Study of mantle evolution and development of Hf isotope analysis at ng/g levels

• Project/Area Number: 19340162
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Petrology/Mineralogy/Science of ore deposit
• Research Institution: Okayama University
• Principal Investigator: MAKISHIMA Akio Okayama University, 地球物質科学研究センター, 教授 (70219301)
• Co-Investigator(Kenkyū-buntansha): 中村 栄三 岡山大学, 地球物質科学研究センター, 教授 (80201672)
• Project Period (FY): 2007 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥14,950,000 (Direct Cost: ¥11,500,000、Indirect Cost: ¥3,450,000); Fiscal Year 2010: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000); Fiscal Year 2009: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000); Fiscal Year 2008: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000); Fiscal Year 2007: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
• Keywords: Lu-Hf,同位体 / 幌満 / かんらん岩体 / 成因 / 鉛同位体比 / Lu-Hf / 同位体 / マントル / 微量元素 / ハフニウム / 同位体比 / かんらん岩 / チタン / HFSE / MC-ICP-MS / 幌満かんらん岩体 / 鉛同位体 / ハフニウム同位体 / ルテチウム / 共沈 / 放射壊変

Research Abstract

We analyzed the origin and evolution of the Horoman peridotite massif based on major and trace elements and Hf-Nd-Pb-Sr isotope systematics. We identified at least four events in the evolution of the Horoman peridotite. In addition, we found the least radiogenic lead from the Horoman peridotite so far. Furthermore, we have developed the Hf isotope analytical method at ng/g levels.

Research Products

• [Journal Article] (2010)
  • Author(s): Malaviarachchi, S.P.K., Makishima, A., Nakamura, E.
  • Journal Title: Journal of Petrology 51 Pages: 1417-1445
  • Peer Reviewed
• [Journal Article] (2010)
  • Author(s): Wang, Q.-Y., Makishima, A., Nakamura, E.
  • Journal Title: Geostandards and Geoanalytical Research 34 Pages: 175-183
  • Peer Reviewed
• [Journal Article] (2010)
  • Author(s): Makishima, A., Nakamura, E.
  • Journal Title: Journal of Analytical Atomic Spectrometry 25 Pages: 175-183
  • Peer Reviewed
• [Journal Article] Slab decarbonation and CO2 recycling in the Southwestern Colombian volcanic arc. (2010)
  • Author(s): Marin-Ceron, M.I., Moriguti, T., Makishima A., Nakamura, E.
  • Journal Title: Geochimica et Cosmochimca Acta Volume: 74 Pages: 1104-1121
  • Peer Reviewed
• [Journal Article] Precise determination of Cr, Mn, Fe, Co and Ni concentration by an isotope dilution-internal standardization method employing high resolution MC-ICP-MS. (2010)
  • Author(s): Makishima, A., Tamakawa, A., Yamashita, K., Nakamura, E.
  • Journal Title: Chemical Geology Volume: 274 Pages: 82-86
  • Peer Reviewed
• [Journal Article] 2010. Melt-peridotite reactions and fluid-metasomatism in the upper mantle, revealed from the geochemistry of peridotite and gabbro from the Horoman peridotite massif, Japan., 51, 1417-1445. (2010)
  • Author(s): Malaviarachchi, S.P.K., Makishima, A., Nakamura, E.
  • Journal Title: Journal of Petrology Volume: 51 Pages: 1417-1445
  • Peer Reviewed
• [Journal Article] Chromium isotope systematics of achondrites : chronology and isotopic heterogeneity of the inner solar system bodies. (2010)
  • Author(s): Yamakawa, A., Yamashita, K., Makishima, A., Nakamura, E.
  • Journal Title: The Astrophysical Journal Volume: 720 Pages: 150-154
  • Peer Reviewed
• [Journal Article] Determination of fluorine and chlorine by pyrohydrolysis and ion chromatography : comparison with alkaline fusion digestion and ion chromatography. (2010)
  • Author(s): Wang, Q.-Y., Makishima, A., Nakamura, E.
