| Budget Amount *help |
¥20,800,000 (Direct Cost: ¥16,000,000、Indirect Cost: ¥4,800,000)
Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2008: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2007: ¥18,460,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥4,260,000)
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| Research Abstract |
Metallochelate-type phosphorus ligands, in which a transition-metal complex is incorporated in a chelate-backbone, are expected to be a useful auxiliary ligand for a development of a new metal-catalyst. In this project, two following systems are investigated : 1) new diphosphine chelates bearing a group 4 metal in a chelate-backbone were prepared, and their Pd complexes were found to exhibit high catalytic activities for addition reaction of a P-H bond to C-C triple bonds, 2) several phosphamacrocycles having ferrocene units as chelate-chains were synthesized, and their functionalities were exprored.
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