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Search for unusual magnetic, electric and dielectric phenomena with contributions of s-electrons

Research Project

Project/Area Number 19340098
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Condensed matter physics II
Research InstitutionKyoto University

Principal Investigator

AZUMA Masaki  Kyoto University, 化学研究所, 准教授 (40273510)

Co-Investigator(Kenkyū-buntansha) SHIMAKAWA Yuichi  京都大学, 化学研究所, 教授 (20372550)
SAITO Tkashi  京都大学, 化学研究所, 助教 (40378857)
MIZUMAKI Masaichiro  財)高輝度光科学研究センター, 利用研究促進部門動的構造クセループ, 副主任研究員 (60360830)
Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥18,330,000 (Direct Cost: ¥14,100,000、Indirect Cost: ¥4,230,000)
Fiscal Year 2009: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2008: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2007: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Keywords強相関電子系 / 電子・電気材料 / 放射線・X線・粒子線 / 物性実験 / 放射線・X線・粒子
Research Abstract

6s electrons of Bi greatly act on the crystallographic structure and the banded structure of a compound, and affect the electrical property. We searched for unusual magnetic, electrical and the dielectric properties in the perovskite compound where such Bi ion was arranged on A-site. Several peculiar phenomena such as absence of the long-range magnetic order in Bi_3Mn_4O_<12>(NO_3), an insulator to metal transition accompanied with a negative thermal expansion in Bi_<0.95>La_<0.05>NiO_3 and the enhancement of the piezoelectric property in BiFe_<1-x>Co_xO_3 were found.

Report

(4 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (39 results)

All 2010 2009 2008 2007

All Journal Article (19 results) (of which Peer Reviewed: 19 results) Presentation (15 results) Patent(Industrial Property Rights) (5 results)

  • [Journal Article] Crystal Structures and Electric Properties of (1-x)BiFe03-xBiCoO3 Thin Films Prepared by Chemical Solution Deposition2010

    • Author(s)
      Y. Nakamura, M. Kawai, M. Azuma, Y. Shimakawa
    • Journal Title

      Jpn. J. Appl. Phys. 49

      Pages: 51501-51501

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Structures and Electric Properties of (1-x) BiFeO3-xBiCoO3 Thin Films Prepared by Chemical Solution Deposition2010

    • Author(s)
      Y.Nakamura, M.Kawai, M.Azuma, Y.Shimakawa
    • Journal Title

      Jpn.J.Appl.Phys. 49(掲載決定)

    • NAID

      210000068432

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Direct observation of the pressure-induced charge redistribution in BiNiO3 by x-ray absorption spectroscopy2009

    • Author(s)
      Mizumaki, M., N. Ishimatsu, N. Kawamura, M. Azuma, Y. Shimakawa, M. Takano, T. Uozumi
    • Journal Title

      Phys. Rev. B 80

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Crystal Structure and Magnetic Properties of Bi3Mn4O12(NO3) Oxynitrate Comprising S=3/2 Honeycomb Lattice2009

    • Author(s)
      O. Smirnova, M. Azuma, N. Kumada, Y. Kusano, M. Matsuda, Y. Shimakawa, T. Takei, Y. Yonesaki, N. Kinomura
    • Journal Title

      J. Am. Chem. Soc. 131

      Pages: 8313-8317

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Temperature-induced A-B intersite charge transfer in an A-site-ordered LaCu3Fe4O12 perovskite2009

    • Author(s)
      Y.W. Long, N. Hayashi, T. Saito, M. Azuma, S. Muranaka, Y. Shimakawa
    • Journal Title

      Nature 458

      Pages: 60-63

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Physical Properties of Double Perovskite Pb2FeReO62009

    • Author(s)
      K. Nishimura, M. Azuma, S. Hirai, M. Takano, Y. Shimakawa
    • Journal Title

      Inorg. Chem 48

      Pages: 5962-5966

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Crystal Structure, and Magnetic Properties of Bi3Mn4O12 (NO3) Oxynitrate Comprising S=3/2 Honeycomb Lattice2009

    • Author(s)
      O Smirnova, M.Azuma, N.Kumada, Y.Kusano, M.Matsuda, Y.Shimakawa, T.Takei, Y.Yonesaki, N.Kinomura
    • Journal Title

      J.Am.Chem.Soc. 131

      Pages: 8313-8317

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Direct observation of the pressure-induced charge redistribution in BiNiO3 by x-ray absorption spectroscopy2009

    • Author(s)
      M.Mizumaki, N.Ishimatsu, N.Kawamura, M.Azuma, Y.Shimakawa, M.Takano, T.Uozumi
    • Journal Title

      Phys.Rev.B 80

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pressure-Induced Transformation of 6H Hexagonal to 3C Perovskite Structure in PbMnO32009

    • Author(s)
      K.Oka, M.Azuma, S.Hirai, AA.Belik, H.Kojitani, M.Akaogi, M.Takano, Y.Shimakawa
    • Journal Title