  • Journal Title: Geostandards and Geoanalytical Research Volume: 34 Pages: 175-188
  • Peer Reviewed
• [Journal Article] Precise isotopic determination of Hf and Pb at sub-nano gram levels by MC-ICPMS employing a newly designed sample cone and a pre-amplifier with a 1012 ohm register. (2010)
  • Author(s): Makishima, A., Nakamura, E.
  • Journal Title: Journal of Analytical Atomic Spectrometry Volume: 25 Pages: 1712-1716
  • Peer Reviewed
• [Journal Article] Slab decarbonation and CO_2 recycling in the Southwestern Colombian volcanic arc (2010)
  • Author(s): Marin-Ceron, M. I., Moriguti, T., Makishima, A. Nakamura, E.
  • Journal Title: Geochimica et Cosmochimca Acta 74 Pages: 1104-1121
• [Journal Article] (2009)
  • Author(s): Makishima, A., Nakamura, E.
  • Journal Title: Geostandards and Geoanalytical Research 33 Pages: 369-384
  • Peer Reviewed
• [Journal Article] (2009)
  • Author(s): Nath, B.N., Makishima, A., Noordmann, J., Tanaka, R., Nakamura, E.
  • Journal Title: Geochemical Journal 43 Pages: 207-216
  • Peer Reviewed
• [Journal Article] Precise elemental and isotopic analyses in silicate samples employing ICP-MS : Application of HF solution and analytical techniques (2009)
  • Author(s): Makishima, A., Tanaka, R. Nakamura, E.
  • Journal Title: Analytical Sciences 25 Pages: 1181-1187
• [Journal Article] Comprehensive analysis for major, minor and trace element contents and Sr-Nd-Pb-Hf isotope ratios in sediment reference materials, JSd-1 and MAG-1 (2009)
  • Author(s): Nath, B. N., Makishima, A., Noordmann, J., Tanaka, R. Nakamura, E.
  • Journal Title: Geochemical Journal 43 Pages: 207-216
  • NAID: 10026141523
• [Journal Article] Comprehensive analysis for major, minor and trace element contents and Sr-Nd-Pb-Hf isotope ratios in sediment reference materials. JSd-1 and MAG-1. (2009)
  • Author(s): Nath, B.N., Makishima, A., Noordmann, J., Tanaka, R., Nakamura, E.
  • Journal Title: Geochemical Journal 43 Pages: 207-216
  • NAID: 10026141523
  • Peer Reviewed
• [Journal Article] 2009. Accumulation of radium in ferruginous protein bodies formed in lung tissue : association of resulting radiation hotspots with malignant mesothelioma and other malignancies. (2009)
  • Author(s): Nakamura, E., Makishima, A., Hagino, K., Okabe, K.
  • Journal Title: Proceedings of the Japan Academy. Ser. B. 85 Pages: 229-239
  • Peer Reviewed
• [Journal Article] Determination of Ge. As, Se and Te in silicate samples using isotope dilution-internal standardization octopole reaction cell ICP-QMS by normal sample nebulization. (2009)
  • Author(s): Makishima, A., Nakamura, E.
  • Journal Title: Geostandards and Geoanalytical Research 33 Pages: 369-389
  • Peer Reviewed
• [Journal Article] Precise elemental and isotopic analyses in silicate samples employing ICP-MS : Application of HF solution and analytical techniques. (2009)
  • Author(s): Makishima, A., Tanaka. R., Nakamura. E.
  • Journal Title: Analytical Sciences 25 Pages: 1181-1187
  • Peer Reviewed
• [Journal Article] Chemical separation and mass spectrometry of Cr. Fe. Ni. Zn and Cu in terrestrial and extraterrestrial materials using Thermal Ionization Mass Spectrometry. 81. 9787-9794. (2009)
  • Author(s): Yamakawa, A., Yamashita, K., Makishima, A., Nakamura, E.
