Journal Title

      Journal of Physical Society of Japan 78

      Pages: 74801-74801

    • NAID

      10025962934

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Infrared spectroscopic studies on incorporating the effect of metallic ions into a M-DNA double helix2009

    • Author(s)
      H.Matsui
    • Journal Title

      Physical Review B 79

      Pages: 1235201-1235201

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydration Effects on the Microwave Dielectricity in Dry Poly (dA)-Poly (dT) DNA2008

    • Author(s)
      A. Hojo, H. Matsui, K. Iwamoto, T. Yanagimachi, H. Abdrurakhan, M. Taniguchi, T. Kawai, N. Toyota
    • Journal Title

      J.Phys.Soc.Jpn. 77巻

    • NAID

      110006649432

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hydration Effects on the Microwave Dielectricity in Dry Poly(dA9-Poly(dT) DNA2008

    • Author(s)
      A. Hojo
    • Journal Title

      J. Phys. Soc. Jpn. 77

      Pages: 44802-44802

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydration Effects on the Microwave Dielectricity in Dry Poly(dA)-Poly(dT)DNA2008

    • Author(s)
      A. Hojo
    • Journal Title

      J. Phys. Soc. Jpn. 77

      Pages: 44802-44802

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Infrared Spectroscopy on Poly (dG)-Poly (dC) DNA at Low Hydration2007

    • Author(s)
      H. Abdurakhan, K. Tajiri, H. Yokoi, N. Kuroda, H. Matsui, T. Yanagimachi, M. Taniguchi, T. Kawai, N. Toyota
    • Journal Title

      J.Phys.Soc.Jpn. 76巻

    • NAID

      110006203512

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Infrared Spectroscopy on Poly(dG)-Poly(dC) DNA at Low Hydration2007

    • Author(s)
      H. Abdurakhman
    • Journal Title

      J. Phys. Soc. Jpn. 76

      Pages: 24009-24009

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] Naバーナサイトにおける閉ざされた水の構造2010

    • Author(s)
      松井広志, Jing Ju, 大平倫裕, 豊田直樹
    • Organizer
      日本物理学会第65回年次大会
    • Place of Presentation
      岡山大学
    • Year and Date
      2010-03-22
    • Related Report
      2009 Final Research Report
  • [Presentation] Naバーナサイトにおける閉ざされた水の構造2010

    • Author(s)
      松井広志
    • Organizer
      日本物理学会年次大会
    • Place of Presentation
      岡山
    • Year and Date
      2010-03-22
    • Related Report
      2009 Annual Research Report
  • [Presentation] I型クラスレートEu_8Ga_<16>Ge_<30>のラジオ波帯電気伝導2010

    • Author(s)
      岩本慧, 櫛引俊介, 松井広志, 森龍也, 本多裕典, 豊田直樹
    • Organizer
      日本物理学会第65回年次大会
    • Place of Presentation
      岡山大学
    • Year and Date
      2010-03-21
    • Related Report
      2009 Final Research Report
  • [Presentation] Electrodynamics and Hydration States of Confined Water in Dry DNA and Na-Birnessite2009

    • Author(s)
      H. Matsui
    • Organizer
      Horiba-ISSP international Symposium (ISSP-11)
    • Place of Presentation
      Chiba, Japan
    • Year and Date
      2009-10-13
    • Related Report
      2009 Final Research Report
  • [Presentation] Electrodynamics and Hydration States of Confined Water in Dry DNA and Na-Birnessite2009

    • Author(s)
      松井広志
    • Organizer
      Horiba-ISSP International Symposium(ISSP-11)
    • Place of Presentation
      千葉
    • Year and Date
      2009-10-13
    • Related Report
      2009 Annual Research Report
  • [Presentation] Intercalation Effects of Metallic Ions in Dry DNA2009

    • Author(s)
      H. Matsui
    • Organizer
      15th International Symposium on Intercalation Compounds
    • Place of Presentation
      Tsinghua University, Beijing, China
    • Year and Date
      2009-05-15
    • Related Report
      2009 Final Research Report
  • [Presentation] Hydration states and metallic intercalation effects in dry DNA2009

    • Author(s)
      松井広志
    • Organizer
      International Symposium on Intercalation Compounds
    • Place of Presentation
      北京、中国
    • Year and Date
      2009-05-15
    • Related Report
      2009 Annual Research Report
  • [Presentation] 金属イオンをドープしたDNAの赤外分光測定2009

