Development of metal complexes having active oxygen species by controlling of reaction cavity
| Project/Area Number |
19350029
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Kanazawa University |
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Principal Investigator |
SUZUKI Masatatsu Kanazawa University, 物質化学系, 教授 (20091390)
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| Co-Investigator(Kenkyū-buntansha) |
FUJINAMI Shuhei 金沢大学, 物質化学系, 准教授 (10115272)
FURUTACHI Hideki 金沢大学, 物質化学系, 准教授 (40332663)
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| Project Period (FY) |
2007 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥16,380,000 (Direct Cost: ¥12,600,000、Indirect Cost: ¥3,780,000)
Fiscal Year 2009: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2008: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2007: ¥9,750,000 (Direct Cost: ¥7,500,000、Indirect Cost: ¥2,250,000)
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| Keywords | 金属錯体化学 / 生物無機化学 / 合成化学 / 酸素活性種 / 機能モデル / 反応活性種 / 酸素錯体 / 金属酵素モデル / チロシナーゼモデル |
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| Research Abstract |
(μ-η^2:η^2-Peroxo)dicopper(II), bis(μ-oxo)dinickel(III), and (μ-1,2-peroxo)Fe(III)_2 complexes having a variety of dinucleating ligands were prepared. The copper complexes are capable of initiating the oxidation of aliphatic C-H bonds having BDEs from ～74-～92 kcal mol^<-1>. The nickel complexes are also capable of hydroxylating the m-xylyl linker of the supporting ligands. Oxidation ability of the diiron complexes was also investigated.
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Report
(5 results)
Research Products
(52 results)
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[Journal Article] Oxidation Reactivity of a Bis(μ-oxo)- dinickel(III) Complex : Arene Hydroxylation of the Supporting Ligand.2009
Author(s)
K.Honda, J.Cho, T.Matsumoto, J.Roh, H.Furutachi, T.Tosha, M.Kubo, S.Fujinami, T.Ogura, T.Kitagawa, M.Suzuki
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Journal Title
Angew.Chem.Int.Ed. 48
Pages: 3304-3307
Related Report
Peer Reviewed
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[Journal Article] Oxidation Reactivity of a Bis(μ-oxo)-dinickel(III) Complex : Arene Hydroxylation of the Supporting Ligand2009
Author(s)
K. Honda, J. Cho, T. Matsumoto, J. Roh, H. Furutachi, T. Tosha, M. Kubo, S. Fujinami, T. Ogura, T. Kitagawa, M. Suzuki
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Journal Title
Angew.Chem.Int.Ed. 48
Pages: 3304-3307
Related Report
Peer Reviewed
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