  • Journal Title: Analytical Chemistry 81 Pages: 9787-9794
  • Peer Reviewed
• [Journal Article] (2008)
  • Author(s): Makishima, A., Nakamura, E.
  • Journal Title: Geochemical Journal 42 Pages: 199-206
  • Peer Reviewed
• [Journal Article] (2008)
  • Author(s): Makishima, A., Nath, B.N., Nakamura, E.
  • Journal Title: Geochemical Journal 42 Pages: 237-246
  • Peer Reviewed
• [Journal Article] (2008)
  • Author(s): Malaviarachchi, S.P.K., Makishima, A., Tanimoto, M., Kuritani, T., Nakamura, E.
  • Journal Title: Nature Geoscience 1 Pages: 859-863
  • Peer Reviewed
• [Journal Article] Highly unradiogenic lead isotope ratios from the Horoman peridotite in Japan (2008)
  • Author(s): Malaviarachchi, S. P. K., Makishima, A., Tanimoto, M., Kuritani, T. Nakamura, E.
  • Journal Title: Nature Geoscience 1 Pages: 859-863
• [Journal Article] Multiple pulses of the mantle plume : evidence from Tertiary Icelandic lavas (2008)
  • Author(s): Kitagawa, A., Kobayashi, K., Makishima, A. Nakamura, E.
  • Journal Title: Journal of Petrology 49 Pages: 1365-1396
• [Journal Article] New preconcentration technique of Zr, Nb, Mo, Hf, Ta and W employing coprecipitation with Ti compounds : its application to Lu-Hf system and sequential Pb-Sr-Nd-Sm separation (2008)
  • Author(s): Makishima, A. Nakamura, E.
  • Journal Title: Geochemical Journal 42 Pages: 199-206
  • NAID: 10021093378
• [Journal Article] Hawaiian double volcanic chain triggered by an episodic involvement of recycled material : Constraints from temporal Sr-Nd-Hf-Pb isotopic trend of the Loa-type volcanoes (2008)
  • Author(s): Tanaka, R., Makishima, A., Nakamura, E.
  • Journal Title: Earth and Planetary Science Letters 265 Pages: 450-465
• [Journal Article] Hawaiian double volcanic chain triggered by an episodic involvement of recycled material : Constraints from temporal Sr-Nd-Hf-Pb isotopic trend of the Loa-type volcanoes. (2008)
  • Author(s): Tanaka, R., Makishima, A., Nakamura, E.
  • Journal Title: Earth and Planetary Science Letters 285 Pages: 450-465
  • Peer Reviewed
• [Journal Article] New preconcentration technique of Zr, Nb, Mo, Hf, Ta and W employing coprecipitation with Ti compounds : its application to Lu-Hf system and sequential Pb-Sr-Nd-Sm separation. (2008)
  • Author(s): Makishima, A., Nakamura, E.
  • Journal Title: Geochemical Journal 42 Pages: 199-208
  • NAID: 10021093378
  • Peer Reviewed
• [Journal Article] Highly unradiogenic lead isotope ratios from the Horoman peridotite in Japan. (2008)
  • Author(s): Malaviarachchi. S. P. K., Makishima, A., Tanimoto. M., Kuritani. T., Nakamura E.
  • Journal Title: Nature Geoscience 1 Pages: 859-863
  • Peer Reviewed
• [Journal Article] New sequential separation procedure for Sr. Nd and Pb isotope ratio measurement in geological material using MC-ICP-MS and TIMS. (2008)
  • Author(s): Makishima, A., Nath, B. N., Nakamura, E.
  • Journal Title: Geochemical Journal 42 Pages: 237-246
  • NAID: 10021093518
  • Peer Reviewed
• [Journal Article] Multiple pulses of the mantle plume : evidence from Tertiary Icelandic lavas. (2008)
  • Author(s): Kitagawa, A., Kobayashi, K., Makishima, A., Nakamura, E.