      Inorg.Chem. 48

      Pages: 2285-2288

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrothermal Synthesis of a New Double Perovskite-Type Bismuthate, (Ba0.75K0.14H0.11) BiO3・Nh2o2009

    • Author(s)
      H.Jiang, N.Kumada, Y.Yonesaki, T.Takei, N.Kinomura, M.Yashima, M.Azuma, K.Oka, Y.Shimakawa
    • Journal Title

      Jpn.J.Appl.Phys. 48

    • NAID

      210000066144

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic ground-state of perovskite PbVO3 with large tetragonal distortion2008

    • Author(s)
      K. Oka, I. Yamada, M. Azuma, S. Takeshita, K.H. Satoh, A. Koda, R. Kadono, M. Takano, Y. Shimakawa
    • Journal Title

      Inorg. Chem. 47

      Pages: 7355-7359

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Charge and magnetic orderings in the triangular-lattice antiferromagnet InFe2O42008

    • Author(s)
      K. Oka, M. Azuma, N. Hayashi, S. Muranaka, Y. Narumi, K. Kindo, S. Ayukawa, M. Kato, Y. Koike, Y. Shimakawa, M. Takano
    • Journal Title

      J. Phys. Soc. Jpn. 77

      Pages: 64803-64803

    • NAID

      130005436482

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Rhombohedral-tetragonal phase boundary with high curie temperature in 1-xBiCoO_3-xBiFeO_3 solid solution2008

    • Author(s)
      M. Azuma, et al.
    • Journal Title

      Jpn. J. App. Phys 47

      Pages: 7579-7581

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic ground-state of perovskite PbV0_3 with large tetragonal distortion2008

    • Author(s)
      K. Oka, et al.
    • Journal Title

      Inorg. Chem. 47

      Pages: 7355-7359

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Charge and magnetic orderings in the triangular-lattice antiferromagnet In Fe_2O_42008

    • Author(s)
      K. Oka, et al.
    • Journal Title

      J. Phys. Soc. Jpn. 77

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pressure-Induced Intermetallic Valence Transition in BiNiO32007

    • Author(s)
      M. Azuma, S. Carlsson, J. Rodgers, M.G. Tucker, M. Tsujimoto, S. Ishiwata, S. Isoda, Y. Shimakawa, M. Takano, J.P. Attfield
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 11443-114436

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Pressure-Induced Intermetallic Valence Transition in BiNiO_32007

    • Author(s)
      M. Azuma, et. al.
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 14433-14436

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Quasi-particle interference and superconducting gap in a high-temperature superconductor Ca_<2-χ>Na_χCuO_2Cl_22007

    • Author(s)
      T. Hanaguri, et. al.
    • Journal Title

      Nature Physics 3

      Pages: 865-871

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Temperature-dependent photoemission and x-ray absorption studies of the metal-insulator transition in Bi_<1-χ>La_χNiO_32007

    • Author(s)
      H. Wadati, et. al.
    • Journal Title

      Phys. Rev. B 76

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] Frustrated S=3/2 Honeycomb Antiferromagnet Bi3Mn4O12(NO3), International Conference on Magnetism2009

    • Author(s)
      M. Azuma
    • Organizer
      Conference on Magnetism, Superconductivity and Phase Transitions in Novel and Complex Materials 2009
    • Place of Presentation
      カルカッタ、インド
    • Year and Date
      2009-11-12
    • Related Report
      2009 Final Research Report
  • [Presentation] Frustrated S=3/2 Honeycomb Antiferromagnet Bi3Mn4O12 (NO3)2009

    • Author(s)
      東正樹
    • Organizer
      6th International Conference on Magnetism, Superconductivity and Phase Transitions in Novel and Complex Materials
    • Place of Presentation
      カルカッタ、インド
    • Year and Date
      2009-11-12
    • Related Report
      2009 Annual Research Report
  • [Presentation] 巨大な正方晶歪みを持つPbTiO3型ペロブスカイトPbVO3とBiCoO32009

    • Author(s)
      東正樹
    • Organizer
      日本物理学会2009年秋季大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-09-26
    • Related Report
      2009 Final Research Report
  • [Presentation] 巨大な正方晶歪みを持つPbTiO3型ペロブスカイトPbVO3とBiCoO32009

    • Author(s)
      東正樹
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-09-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] 巨大な体積変化を伴うBiCoO3の圧力誘起スピン状態転移2009

    • Author(s)
      岡研吾
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-09-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] Pressure-Induced Intermetallic Valence Transition in BiNiO32009

    • Author(s)
      東正樹
    • Organizer
      International Conference on High Pressure Science and Technology (AIRAPT-22 & HPCJ-50)
    • Place of Presentation
      東京
    • Year and Date
      2009-07-31
    • Related Report
      2009 Annual Research Report
  • [Presentation] Magnetic ground state of PbVO3 and origin of the large tetragonal distortion2009

    • Author(s)
      岡研吾
    • Organizer
      International Conference on High Pressure Science and Technology (AIRAPT-22 & HPCJ-50)
    • Place of Presentation
      東京
    • Year and Date
      2009-07-31
    • Related Report
      2009 Annual Research Report
  • [Presentation] 巨大な正方晶歪みを持つPbTiO3型ペロブスカイトPbVO3とBiCoO32008

