| Budget Amount *help |
¥20,150,000 (Direct Cost: ¥15,500,000、Indirect Cost: ¥4,650,000)
Fiscal Year 2009: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2008: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2007: ¥11,960,000 (Direct Cost: ¥9,200,000、Indirect Cost: ¥2,760,000)
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| Research Abstract |
In order to clarify the specialties of water above the gas-liquid critical temperature (supercritical water), we have selected the molecules which shows the intra-molecular charge-transfer as target, and studied the electronic states, structure, and electron transfer dynamics which is induced by the photo-excitation, using various kinds of laser spectroscopy and theoretical calculations. We have clarified for the first time the hydrogen-bonding between solute and solvent in protic supercritical fluids, and the details of the electron transfer reaction and the vibrational energy relaxation.
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