  • Journal Title: Journal of Petrology 49 Pages: 1365-1398
  • Peer Reviewed
• [Journal Article] Precise measurement of 228Ra/226Ra for 226Ra determination employing total integration and simultaneous 228Th correction by multicollector ICP-MS using multiple ion counters. 23, 1102-1107 (2008)
  • Author(s): Makishima. A., Chekol, T. A., Nakamura, E.
  • Journal Title: Journal of Analytical Atomic Spectrometry 23 Pages: 1102-1107
  • Peer Reviewed
• [Journal Article] Hawaiian double volcanic chain triggered by an episodic involvement of recycled material: Constraints from temporal Sr-Nd-Hf-Pb isotopic trend of the Loa-type volcanoes. (2008)
  • Author(s): Tanaka, R., Makishima, A. and Nakamura, E.
  • Journal Title: Earth and Planetary Science Letters 265 Pages: 450-465
  • Peer Reviewed
• [Journal Article] (2007)
  • Author(s): Lu, Y.H., Makishima A., Nakamura, E.
  • Journal Title: Chemical Geology 236 Pages: 13-26
  • Peer Reviewed
• [Journal Article] (2007)
  • Author(s): Lu, Y.H., Makishima A., Nakamura, E.
  • Journal Title: Journal of Analytical Atomic Spectrometry 22 Pages: 69-76
  • Peer Reviewed
• [Journal Article] (2007)
  • Author(s): Makishima, A., Nath, B.N., Nakamura, E.
  • Journal Title: Journal of Analytical Atomic Spectrometry 22 Pages: 407-410
  • Peer Reviewed
• [Journal Article] Ancient recycled crust beneath the Ontong Java Plateau : isotopic evidence from the garnet clinopyroxenite xenoliths, Malaita, Solomon Islands (2007)
  • Author(s): Ishikawa, A., Kuritani, T., Makishima, A. Nakamura, E.
  • Journal Title: Earth and Planetary Science Letters 259 Pages: 134-148
• [Journal Article] Precise determination of Pb isotope ratios by simple double spike MC-ICP-MS technique without T1 addition (2007)
  • Author(s): Makishima, A., Nath, B. N. Nakamura, E.
  • Journal Title: Journal of Analytical Atomic Spectrometry 22 Pages: 407-410
• [Journal Article] Ancient recycled crust beneath the Ontong Java Plateau: isotopic evidence from the garnet clinopyroxenite xenoliths, Malaita, Solomon Islands. (2007)
  • Author(s): Ishikawa, A., Kuritani, T., Makishima, A. and Nakamura, E.
  • Journal Title: Earth and Planetary Science Letters 259 Pages: 134-148
  • Peer Reviewed
• [Journal Article] Accurate determination of 234U/238U and 230Th/232Th for U-Th disequilibria studies. by MC-ICP-MS with simple bracketing. (2007)
  • Author(s): Makishima, A., Chekol, T.A. and Nakamura, E.
  • Journal Title: Journal of Analytical Atomic Spectrometry 22 Pages: 1383-1389
  • Peer Reviewed
• [Journal Article] Purification of Hf in silicate materials using extraction chromatographic resin, and its application to precise determination of 176Hf/177Hf by MC-ICP-MS with 179Hf spike. (2007)
  • Author(s): Lu, Y.H., Makishima A. and Nakamura, E.
  • Journal Title: Journal of Analytical Atomic Spectrometry 22 Pages: 69-76
  • Peer Reviewed
• [Journal Article] Precise determination of Pb isotope ratios by simple double spike MC-ICP-MS technique without Tl addition. (2007)
  • Author(s): Makishima, A., Nath, B.N. and Nakamura, E.
  • Journal Title: Journal of Analytical Atomic Spectrometry 22 Pages: 407-410
  • Peer Reviewed
• [Journal Article] Simultaneous determination of Cd with In, Tl and Bi by isotope dilution-internal standardization ICP-QMS using externally measured MoO+/Mo+ ratios.
  • Author(s): Makishima, A., Kitagawa, H., Nakamura, E.