    • Author(s)
      松井広志, 永鳥舞, 坂本浩一, 溝口憲治, 豊田直樹
    • Organizer
      日本物理学会第64回年次大会
    • Place of Presentation
      立教大学
    • Year and Date
      2009-03-27
    • Related Report
      2009 Final Research Report
  • [Presentation] 金属をドープしたDNAの電子状態の温度依存性III2009

    • Author(s)
      永鳥舞, 溝口憲治, 坂本浩一, 尾島雅也, 圓谷淳, 柴田譲, 松井広志
    • Organizer
      日本物理学会第64回年次大会
    • Place of Presentation
      立教大学
    • Year and Date
      2009-03-27
    • Related Report
      2009 Final Research Report
  • [Presentation] 金属イオンをドープしたDNAの赤外分光測定2009

    • Author(s)
      松井広志
    • Organizer
      日本物理学会年次大会
    • Place of Presentation
      立教大学
    • Year and Date
      2009-03-27
    • Related Report
      2008 Annual Research Report
  • [Presentation] 金属をドープしたDNAの電子状態の湿度依存性III2009

    • Author(s)
      永鳥舞
    • Organizer
      日本物理学会年次大会
    • Place of Presentation
      立教大学
    • Year and Date
      2009-03-27
    • Related Report
      2008 Annual Research Report
  • [Presentation] I型クラスレートEu_8Ga_<16>Sn_<30>のラジオ波帯電気伝導2009

    • Author(s)
      岩本慧
    • Organizer
      日本物理学会年次大会
    • Place of Presentation
      岡山
    • Year and Date
      2009-03-21
    • Related Report
      2009 Annual Research Report
  • [Presentation] ハサヌディン、ヨウ素ドープした乾燥DNAの赤外分光2008

    • Author(s)
      岩本慧, 松井広志
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      岩手大学
    • Year and Date
      2008-09-20
    • Related Report
      2009 Final Research Report
  • [Presentation] ヨウ素ドープした乾燥DNAの赤外分光2008

    • Author(s)
      岩本慧、松井広志
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      岩手大学
    • Year and Date
      2008-09-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] Microwave Dielectric Response in Dry Poly (dA)-Poly (dT) DNA2008

    • Author(s)
      H. Matsui
    • Organizer
      International Conference on Science and Technology of Synthetic Metals (ICSM2008)
    • Place of Presentation
      Porto de Galinhas, Brazil
    • Year and Date
      2008-07-10
    • Related Report
      2009 Final Research Report
  • [Presentation] Microwave Dielectric Response in Dry Poly(dA)-Poly(dT) DNA2008

    • Author(s)
      Hiroshi Matsui
    • Organizer
      International Conference on Science and Technology of Synthetic Metals
    • Place of Presentation
      Porto de Galinhas, Brazil
    • Year and Date
      2008-07-10
    • Related Report
      2008 Annual Research Report
  • [Presentation] 乾燥DNAにおける水和殻のマイクロ波応答2007

    • Author(s)
      松井広志, 北條淳征
    • Organizer
      日本物理学会第62回年次大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2007-09-21
    • Related Report
      2009 Final Research Report
  • [Presentation] 乾燥DNAのヨウ素ドープ効果2007

    • Author(s)
      岩本慧, 松井広志
    • Organizer
      日本物理学会第62回年次大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2007-09-21
    • Related Report
      2009 Final Research Report
  • [Presentation] 乾燥DNAにおける水和殻のマイクロ波応答2007

    • Author(s)
      松井 広志
    • Organizer
      日本物理学会 第62回年次大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2007-09-21
    • Related Report
      2007 Annual Research Report
  • [Presentation] 乾燥DNAのヨウ素ドープ効果2007

    • Author(s)
      松井 広志
    • Organizer
      日本物理学会 第62回年次大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2007-09-21
    • Related Report
      2007 Annual Research Report
  • [Remarks] ホームページ等

    • URL

      http://ldp.phys.tohoku.ac.jp

    • Related Report
      2009 Final Research Report
  • [Remarks]

    • URL

      http://ldp.phys.tohoku.ac.jp/

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://ldp.phys.tohoku.ac.jp/

    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://ldp.phys.tohoku.ac.jp/

    • Related Report
      2007 Annual Research Report

URL: 

Published: 2007-04-01   Modified: 2020-05-15  

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