    • Author(s)
      東正樹
    • Organizer
      日本セラミックス協会第21回秋期シンポジウム
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2008-09-18
    • Related Report
      2009 Final Research Report
  • [Presentation] PbVO3 and BiCoO3 with large tetragonal distortions2008

    • Author(s)
      M. Azuma
    • Organizer
      7th Korea-Japan Conference on Ferroelectricity
    • Place of Presentation
      済州国立大学韓国
    • Year and Date
      2008-08-08
    • Related Report
      2009 Final Research Report
  • [Presentation] Charge and Orbital Orderings in Some New Oxides2008

    • Author(s)
      M. Azuma
    • Organizer
      UC Santa Barbara Workshop on Frontiers in Complex Oxide
    • Place of Presentation
      カリフォルニア大学サンタバーバラ校
    • Year and Date
      2008-07-07
    • Related Report
      2009 Final Research Report
  • [Presentation] Charge and Orbital Orderings in Some New Oxides2008

    • Author(s)
      M. Azuma
    • Organizer
      UC Santa Barbara Workshop on Frontiers in Complex Oxides
    • Place of Presentation
      カリフォルニア大学サンタバーバラ校
    • Related Report
      2008 Annual Research Report
  • [Presentation] 新しい電荷不均化系の高圧合成とその圧力下物性2007

    • Author(s)
      東正樹
    • Organizer
      日本物理学会第62回年次大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2007-09-23
    • Related Report
      2009 Final Research Report
  • [Presentation] ビスマスの特性を活かしたペロブスカイト化合物の磁性・誘電性・電気伝導制御2007

    • Author(s)
      東正樹
    • Organizer
      日本セラミックス協会第20回秋期シンポジウム
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2007-09-13
    • Related Report
      2009 Final Research Report
  • [Presentation] High Pressure Synthesis of Functional Transition Metal Oxides2007

    • Author(s)
      M. Azuma
    • Organizer
      ICMR Workshou on Functional Oxide Material
    • Place of Presentation
      カリフォルニア大学サンタバーバラ校
    • Year and Date
      2007-08-22
    • Related Report
      2009 Final Research Report
  • [Presentation] High Pressure Synthesis of Functional Transition Metal Oxides2007

    • Author(s)
      M. Azuma
    • Organizer
      ICMR Workshop on Functional Oxide Materials
    • Place of Presentation
      カリフォルニア大学サンタバーバラ校
    • Year and Date
      2007-08-22
    • Related Report
      2007 Annual Research Report
  • [Patent(Industrial Property Rights)] 圧電薄膜、圧電素子および圧電素子の製造方法2010

    • Inventor(s)
      久保田純, 高嶋健二, 東正樹, 中村嘉孝, 島川祐一, 飯島高志, 李鳳淵
    • Industrial Property Rights Holder
      キヤノン株式会社,国立大学法人京都大学,独立行政法人産業技術総合研究所
    • Industrial Property Number
      2010-045907
    • Filing Date
      2010-03-11
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] 圧電薄膜、圧電素子、圧電素子の製造方法、液体吐出ヘッドおよび超音波モータ2010

    • Inventor(s)
      久保田純, 武田憲一, 林潤平, 島田幹夫, 島川祐一、東正樹, 中村嘉孝, 河合正徳
    • Industrial Property Rights Holder
      キヤノン株式会社,国立大学法人京都大学
    • Industrial Property Number
      2010-045907
    • Filing Date
      2010-03-02
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] 圧電薄膜, 圧電素子, 圧電素子の製造方法, 液体吐出ヘッドおよび超音波モータ2010

    • Inventor(s)
      東正樹, 中村嘉孝, 他8名
    • Industrial Property Rights Holder
      キヤノン株式会社, 京都大学
    • Industrial Property Number
      2010-045907
    • Filing Date
      2010-03-02
    • Related Report
      2009 Annual Research Report
  • [Patent(Industrial Property Rights)] 金属酸化物および圧電材料2009

    • Inventor(s)
      久保田純, 三浦薫, 伊福敏博, 林潤平, 東正樹, スミルノワオルガアレキサンドロワ, 舟窪浩, 内田寛, 熊田伸弘, 和田智志, 飯島高志, 岡村総一郎
    • Industrial Property Rights Holder
      キヤノン株式会社、国立大学法人京都大学、国立大学法人東京工業大学、学校法人上智学院、国立大学法人山梨大学、独立行政法人産業技術総合研究所、学校法人東京理科大学
    • Patent Publication Number
      2010-053024
    • Filing Date
      2009-07-24
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] 正方晶BiCoO_3及びその製造方法2008

    • Inventor(s)
      東 正樹, 新高誠司
    • Industrial Property Rights Holder
      科学技術振興機構
    • Acquisition Date
      2008-03-14
    • Related Report
      2007 Annual Research Report

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Published: 2007-04-01   Modified: 2020-05-15  

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