  • Journal Title: Geostandards and Geoanalytical Research Volume: (印刷中)
  • Peer Reviewed
• [Journal Article] Melt-peridotite reactions and fluid-metasomatism in the upper mantle, revealed from the geochemistry of peridotite and gabbro from Horoman peridotite massif, Japan
  • Author(s): Malaviarachchi, S. P. K., Makishima, A. Nakamura, E.
  • Journal Title: Journal of Petrology (in press)
• [Journal Article] New preconcentration technique of Zr, Nb, Mo, Hf, Ta and W employing coprecipitation with Ti compounds: its application to Lu-Hf system and sequential Pb-Sr-Nd-Sm separation.
  • Author(s): Makishima, A. and Nakamura, E.
  • Journal Title: Geochemical Journal (in press)
  • NAID: 10021093378
  • Peer Reviewed
• [Journal Article] New sequential separation procedure for Sr, Nd and Pb isotope ratiomeasurement in geological material using MC-ICP-MS and TIMS.
  • Author(s): Makishima, A., Nath, B.N. and Nakamura, E.
  • Journal Title: Geochemical Journal (in press)
  • NAID: 10021093518
  • Peer Reviewed
• [Remarks]
  • URL: http://www.misasa.okayama-u.ac.jp/jp/
• [Remarks]
  • URL: http://misasa.okayama-u.ac.jp/
• [Remarks]
  • URL: http://www.misasa.okayama-u.ac.jp/
• [Remarks]
  • URL: http://www.misasa.okayama-u.ac.jp/
• [Patent(Industrial Property Rights)] 微量元素濃縮の前処理方法 (2009)
  • Inventor(s): 牧嶋昭夫, 中村栄三
  • Industrial Property Rights Holder: 岡山大学学長
  • Filing Date: 2009-08-28
• [Patent(Industrial Property Rights)] 微量元素濃縮の前処理方法 (2009)
  • Inventor(s): 牧嶋昭夫、中村栄三
  • Industrial Property Rights Holder: 岡山大学学長
  • Acquisition Date: 2009-08-28
• [Patent(Industrial Property Rights)] チタン試料中の微量元素を除去する方法 (2008)
  • Inventor(s): 牧嶋昭夫、森口拓弥、中村栄三
  • Industrial Property Rights Holder: 岡山大学学長
  • Patent Publication Number: 2009-256708
  • Filing Date: 2008-04-15
• [Patent(Industrial Property Rights)] チタン試料中の微量元素を除去する方法 (2008)
  • Inventor(s): 牧嶋昭夫, 森口拓弥, 中村栄三
  • Industrial Property Rights Holder: 岡山大学学長
  • Industrial Property Number: 2008-105383
  • Acquisition Date: 2008-04-15
• [Patent(Industrial Property Rights)] チタン試料中の微量元素を除去する方法 (2008)
  • Inventor(s): 牧嶋昭夫、森口拓弥、中村栄三
  • Industrial Property Rights Holder: 岡山大学学長
  • Industrial Property Number: 2008-105383
  • Filing Date: 2008-04-15
• [Patent(Industrial Property Rights)] チタン試料中の微量元素を除去する方法. (2008)
  • Inventor(s): 牧嶋昭夫, 森口拓弥, 中村栄三
  • Industrial Property Rights Holder: 岡山大学・学長
  • Industrial Property Number: 2008-105383
  • Filing Date: 2008-04-15
• [Patent(Industrial Property Rights)] 微量元素濃縮の前処理方法 (2007)
  • Inventor(s): 牧嶋昭夫、中村栄三
  • Industrial Property Rights Holder: 岡山大学学長
  • Filing Date: 2007-01-24
• [Patent(Industrial Property Rights)] 特許出願 (2007)
  • Inventor(s): 牧嶋昭夫、中村栄三
  • Industrial Property Rights Holder: 岡山大学学長
  • Industrial Property Number: 2007-014088
  • Acquisition Date: 2007-01-24